Hydrophobic anti-reflection solution and hydrophobic anti-reflection glass

An anti-reflection glass, hydrophobic technology, applied in coatings and other directions, can solve the problems of increased maintenance costs and high frequency of glass cleaning, reducing frequency and cost, extending service life, and improving gloss and smoothness.

Pending Publication Date: 2019-08-02
RIZHAO HUAYE GLASS +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Coating anti-reflection coating on the surface of photovoltaic glass has almost become the standard configuration of the industry. Solar photovoltaic panels are mainly installed in outdoor environments, which are inevitably affected by environmental conditions such as wind, sand, rain, and fog. Due to the differences in domestic natural environments, Sometimes sand, dust, pollutants, etc. adhere to the glass surface, requiring high frequency of glass cleaning, which increases the cost of maintenance

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] The hydrophobic antireflection solution described in this example was prepared according to the following steps:

[0025] 1. Using ethyl orthosilicate as a precursor, absolute ethanol as a solvent, and ammonia (25% by mass fraction) as a catalyst, the specific operations are as follows: at room temperature, mix 3 parts of ethyl orthosilicate, 80 parts of absolute ethanol, 0.05 parts of ammonia water and 6 parts of deionized water were mixed, stirred for 30 minutes, and aged at room temperature for 8 to 10 days, then refluxed to remove ammonia at 80°C for 4 to 10 hours; standing still, the first mixed solution ( Alkali-catalyzed nano-SiO 2 Sol);

[0026] 2. Mix 3 parts of dimethyldiethoxysilane (DDS), 80 parts of anhydrous isopropanol, 0.01 part of hydrochloric acid, and 2 parts of deionized water, stir and age for 3-10 days to obtain The second mixed solution (hydrophobic modification solution);

[0027] 3. Mix 10 parts of the second mixed solution and 100 parts of t...

Embodiment 2

[0041] The hydrophobic antireflection solution described in this example was prepared according to the following steps:

[0042] 1. Using tetraisopropyl orthosilicate as a precursor, isopropanol as a solvent, and 0.1mol / L potassium hydroxide as a catalyst, mix 8 parts of tetraisopropyl orthosilicate, 100 parts of isopropanol, Mix 0.05 parts of 0.1 mol / L potassium hydroxide solution and 20 parts of deionized water, stir for 30 minutes, and age at room temperature for 8 to 10 days to obtain the first mixed solution (alkali-catalyzed nano-SiO 2 Sol);

[0043] 2. Mix 5 parts of dimethyldiethoxysilane (DDS), 100 parts of absolute ethanol, 0.04 parts of glacial acetic acid, and 20 parts of deionized water, stir and age for 3 to 10 days to obtain the second Mixed solution (hydrophobic modification solution);

[0044] 3. Mix 40 parts of the second mixed solution and 100 parts of the first mixed solution, stir, and add 0.1 parts of monomer nano-silver solution, 0.5 parts of silane co...

Embodiment 3

[0051] The hydrophobic antireflection solution described in this example was prepared according to the following steps:

[0052] 1. Using ethyl orthosilicate as a precursor, absolute ethanol as a solvent, and ammonia (25% by mass fraction) as a catalyst, the specific operations are as follows: at room temperature, mix 2 parts of ethyl orthosilicate, 80 parts of absolute ethanol, 0.05 parts of ammonia water and 6 parts of deionized water were mixed, stirred for 30 minutes, and aged at room temperature for 8 to 10 days, then refluxed to remove ammonia at 80°C for 4 to 10 hours; standing still, the first mixed solution ( Alkali-catalyzed nano-SiO 2 Sol);

[0053] 2. Mix 8 parts of dimethyldiethoxysilane (DDS), 100 parts of absolute ethanol, 0.04 parts of glacial acetic acid, and 20 parts of deionized water, stir and age for 3 to 10 days to obtain the second Mixed solution (hydrophobic modification solution);

[0054] 3. Mix 40 parts of the second mixed solution and 100 parts o...

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Abstract

The invention relates to the technical field of glass product manufacturing, in particular to a hydrophobic anti-reflection solution and hydrophobic anti-reflection glass. The hydrophobic anti-reflection solution provided by the invention is prepared by the following steps: 1, preparing a base-catalyzed nano-SiO2 sol; 2, preparing a hydrophobically modified solution; 3, stirring the hydrophobically modifying solution and the base-catalyzed nano-SiO2 sol, sequentially adding a monomeric nanosilver solution, a stabilizer, a leveling agent and a viscosity modifier, stirring and aging to obtain the hydrophobic anti-reflection solution. When the surface of the glass is coated with the hydrophobic anti-reflection solution, a dense network nano-protective film is formed on the glass base surface,thereby effectively improving the surface gloss and smoothness of a material; a static contact angle of the glass and water is greater than or equal to 100 degrees, the glass surface reflectivity isreduced by 90% or more, and therefore, the hydrophobic anti-reflection solution not only has the advantages of anti-reflection, easy cleaning, anti-fouling and anti-bacterial effect, but also has relatively high hardness and wear resistance, and can prolong the service life of the glass.

Description

technical field [0001] The invention relates to the technical field of glass product manufacture, in particular to a hydrophobic anti-reflection solution and a hydrophobic anti-reflection glass. Background technique [0002] Glass is a kind of inorganic amorphous material composed of sodium calcium silicate. It is easy to be corroded by air and water vapor, resulting in surface aging, decreased transmittance, and difficult to clean. Glass is also hydrophilic, which will attract and lock a layer of water molecules on the surface, and adhere to dust; in addition, glass is not conductive, and the static electricity generated by friction is not easy to dissipate, and it is easy to absorb sand and dust. Many substances, such as lime deposits, plaster, mortar, sealants, metal oxides, and carbonized food deposits, etc., are firmly attached to the glass surface by chemical means, and it is difficult to remove them with general cleaning methods. A large number of bacteria will adhere...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C17/00
CPCC03C17/007C03C17/009C03C2217/29C03C2217/732C03C2218/11
Inventor 辛崇飞尹强丁磊李江郑世军丁明娟
Owner RIZHAO HUAYE GLASS
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