Laminar composite SiC/graphite film material for thermal management and preparation method thereof

A technology of layered composite material and graphite film, which is applied in the field of SiC/graphite film layered composite material for thermal management and its preparation, can solve problems such as public literature reports of non-SiC ceramic reinforced graphite film layered composite material, and achieve high Strength, ensuring work efficiency and service life, and the effect of simple preparation process

Active Publication Date: 2019-05-31
XIAN AERONAUTICAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, up to now, research on graphite film layered composites at home and abroad has mainly focused on high thermal conductivity metals (such as Al, Cu, etc.) composites for effective thermal management” (J.Alloys Compd.711(2017) 22-30), literature “Layer by layergraphite film reinforced aluminum composites with an enhanced performance of thermal conduction in the thermal management applications” (J.Alloys Compd.742(2018 ) 601-609), etc., there is no public literature report on SiC ceramic reinforced graphite film layered composites

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] The first step is the preparation of graphite film coated with SiC ceramic layer:

[0027] 1) According to the molar ratio of Si powder and graphite film as 1:2, take Si powder with a particle size of 5 microns;

[0028] 2) Take NaCl and NaF according to the molar ratio of NaCl and NaF as 1:1, pour them into a mortar, grind them and mix them evenly to obtain mixed salt powder;

[0029] 3) According to the mass ratio of Si powder and mixed salt powder as 1:5, pour Si powder and mixed salt powder into a mortar and grind and mix evenly to obtain coating powder;

[0030] 4) Take the graphite film and coating powder with a thickness of 12 microns and alternately load them layer by layer in the graphite crucible whose inner surface is coated with SiC ceramic layer according to the order of "coating powder-graphite film-coating powder...", cover Put the crucible cover in the heat treatment furnace;

[0031] 5) Vacuumize the heat treatment furnace and feed it with argon gas. ...

Embodiment 2

[0037] The first step is the preparation of graphite film coated with SiC ceramic layer:

[0038] 1) According to the molar ratio of Si powder and graphite film as 2:5, take Si powder with a particle size of 5 microns;

[0039] 2) Take NaCl and NaF according to the molar ratio of NaCl and NaF as 1:1, pour them into a mortar, grind them and mix them evenly to obtain mixed salt powder;

[0040] 3) According to the mass ratio of Si powder and mixed salt powder as 1:5, pour Si powder and mixed salt powder into a mortar and grind and mix evenly to obtain coating powder;

[0041] 4) Take the graphite film and coating powder with a thickness of 50 microns and alternately load them layer by layer in the graphite crucible whose inner surface is coated with SiC ceramic layer according to the order of "coating powder-graphite film-coating powder...", cover Put the crucible cover in the heat treatment furnace;

[0042] 5) Vacuumize the heat treatment furnace and feed it with argon gas. ...

Embodiment 3

[0048] The first step is the preparation of graphite film coated with SiC ceramic layer:

[0049] 1) According to the molar ratio of Si powder and graphite film as 3:10, take Si powder with a particle size of 5 microns;

[0050] 2) Take NaCl and NaF according to the molar ratio of NaCl and NaF as 1:1, pour them into a mortar, grind them and mix them evenly to obtain mixed salt powder;

[0051] 3) According to the mass ratio of Si powder and mixed salt powder as 1:5, pour Si powder and mixed salt powder into a mortar and grind and mix evenly to obtain coating powder;

[0052] 4) Take graphite film and coating powder with a thickness of 40 microns and alternately load them layer by layer into a graphite crucible whose inner surface is coated with a SiC ceramic layer in the order of "coating powder-graphite film-coating powder...", cover Put the crucible cover in the heat treatment furnace;

[0053] 5) Vacuumize the heat treatment furnace and feed it with argon gas. Under the p...

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Abstract

The invention discloses a laminar composite SiC / graphite film material for thermal management and a preparation method thereof. The composite material is prepared from, by volume, 10-50% of a reinforced SiC phase and 50-90% of a graphite film matrix phase, wherein graphite films and SiC are alternately distributed in the composite material layer by layer and show perfect directional arrangement. The preparation method of the composite material comprises the four steps of coating the surface of each graphite film with a SiC ceramic layer, stacking the graphite films coated with the SiC ceramiclayers on the surfaces layer by layer for pre-pressing and shaping, performing vacuum hot-pressing sintering on a pre-shaped sample, and performing subsequent treatment on the sintered sample. The preparation method effectively solves the problems that it is difficult to conduct sintering densification on a traditional composite SiC / graphite material and the interface bonding strength between SiCand graphite is low. The laminar composite SiC / graphite film material prepared by the method not only has high thermal conductivity in a direction parallel to a lamination direction but also can obtain a thermal expansion coefficient matched with a packaging substrate in a direction perpendicular to the lamination direction. Meanwhile, the material is low in density and high in strength and servesas a novel thermal management material with a great application prospect.

Description

technical field [0001] The invention relates to a functional material and a preparation method thereof, in particular to a SiC / graphite film layered composite material for thermal management and a preparation method thereof. Background technique [0002] In recent years, with the advancement of electronic components / devices towards high integration, miniaturization and light weight, the research on anisotropic graphite materials for thermal management has made great progress. At present, more researches are mainly on highly oriented graphite materials, and the raw materials used are usually graphite fibers, graphite flakes, etc. Such as the literature "Laminate squeeze casting of carbon fiber reinforced aluminum matrix composites" (Materials and Design.67 (2015) 154-158), the literature "In-plane thermal enhancement behaviors of Al matrix composites with oriented graphite flake alignment" (Composites: Part B 70 (2015) 256-262) et al. Studies have shown that the degree of o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B41/87
Inventor 张阔马莹王栓强唐健江
Owner XIAN AERONAUTICAL UNIV
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