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Poplar steam blasting liquid hemicellulose-based hydrogel and preparation method thereof

A technology of hemicellulose and hydrogel, which is applied in poplar wood steam explosion liquid hemicellulose-based hydrogel and its preparation field, can solve the problems of poor water retention performance, poor environmental protection performance and poor treatment effect of hydrogel, etc. Achieve excellent water retention performance, less environmental pollution, and simplify the preparation process

Active Publication Date: 2019-09-17
TIANJIN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The acquisition and preparation of hydrogels are mainly divided into two categories from the source of materials: one is synthetic hydrogels based on petroleum sources, such as polyacrylic acid and its ester series hydrogels, polyvinyl alcohol series hydrogels, and polyvinyl alcohol series hydrogels. Gel etc., such as the publication number is CN106554454A, the patent name is a kind of preparation method of polyacrylic acid hydrogel adsorption material and the patent of application discloses a kind of preparation method of polyacrylic acid hydrogel, but this kind of hydrogel has its The initial preparation material is non-renewable energy, and the environmental protection performance is poor; the second is the non-synthetic hydrogel with natural polymer as the main body or starting material, such as starch-based hydrogel and cellulose-based hydrogel belonging to polysaccharides. Hydrogel, etc. The manufacture of this type of hydrogel is basically environmentally friendly and degradable in terms of starting materials, and the source of raw materials is also relatively extensive and renewable. The publication number is CN105504315B, and the patent name is a kind of straw full-component hydraulic The patent on the preparation method of glue and its application discloses a method of preparing hydrogel with straw as the starting material, but the method uses chemical methods to pretreat the straw to break the fibers in the straw and destroy the hemicellulose 1. The encapsulation of cellulose by lignin has poor treatment effect, high energy consumption, complicated method, and poor practicability; in addition, the hydrogel with natural polymer as the main body in the prior art has poor water retention performance, which hinders its application

Method used

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  • Poplar steam blasting liquid hemicellulose-based hydrogel and preparation method thereof
  • Poplar steam blasting liquid hemicellulose-based hydrogel and preparation method thereof
  • Poplar steam blasting liquid hemicellulose-based hydrogel and preparation method thereof

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Embodiment 1

[0036] The poplar wood steam explosion liquid hemicellulose-based hydrogel described in this embodiment is a three-dimensional network structure polymer formed by graft copolymerization of hemicellulose in the poplar wood steam explosion liquid with acrylamide and acrylic acid. The mass ratio of cellulose, acrylamide and acrylic acid is 1:1.3:3.6.

[0037] The preparation method of the poplar steam explosion liquid hemicellulose-based hydrogel described in the present embodiment is as follows:

[0038] S1. Immerse the poplar wood in a sealed bag with distilled water for rehydration balance, control the water content at about 35%, put it in a refrigerator at 6°C, and balance it for 48 hours; put the rehydrated and balanced poplar wood chips into the high pressure reaction In the autoclave, steam is introduced into the autoclave first, so that the temperature rises to 209°C, then heat preservation is carried out, and the pressure is maintained. The pressure maintenance time is 7...

Embodiment 2

[0045] The poplar wood steam explosion liquid hemicellulose-based hydrogel described in this embodiment is a three-dimensional network structure polymer formed by graft copolymerization of hemicellulose in the poplar wood steam explosion liquid with acrylamide and acrylic acid. The mass ratio of cellulose, acrylamide and acrylic acid is 1:1.4:3.

[0046] The preparation method of the poplar steam explosion liquid hemicellulose-based hydrogel described in the present embodiment is as follows:

[0047] S1. Immerse the poplar wood in a sealed bag with distilled water for rehydration balance, control the water content at about 35%, put it in a refrigerator at 6°C, and balance it for 48 hours; put the rehydrated and balanced poplar wood chips into the high pressure reaction In the autoclave, steam is introduced into the autoclave first, so that the temperature rises to 209°C, then heat preservation is carried out, and the pressure is maintained. The pressure maintenance time is 7 m...

Embodiment 3

[0053] The poplar wood steam explosion liquid hemicellulose-based hydrogel described in this embodiment is a three-dimensional network structure polymer formed by graft copolymerization of hemicellulose in the poplar wood steam explosion liquid with acrylamide and acrylic acid. The mass ratio of cellulose, acrylamide and acrylic acid is 1:1:4.

[0054] The preparation method of the poplar steam explosion liquid hemicellulose-based hydrogel described in the present embodiment is as follows:

[0055] S1. Immerse the poplar wood in a sealed bag with distilled water for rehydration balance, control the water content at about 35%, put it in a refrigerator at 6°C, and balance it for 48 hours; put the rehydrated and balanced poplar wood chips into the high pressure reaction In the autoclave, steam is introduced into the autoclave first, so that the temperature rises to 209°C, then heat preservation is carried out, and the pressure is maintained. The pressure maintenance time is 7 min...

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Abstract

The invention provides poplar steam blasting liquid hemicellulose-based hydrogel and a preparation method thereof. The poplar steam blasting liquid hemicellulose-based hydrogel is a three-dimensional network structural polymer formed by graft copolymerization of hemicellulose in a poplar steam blasting liquid, acrylamide and acrylic acid, wherein the poplar steam blasting liquid is obtained by steam blasting of poplar. According to the poplar steam blasting liquid hemicellulose-based hydrogel and the preparation method thereof provided by the invention, the hydrogel uses the hemicellulose in the poplar steam blasting liquid as a main body, the starting preparation material has a wide source, the environmental protection performance is high, the preparation method of the hydrogel is simple and has high practicability, and the obtained hydrogel has excellent water retention performance.

Description

technical field [0001] The invention belongs to the technical field of hydrogel preparation, and in particular relates to a poplar wood steam explosion liquid hemicellulose-based hydrogel and a preparation method thereof. Background technique [0002] Hydrogel is a kind of hydrophilic network polymer swelling body that can swell in water, absorb and retain a large amount of water, and will not dissolve in water. There are hydrophilic groups on its main chain or side chain. After swelling A portion of water can form hydrogen bonds with these hydrophilic groups, thereby retaining a large amount of water. Due to its functional properties such as water retention and thickening, hydrogels have been widely used in various industries in recent years. [0003] The acquisition and preparation of hydrogels are mainly divided into two categories from the source of materials: one is synthetic hydrogels based on petroleum sources, such as polyacrylic acid and its ester series hydrogels,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F251/00C08F220/56C08F220/06C08F222/38C08J3/075
CPCC08F251/00C08J3/075C08F220/56C08F220/06C08F222/385
Inventor 刘忠惠岚峰马兰王慧梅郑续
Owner TIANJIN UNIV OF SCI & TECH
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