Preparation method for aramid fiber composite rubber pipeline

A technology of aramid fiber and composite rubber, which is applied in the direction of tubular objects, applications, household appliances, etc., can solve the problems of rubber molecular weight drop, excessive fiber length reduction, and lack of composite rubber hose materials, etc., to achieve puncture resistance and anti-corrosion The effect of improving the tensile capacity and improving the tensile modulus

Inactive Publication Date: 2019-07-30
青岛中维新材料有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, because aramid fiber has a high degree of orientation and cleanliness, and has no amorphous region, and there are a large number of benzene rings in the molecular chain segment, the steric hindrance is relatively large, so it is difficult for the amide group to interact with other atoms or groups. Chemical reaction occurs, so it is difficult to bond and impregnate the surface of aramid fibers, and the dispersion of fibers is another technical problem in the industry. Excessive mixing for uniform fiber dispersion will lead to excessive reduction in fiber length and rubber The molecular weight decreases, which deteriorates the performance; if the fiber length is long but the dispersion is uneven, the composite rubber hose material with excellent performance cannot be obtained.

Method used

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  • Preparation method for aramid fiber composite rubber pipeline

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preparation example Construction

[0056] A preparation method for an aramid fiber composite rubber pipeline, comprising the steps of:

[0057] (1) Modification of aramid fibers;

[0058] (2) Mixed rubber processing

[0059] (3) Forming

[0060] (4) vulcanization;

[0061] Wherein, the specific steps in step one are as follows:

[0062] It includes the following processing steps for aramid raw silk: A: first bath; B: first drying; C: second bath; D: second drying; E: winding; F: cutting; wherein: the steps In A, the water-solvent type highly reactive isocyanate is used for pre-impregnation; in step C, the RFL impregnation solution is used for impregnation, and the formula of the RFL impregnation solution is: RF resin: 420.6 parts by weight; soft water: 95.2 parts by weight; VP Latex 40%: 484.2 parts by weight; Wherein the formula of RF resin is: Soft water: 425.6 parts by weight; Sodium hydroxide 7%: 16 parts by weight; Resorcinol solid: 22 parts by weight; Formaldehyde 38%: 13 parts by weight;

[0063] I...

Embodiment 1

[0072] Embodiment 1: RF resin solution deployment;

[0073] (1) prepare soft water, the resorcinol solid of 22 parts by weight and the formaldehyde 38% of 13 parts by weight;

[0074] (2) Put soft water in the reaction tank, and the water temperature is controlled at 23°C;

[0075] (3) Sodium hydroxide is dissolved in demineralized water, and after being mixed with the aqueous sodium hydroxide solution of 7%, put in the reaction tank, the aqueous sodium hydroxide solution is 16 parts by weight, and stirs and mixes for 10 minutes;

[0076] (4) resorcinol solid is dissolved in demineralized water, is mixed with the resorcinol solution of concentration 10~20% and puts in the reaction tank after, and stirs and mixes 20 minutes;

[0077] (5) Put 38% of formaldehyde into soft water and mix to prepare a formaldehyde solution with a concentration of 5-20%, slowly add the formaldehyde solution into the reaction tank, and continue to stir the reaction tank;

[0078] (6) Cool the react...

Embodiment 2

[0079] Embodiment 2: the deployment of RFL dipping solution;

[0080] One, prepare the RF resin liquid of 420.6 parts by weight, the soft water of 95.2 parts by weight and the VP latex 40% of 484.2 parts by weight, total weight part 1000;

[0081] 2. Put soft water and VP latex into the blending tank;

[0082] 3. Transfer the RF resin liquid to the blending tank and keep stirring. The transfer of the RF resin liquid is completed within 10 minutes. The RF resin liquid is transferred by spraying. The temperature of the glue solution is 20°C, and the pH value is adjusted to between 8-9;

[0083] 4. From the transfer of RF resin, after 27 hours of aging, the obtained RFL impregnation solution is sent to the subsequent impregnation machine for use.

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Abstract

The invention provides a preparation method of an aramid fiber composite rubber pipeline. The method includes the following steps of 1, modification of aramid fiber, 2, processing of blended rubber, 3, molding and 4, vulcanization. The modification of aramid fiber specifically includes the following steps of A, first bath treatment, B, primary drying, C, secondary bath treatment and D, secondary drying, wherein in the step A, water-soluble high-activity reactive isocyanate is adopted for pre-impregnation, and in the step C, RFL impregnation liquid is used for impregnation. The two-bath impregnation treatment technology with activating first and RFL tackifying second is adopted, and not only has improvement in the fiber surface activation pretreatment technology during primary bath, but also has creative improvement in RFL tackifying treatment formula and process during secondary bath. After repeated experiments, the matching ratio of primary-bath impregnation liquid, secondary-bath RFresin and RFL impregnation liquid and the technological parameters of impregnation treatment are obtained, the specific parameters are determined, and the optimal effect is achieved.

Description

technical field [0001] The invention relates to the technical field of aramid fiber preparation, in particular to a method for preparing an aramid fiber composite rubber pipeline. Background technique [0002] Rubber hose refers to the pipe used for gas transportation, which is often used in gas welding, gas cutting, various gas shielded welding, plasma arc welding and cutting, etc. Rubber tubes are widely used. After more than 50 years of development, my country's rubber tube industry has played an indispensable supporting role in the national economy. The rubber tube industry has continuously penetrated into related fields, opening up the application range and fields of rubber tubes. Products are widely used in ports, petroleum, automobiles, light industry, engineering machinery, agriculture, aviation, aerospace and other fields. [0003] The rubber tube has good sealing performance, firm and flexible structure, and has incomparable advantages compared with metal tubes or ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L9/10C08L61/12C08L77/10B29D23/00
CPCB29D23/001C08L9/10C08L2205/03C08L2205/16C08L61/12C08L77/10
Inventor 马常杰
Owner 青岛中维新材料有限公司
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