Polyurethane prepolymer, preparation method thereof and preparation method of environmentally friendly polyurea moving scene layer
A polyurethane prepolymer and cycloaliphatic technology, which is applied in the field of polyurethane materials, can solve problems such as poor adhesion, disconnection of primer materials, and poor weather resistance, and achieve low cost and improved yellowing resistance.
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[0030] The embodiment of the present invention also provides a kind of preparation method of polyurethane prepolymer, comprises the following steps:
[0031] After vacuum dehydration of polyether polyol at 100-110°C for 1-3h, react with polyisocyanate and aliphatic or alicyclic diisocyanate at 75-85°C for 1-3h to obtain intermediate body. The inventor further improves the yellowing resistance of the polyurethane prepolymer by adjusting the temperature and time of the reaction process, thereby improving the yellowing resistance of the final polyurethane product.
[0032] In some embodiments, the raw material of the polyurethane prepolymer also includes a silane modifier and a plasticizer, and the preparation method of the polyurethane prepolymer also includes mixing the intermediate with the silane modifier and heating the mixture at a temperature of 75-85°C React at low temperature for 1-3h, then mix the reacted mixture with plasticizer and react at a temperature of 50-70°C f...
Embodiment 1
[0045] This embodiment provides a polyurethane prepolymer, its preparation raw materials include 55 parts of polyether polyol, 10 parts of polyisocyanate and 2 parts of hexamethylene diisocyanate in parts by weight; wherein, the functional The degree is 2, the molecular weight is about 1000, and the polyisocyanate is diphenylmethane-4,4'-diisocyanate.
[0046] This embodiment also provides a method for preparing a polyurethane prepolymer, which uses the above formula as a raw material, including: vacuum dehydrating polyether polyol at a temperature of 100°C for 1 hour, and then mixing it with polyisocyanate and diphenylmethane- 4,4'-diisocyanate was reacted at 75°C for 3 hours to obtain an intermediate.
Embodiment 2
[0048] This embodiment provides a polyurethane prepolymer, its preparation raw material includes 90 parts of polyether polyol, 25 parts of polyisocyanate and 6 parts of hexamethylene diisocyanate in parts by weight; wherein, the functional The degree is 3, the molecular weight is about 5000, and the polyisocyanate is diphenylmethane-4,4'-diisocyanate.
[0049] This embodiment also provides a method for preparing a polyurethane prepolymer, which uses the above formula as a raw material, including: vacuum dehydrating polyether polyol at a temperature of 110° C. for 3 hours, and then mixing it with polyisocyanate and diphenylmethane- 4,4'-diisocyanate was reacted at 85°C for 1 hour to obtain an intermediate.
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