Method for preparing butene and butadiene by catalytic dehydrogenation of butane

A technology for catalytic dehydrogenation and butadiene, applied in chemical instruments and methods, catalyst activation/preparation, catalysts, etc., can solve problems such as deactivation, easy carbon deposition, environmental pollution, etc., and achieve great industrial value and application prospects, Good stability and reproducibility, environmentally friendly effect
CN109608301AActive Publication Date: 2019-04-12SUZHOU UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
SUZHOU UNIV
Publication Date
2019-04-12

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Abstract

The invention provides a method for preparing butene and butadiene by catalytic dehydrogenation of butane. According to the method provided by the invention, a dual active component composite catalystcontaining zirconium and gallium is used, high-efficiency dehydrogenation is performed on the butane, the selectivity of the butadiene in the product reaches 17 %, the selectivity of the total butenereaches 81.5%, and the catalyst shows good stability and reproducibility at high temperatures.
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Description

technical field

[0001] The invention relates to a method for preparing butene and butadiene, in particular to a method for preparing butene and butadiene by catalytic dehydrogenation of butane. Background technique

[0002] Butene is the basic raw material of petrochemical industry, second only to ethylene and propylene in petrochemical olefin raw materials, and is an important monomer of synthetic rubber and polymer materials. Generally speaking, butene mainly has several isomers, such as n-butene (1-butene), isobutene, cis-dibutene and trans-dibutene. N-butene is mainly used in the manufacture of methyl ethyl ketone, sec-butanol, butylene oxide and butene polymers and copolymers. Isobutylene is mainly used in the manufacture of butyl rubber, polyisobutylene rubber and various plastics. Generally speaking, 1-butene and 2-butene do not need to be separated, and can be chemically processed together to produce many important basic organic chemical products, such as hydration...

Claims

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