A kind of inorganic perovskite solar cell without hole transport layer and preparation method thereof

A technology for solar cells and transport layers, applied in circuits, photovoltaic power generation, electrical components, etc., can solve the problem of poor chemical stability of hole transport layers, hysteresis of perovskite solar cell volt-ampere characteristic curve tests, and hole transport layer materials Expensive and other issues, to achieve the effect of reducing costs, simplifying the battery structure, and stabilizing the photoelectric conversion efficiency

Active Publication Date: 2020-05-12
NINGBO UNIVERSITY OF TECHNOLOGY
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AI Technical Summary

Problems solved by technology

The hole transport layer material is expensive, which makes the manufacturing cost of perovskite solar cells greatly increased
And due to the poor chemical stability of the hole transport layer, the volt-ampere characteristic curve test of perovskite solar cells shows obvious hysteresis.

Method used

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  • A kind of inorganic perovskite solar cell without hole transport layer and preparation method thereof
  • A kind of inorganic perovskite solar cell without hole transport layer and preparation method thereof
  • A kind of inorganic perovskite solar cell without hole transport layer and preparation method thereof

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Embodiment Construction

[0037] The technical solutions of the present invention will be further described and illustrated through specific examples below. Unless otherwise specified, the raw materials used in the examples of the present invention are commonly used raw materials in the art, and the methods used in the examples are conventional methods in the art.

[0038] The term "perovskite" as used herein refers to a compound with CaTiO 3 The three-dimensional crystal structure related to the three-dimensional crystal structure of the material, the perovskite material can be formulated by the general formula [A][B][X] 3means, wherein A is at least one cation, B is at least one cation, and X is at least one anion. In the present invention, A is Cs, B is Sn and Pb, and X is I.

[0039] The term "alloy" as used herein refers to a substance having two or more metal elements forming one or more metal phases.

[0040] In an example of the present invention, an inorganic perovskite solar cell without a...

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Abstract

The invention belongs to the technical field of perovskite solar cells, and particularly relates to an inorganic perovskite solar cell without a hole transport layer and a preparation method thereof.The solar cell is sequentially provided with conductive glass, a luminous layer, an electron transport layer and a metal electrode in a laminated mode. The luminescent layer is a Sn-Pb alloy perovskite thin film with a molecular formula of CsSn 1-x Pb x I 3, wherein x is larger than 0 and is less than 1. The preparation of the solar cell without the hole transport layer is realized by using the CsSn 1-x Pb x I 3 perovskite material as a luminescent layer, so that the structure of the solar cell is further simplified, and the cost is reduced. In addition, the HTM-free solar cell based on CsSn 1-x Pb x I 3 has stable photoelectric conversion efficiency and no obvious hysteresis.

Description

technical field [0001] The invention belongs to the technical field of perovskite solar cells, and in particular relates to an inorganic perovskite solar cell without a hole transport layer and a preparation method thereof. Background technique [0002] In recent years, organic-inorganic hybrid halide perovskite materials have become popular in the field due to their unique physical and chemical properties, such as high optical absorption, high carrier mobility, long diffusion length, and low cost and solvent processability. Optoelectronic devices such as solar cells have received extensive attention. Although this high-performance perovskite solar cell has been improved through continuous research and is beginning to be comparable to commercial silicon-based solar cells, the long-term stability of perovskite remains a problem as companies begin to commercialize it on a large scale. Perovskite solar cells with better performance usually contain organic cations such as methy...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L51/46H01L51/42H01L51/48C03C17/22
CPCY02E10/549
Inventor 杨祚宝张小红侯慧林王霖陈善亮刘乔杨为佑
Owner NINGBO UNIVERSITY OF TECHNOLOGY
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