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Polyurethane prepolymer, preparation method thereof and preparation method of environmentally friendly polyurea moving scene layer

A polyurethane prepolymer and cycloaliphatic technology, which is applied in the field of polyurethane materials, can solve problems such as poor adhesion, disconnection of primer materials, and poor weather resistance, and achieve low cost and improved yellowing resistance.

Active Publication Date: 2019-03-29
新疆天地金阳环保新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The prior art has the following problems in terms of environmental protection: (1) when producing polyurethane prepolymers, the polyisocyanates added are mostly toxic toluene diisocyanate (TDI), which has a large vapor pressure and is volatile and poisonous, which is the main cause of poisonous runways. Source; (2) The diamine in the curing agent B component, mostly adopts Moca (MOCA). Although Moca has excellent performance, it is a carcinogen, which is easy to bring harm to the production operator; (3) Curing agent B group Volatile and toxic solvents are often added to the part, such as benzene and toluene; (4) Toxic and harmful plasticizers are often added to the curing agent component B, such as phthalates, and excessive use will sterilize boys; (5) When mixing components A and B, poisonous heavy metal catalysts such as lead and mercury are often added; (6) When mixing components A and B, the diluent added is mostly toxic ethyl acetate solvent, which has a strong smell and is very irritating
[0004] The existing technology has the following problems in performance: (1) poor weather resistance; (2) poor stain resistance, easy to absorb dust, dirty surface, not suitable for cleaning; disconnected, separated
In addition, the existing technology still has the problem of inconvenient construction, and problems such as bubbling are very easy to occur during the construction process, which brings difficulties to the construction

Method used

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  • Polyurethane prepolymer, preparation method thereof and preparation method of environmentally friendly polyurea moving scene layer

Examples

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preparation example Construction

[0030] The embodiment of the present invention also provides a kind of preparation method of polyurethane prepolymer, comprises the following steps:

[0031] After vacuum dehydration of polyether polyol at 100-110°C for 1-3h, react with polyisocyanate and aliphatic or alicyclic diisocyanate at 75-85°C for 1-3h to obtain intermediate body. The inventor further improves the yellowing resistance of the polyurethane prepolymer by adjusting the temperature and time of the reaction process, thereby improving the yellowing resistance of the final polyurethane product.

[0032] In some embodiments, the raw material of the polyurethane prepolymer also includes a silane modifier and a plasticizer, and the preparation method of the polyurethane prepolymer also includes mixing the intermediate with the silane modifier and heating the mixture at a temperature of 75-85°C React at low temperature for 1-3h, then mix the reacted mixture with plasticizer and react at a temperature of 50-70°C f...

Embodiment 1

[0045] This embodiment provides a polyurethane prepolymer, its preparation raw materials include 55 parts of polyether polyol, 10 parts of polyisocyanate and 2 parts of hexamethylene diisocyanate in parts by weight; wherein, the functional The degree is 2, the molecular weight is about 1000, and the polyisocyanate is diphenylmethane-4,4'-diisocyanate.

[0046] This embodiment also provides a method for preparing a polyurethane prepolymer, which uses the above formula as a raw material, including: vacuum dehydrating polyether polyol at a temperature of 100°C for 1 hour, and then mixing it with polyisocyanate and diphenylmethane- 4,4'-diisocyanate was reacted at 75°C for 3 hours to obtain an intermediate.

Embodiment 2

[0048] This embodiment provides a polyurethane prepolymer, its preparation raw material includes 90 parts of polyether polyol, 25 parts of polyisocyanate and 6 parts of hexamethylene diisocyanate in parts by weight; wherein, the functional The degree is 3, the molecular weight is about 5000, and the polyisocyanate is diphenylmethane-4,4'-diisocyanate.

[0049] This embodiment also provides a method for preparing a polyurethane prepolymer, which uses the above formula as a raw material, including: vacuum dehydrating polyether polyol at a temperature of 110° C. for 3 hours, and then mixing it with polyisocyanate and diphenylmethane- 4,4'-diisocyanate was reacted at 85°C for 1 hour to obtain an intermediate.

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Abstract

The invention discloses a polyurethane prepolymer, a preparation method thereof and a preparation method of an environmentally friendly polyurea moving scene layer, which relate to the technical fieldof polyurethane materials. The preparation raw materials of the polyurethane prepolymer comprise 55 to 90 parts of polyether polyol, 10 to 25 parts of polyisocyanate and 2 to 6 parts of fatty group or alicyclic diisocyanate; and fatty group or alicyclic diisocyanate is preferably hexamethylene diisocyanate. The preparation method of the polyurethane prepolymer is characterized in that the above formula is the raw materials, polyether polyol is subjected to vacuum dehydrating and then subjected to a reaction with the polyisocyanate and the fatty group or alicyclic diisocyanate to obtain an intermediate. The preparation method of the environmentally-friendly polyurea moving scene layer is characterized by mixing the polyurethane prepolymer and the curing agent, and the prepared moving scenelayer has good yellowing resistance and is an environment-friendly material.

Description

technical field [0001] The invention relates to the technical field of polyurethane materials, and in particular to a polyurethane prepolymer, a preparation method thereof and a preparation method of an environment-friendly polyurea sports surface layer. Background technique [0002] Generally speaking, in the production of sports surface layer, polyurethane prepolymer and curing agent are mixed and cured to form a film. Polyurethane prepolymer is obtained by reacting polyisocyanate and polyether polyol. The curing agent is generally polyether polyol and diamine expander Chain agent, and assist some fillers, additives, etc. The polyurethane prepolymer and the curing agent are mixed in a certain ratio, and a small amount of catalyst and diluent are added at the same time, and then cured to form a film. [0003] The prior art has the following problems in terms of environmental protection: (1) when producing polyurethane prepolymers, the polyisocyanates added are mostly toxic...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/76C08G18/73C08G18/48C08G18/61C08G18/66C08G18/32C08G18/50C08G18/75C08K3/22C08K3/26C08K3/34C08K3/36
CPCC08G18/4812C08G18/4825C08G18/4829C08G18/5024C08G18/61C08G18/6685C08G18/722C08G18/724C08G18/73C08G18/755C08G18/758C08G18/7614C08G18/7671C08K3/22C08K3/26C08K3/34C08K3/346C08K3/36C08K2003/2241C08K2003/265
Inventor 桑亚军刘卫娜
Owner 新疆天地金阳环保新材料有限公司
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