Low-carbon olefin production method

A low-carbon olefin and regeneration agent technology, which is applied in the production of bulk chemicals, hydrocarbon oil treatment, and hydrocarbon cracking to produce hydrocarbons. It can solve the problems of low olefin yield, high coke yield, and low coke yield. The effect of reducing olefin production

Active Publication Date: 2019-08-16
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0012] The purpose of the present invention is to overcome the defect that the olefin yield is not high and the coke yield is relatively high in the production of ethylene-based olefin products in the prior art, and to provide an olefin yield under the premise of ensuring low energy consumption A method with higher coke yield and lower coke yield to produce mainly ethylene from raw materials containing heavy feed oil and light feed oil, with by-products of propylene and triphenylaromatics

Method used

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  • Low-carbon olefin production method
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  • Low-carbon olefin production method

Examples

Experimental program
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specific Embodiment approach

[0057] The heavy raw material oil 2 and steam 1 are introduced into the first cracking reaction zone 3 containing the first contact agent through pipelines to carry out the cracking reaction, and then the light raw material oil 12 and steam 1 are introduced into the first cracking reaction zone 3 The stream is introduced into the second cracking reaction zone 4 containing the second contact agent for cracking reaction; then the stream after the cracking reaction obtained on the top or top of the second cracking reaction zone 4 is condensed to obtain gaseous substances and liquid substances respectively. and coke contact agent, cracked product 10 leads to the reaction system; through the pipeline, the coke catalyst is introduced into the regenerator 7 containing oxygen-containing gas 5 for charring treatment to obtain the regenerant, and the smoke generated in the regenerator 7 Gas 11 is drawn out of the reaction system from the top of the regenerator 7; and part of the regenera...

Embodiment 1

[0072] According to this embodiment figure 1 The process route shown is carried out, specifically, in the present embodiment:

[0073] Heavy raw oil and water vapor enter the first cracking reaction zone after preheating, the contact agent is MFC-2, and the process conditions are: reaction temperature 500°C, water-oil ratio 0.10, weight hourly space velocity 4h -1 , pressure 0.15MPa. Light crude oil, the stream after cracking reaction and part of the water vapor from the external pipeline enter the second cracking reaction zone. The process conditions are: reaction temperature 700°C, water-oil ratio 0.5, weight hourly space velocity 20h -1 , pressure 0.15MPa. The coke contact agent obtained after the contact cracking reaction enters the settler for stripping and then enters the regenerator for charring treatment. The process conditions are: the temperature in the dense-phase bed is 750 ° C, and the air is charred. Part of the regenerated agent after charring enters the seco...

Embodiment 2

[0076] According to this embodiment figure 1 The process route shown is carried out, specifically, in the present embodiment:

[0077] Heavy raw oil and water vapor enter the first cracking reaction zone after preheating, the contact agent is MFC-1, and the process conditions are: reaction temperature 540 ℃, water-oil ratio 0.20, weight hourly space velocity 12h -1 , pressure 0.28MPa. Light crude oil, the stream after cracking reaction and part of the water vapor from the external pipeline enter the second cracking reaction zone. The process conditions are: reaction temperature 620°C, water-oil ratio 0.9, weight hourly space velocity 40h -1 , pressure 0.28MPa. The coke contact agent obtained after the contact cracking reaction enters the settler for stripping and then enters the regenerator for charring treatment. The process conditions are: the temperature in the dense-phase bed is 700 ° C, and the air is charred. Part of the regenerated agent after charring enters the sec...

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Abstract

The invention relates to the field of low-carbon olefin production, and discloses a low-carbon olefin production method, which comprises: introducing a heavy raw material oil into a first cracking reaction zone, and carrying out a reaction; introducing a light raw material oil and the stream from the first cracking reaction zone into a second cracking reaction zone, and carrying out a reaction toobtain a carbon depositing contact agent; carrying out charring treatment on the carbon depositing catalyst to obtain a regeneration agent; and directly introducing part of the regeneration agent intothe second cracking reaction zone to participate in a cracking reaction, and introducing the remaining regeneration agent into the first cracking reaction zone to participate in the cracking reactionafter heat exchange, wherein a weight ratio of the regeneration agent introduced into the first cracking reaction zone to the regeneration agent introduced into the second cracking reaction zone is 1:(1-8). According to the present invention, with the method, under the premise of the low energy consumption, the main production of ethylene and the by-production of propylene and triphenylarene fromthe raw material-containing heavy oil in a high olefin yield and low coke yield manner can be ensured.

Description

technical field [0001] The invention relates to the field of production of low-carbon olefins, in particular to a method for producing low-carbon olefins. Background technique [0002] Low-carbon olefins such as ethylene and propylene are important organic chemical raw materials. At present, the industrial production of ethylene and propylene mainly includes steam cracking and catalytic cracking. [0003] The steam cracking method uses a high-temperature method for cracking. The range of raw materials includes gaseous hydrocarbons, light oil (naphtha), kerosene, light diesel oil, and heavy diesel oil. The cracking temperature is generally 750-900°C. The reaction is carried out in a furnace tube, and the reacted product is rapidly cooled at the outlet of the furnace to terminate its reaction, and then separated by a fractionating tower to obtain cracked gas, cracked gasoline, cracked diesel and cracked tar. The yield of ethylene in the light olefins obtained by steam cracki...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G51/02C10G9/36C07C4/06
CPCC07C4/06C10G9/36C10G51/023C10G2300/4018C10G2300/4025C10G2400/20Y02P20/52Y02P20/584
Inventor 张书红龙军李延军申海平李子锋任磊
Owner CHINA PETROLEUM & CHEM CORP
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