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High-thermal-conductivity ultraviolet light curing adhesive for optical fiber coil filling and sealing and preparation method thereof

An optical fiber coil, high thermal conductivity technology, applied in the direction of adhesives, adhesive additives, non-polymer adhesive additives, etc., can solve the problems of poor thermal conductivity and large temperature gradient, and achieve improved thermal conductivity and wide operating temperature range , Improve the effect of heat conduction efficiency

Active Publication Date: 2019-03-08
TIANJIN NAVIGATION INSTR RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The purpose of the present invention is to make up for the deficiencies of the prior art, to provide a high thermal conductivity ultraviolet light curing adhesive for optical fiber coil potting and its preparation method, which is used to solve the problem of the existing adhesive after the optical fiber coil potting and curing. The problem of large temperature gradient and poor thermal conductivity, while realizing the full curing of the large thickness of the optical fiber coil potting glue

Method used

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Effect test

preparation example Construction

[0038] A preparation method of a high thermal conductivity ultraviolet light curing adhesive for optical fiber coil potting, comprising the following steps:

[0039]Step 1: Mix epoxy acrylate prepolymer, urethane acrylate prepolymer, and acrylic reactive diluent, add to the reaction kettle, mix evenly at a certain speed, raise the temperature to 80°C, and keep it warm for 1.5 to 2.5 hours. Obtain a mixed prepolymer;

[0040] Step 2: Cool down the mixed prepolymer obtained in step 1 to 45°C, add thermally conductive fillers and additives, stir and mix evenly at a constant temperature of 45°C, and keep warm for 0.5-1.5h to obtain a doped prepolymer;

[0041] Step 3: Heat the doped prepolymer obtained in step 2 to 65°C, add a photoinitiator, a sensitizer and an adhesion promoter under the condition of avoiding light, stir and mix evenly at a constant temperature of 65°C, and cool down at 0.5°C / min Cool down to room temperature at a high rate to obtain a high thermal conductivity...

Embodiment 1

[0044] A method for preparing a high thermal conductivity UV-curable adhesive for optical fiber coil potting, which is specifically completed according to the following steps:

[0045] 1. By weight percentage, take respectively 28% of epoxy acrylate prepolymer, 40% of polyurethane acrylate prepolymer, 15% of acrylic reactive diluent, 3.9% of photoinitiator, 0.1% of sensitizer, and Concentration accelerator 7%, thermal conductivity filler 5%, auxiliary agent 1%;

[0046] The epoxy acrylate prepolymer described in step 1 is Corning 3215;

[0047] The polyurethane acrylate prepolymer described in step 1 is Cytec EB210;

[0048] The acrylic reactive diluent described in step 1 is triethoxylated trimethylolpropane triacrylate;

[0049] The photoinitiator described in step 1 is 2,4,6-trimethylbenzoyl-ethoxyl-phenylphosphine oxide;

[0050] The sensitizer described in step 1 is Doublecure EPD;

[0051] The adhesion promoter described in step 1 is gamma-(methacryloyloxy) propyltri...

Embodiment 2

[0058] A method for preparing a high thermal conductivity UV-curable adhesive for optical fiber coil potting, which is specifically completed according to the following steps:

[0059] 1. By weight percentage, respectively weigh 30% of epoxy acrylate prepolymer, 20% of polyurethane acrylate prepolymer, 26% of acrylic reactive diluent, 0.5% of photoinitiator, 0.5% of sensitizer, and Concentration accelerator 1%, thermal conductivity filler 20%, auxiliary agent 2%;

[0060] The epoxy acrylate prepolymer described in step 1 is Cytec EB6040;

[0061] The polyurethane acrylate prepolymer described in step 1 is Sartomer CN972;

[0062] The acrylic reactive diluent described in step 1 is glycidyl methacrylate;

[0063] The photoinitiator described in step 1 is α, α-diethoxyacetophenone;

[0064] The sensitizer described in step 1 is Doublecure 225;

[0065] The adhesion promoter described in step 1 is 2,3-epoxypropyl propyl trimethoxysilane;

[0066] The thermally conductive fil...

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Abstract

The invention relates to high-thermal-conductivity ultraviolet light curing adhesive for optical fiber coil filling and sealing and a preparation method thereof. The high-thermal-conductivity ultraviolet light curing adhesive comprises, by weight, 10-30% of epoxy acrylate prepolymer, 20-40% of urethane acrylate prepolymer, 15-30% of acrylic acid reactive diluent, 0.5-5% of photo initiator, 0.1-1%of sensitizer, 1-15% of adhesion promoter, 5-20% of heat-conductive filler and 0.2-3% of adjuvant. The prepared high-thermal-conductivity ultraviolet light curing adhesive is capable of realizing large-thickness filling, sealing and curing of coils, a temperature gradient of the optical fiber coils can be decreased in a full temperature range, and full-temperature stability of the optical fiber coils improved. The high-thermal-conductivity ultraviolet light curing adhesive and the preparation method thereof are scientific in designs, innovative and suitable for popularization and application.

Description

technical field [0001] The invention relates to the field of fiber optic gyroscope sensing coil potting technology, in particular to a high thermal conductivity ultraviolet light curing adhesive for fiber optic coil potting and a preparation method thereof. Background technique [0002] Fiber optic gyroscope is a new type of all-solid-state angular rate sensor, which has the advantages of low cost, long life, large dynamic range and high reliability, and has been widely used in military and civilian fields. [0003] The fiber optic coil is the core sensitive component of the fiber optic gyroscope, and its environmental adaptability directly affects the application performance of the fiber optic gyroscope. During the working process, the fiber optic coil has to experience a temperature environment of -45 to 70°C. Whether it can quickly adapt to the external high and low temperature environment is the decisive factor for the coil. important factor in temperature stability. Po...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J175/14C09J163/10C09J11/04C09J11/06
CPCC08K2003/385C08K2201/011C09J11/04C09J11/06C09J175/14C08L63/10C08K3/38C08K5/5435
Inventor 吴晓乐刘伯晗陈桂红赵亮王玥泽左文龙
Owner TIANJIN NAVIGATION INSTR RES INST