Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

A kind of insoluble and infusible metal-modified cruciform ester compound and preparation method thereof

A metal-modified, cross-shaped technology, applied in the field of metal-modified cross-shaped ester compounds and their preparation, can solve the problems of high solubility and low melting point, ensure rheological properties, reduce the influence of rheological properties, and improve the The effect of promoting value

Active Publication Date: 2021-11-19
DONGHUA UNIV +1
View PDF3 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to solve the problem that the functional cross-shaped esterified compound in the above-mentioned prior art has too high solubility in common spinning solvents or polymers and has a low melting point, and to provide an insoluble and infusible metal-modified cross-shaped Ester

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A kind of insoluble and infusible metal-modified cruciform ester compound and preparation method thereof
  • A kind of insoluble and infusible metal-modified cruciform ester compound and preparation method thereof
  • A kind of insoluble and infusible metal-modified cruciform ester compound and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] A kind of preparation method of insoluble and infusible metal-modified cruciform ester compound, concrete steps are as follows:

[0049] (1) prepare cross-type esterified product;

[0050] (a) Dibasic acid A 2 Mix with pentaerythritol at a molar ratio of 4:1, carry out melt esterification reaction under nitrogen protection and mechanical stirring at a stirring speed of 300rpm, collect the product, obtain DAPER through dissolution, filtration and drying, wherein the temperature of the melt esterification reaction is 200°C, the reaction time is 3h, A 2 The structural formula is:

[0051]

[0052] (b) Dibasic carboxylic acid B 2 Mix with ethylene glycol at a molar ratio of 1:1, add 4-methylbenzenesulfonic acid, and carry out melt condensation reaction under nitrogen protection and mechanical stirring at a stirring speed of 500rpm to obtain DADA, wherein B 2 The molar ratio with 4-methylbenzenesulfonic acid is 1:0.01, the temperature of melt condensation reaction is ...

Embodiment 2

[0060] A kind of preparation method of insoluble and infusible metal-modified cruciform ester compound, concrete steps are as follows:

[0061] (1) prepare cross-type esterified product;

[0062] (a) Dibasic acid A 2 Mix with pentaerythritol at a molar ratio of 4:1, carry out melt esterification under argon protection and mechanical stirring at a stirring speed of 350rpm, collect the product, dissolve, filter and dry to obtain DAPER, wherein the melt esterification The temperature is 185°C, the reaction time is 1h, A 2 The structural formula is:

[0063]

[0064] (b) Dibasic carboxylic acid B 2 Mix with propylene glycol at a molar ratio of 1:1, add 4-methylbenzenesulfonic acid, and carry out melt condensation reaction under nitrogen protection and mechanical stirring at a stirring speed of 300rpm to obtain DADA, wherein B 2 The molar ratio with 4-methylbenzenesulfonic acid is 1:0.01, the temperature of the melt condensation reaction is 185°C, and the reaction time is 1h...

Embodiment 3

[0072] A kind of preparation method of insoluble and infusible metal-modified cruciform ester compound, concrete steps are as follows:

[0073] (1) prepare cross-type esterified product;

[0074] (a) Dibasic acid A 2 Mix with pentaerythritol at a molar ratio of 4:1, carry out melt esterification under the condition of helium protection and mechanical stirring at a stirring speed of 400rpm, collect the product, obtain DAPER through dissolution, filtration and drying, wherein the melt esterification The temperature is 180°C, the reaction time is 2h, A 2 The structural formula is:

[0075]

[0076] (b) Dibasic carboxylic acid B 2 Mix with 1,4-butanediol at a molar ratio of 1:1, add 4-methylbenzenesulfonic acid, and carry out melt condensation reaction under argon protection and mechanical stirring at a stirring speed of 500rpm to obtain DADA, wherein B 2 The molar ratio with 4-methylbenzenesulfonic acid is 1:0.01, the temperature of melt condensation reaction is 180°C, an...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
decomposition temperatureaaaaaaaaaa
particle diameteraaaaaaaaaa
decomposition temperatureaaaaaaaaaa
Login to View More

Abstract

The invention relates to an insoluble and infusible metal-modified cruciform ester compound and a preparation method thereof. The insoluble and infusible metal-modified cruciform ester compound is prepared by dripping an acetate metal salt solution into the cruciform ester compound solution. The obtained metal-modified cruciform ester compound is a network polymer formed by cross-linking the cruciform ester compound with metal ions. The metal-modified cruciform ester compound has insoluble and infusible characteristics, and is insoluble in organic solvent I below 80 ° C. No melting within the range from room temperature to T, T≥380°C, organic solvent I is aromatic hydrocarbon solvent, aliphatic hydrocarbon solvent, alicyclic hydrocarbon solvent, halogenated hydrocarbon solvent, alcohol solvent, ester solvent, ketone solvent , acetonitrile, pyridine, phenol, N,N‑dimethylformamide or N,N‑dimethylacetamide. The preparation method of the invention has simple process and low cost; the obtained product has insoluble and infusible characteristics, and solves the problems of excessively high solubility and low melting point of the existing functional cruciform ester compounds.

Description

technical field [0001] The invention belongs to the technical field of polymer blending, and relates to an insoluble and infusible metal-modified cruciform ester compound and a preparation method thereof. Background technique [0002] With the development of my country's synthetic materials industry and the continuous expansion of application fields, polymer materials such as polyester have been widely used in various fields such as chemical building materials, electronic appliances, transportation, aerospace, daily furniture, interior decoration, and basic necessities of life. Higher demands are placed on the functionality of synthetic materials. Functional modification of polymers has become a hot research direction at present. [0003] Ester compounds are often used as functional modification carriers because they are similar in structure to polyester and other polymers and have good compatibility. Researchers often perform functional modification on esterified compound...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C08J3/24C08G63/692C08G63/685C08G63/78C08G63/87C08L67/00
Inventor 孙宾纪晓寰朱美芳李东华敖翔陆育明冯忠耀杨卫忠
Owner DONGHUA UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com