Dihydroagarwood furan-type sesquiterpenes and their preparation and application
A kind of dihydro agarwood and furan type technology, applied in the field of medicine, can solve the problems such as patents or literature reports that have not yet been seen
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Embodiment 1
[0065] Embodiment 1: the preparation of formula compound 1-15
[0066] Take 30 kg of dried Tripterygium wilfordii leaves and extract them three times with ethanol with a volume concentration of 75%. The extraction adopts heating reflux extraction or ultrasonic extraction. Combine all the extracts, concentrate under reduced pressure, recover the solvent, and dry to obtain the extract after completing the concentration under reduced pressure. Sequentially extracted with ethyl acetate and n-butanol, the ethyl acetate layer was subjected to gel column chromatography, petroleum ether-EtOAc mixed system (100:1, 30:1, 15:1 and 10:1, 1:1, v / v ) was eluted to obtain fractions A-D, and fraction C was eluted through cross-linked dextran LH-20 column and ODS gel column to obtain 5 main fractions C1-C5, and C2 (9.5g) was chromatographically separated on a silica gel column , eluted with a petroleum ether-ethyl acetate gradient (25:1 to 1:1) to obtain 8 subfractions (Fr.C2-1 to Fr.C2-8). ...
Embodiment 2
[0067] Example 2: Anti-inflammatory activity of compounds against lipopolysaccharide induction
[0068] 1. Experimental materials
[0069] 1.1 Experimental reagents: Compound 1-15 mouse mononuclear macrophage RAW 264.7 (ATCCTib-71) was purchased from the Chinese Academy of Sciences. RPMI 1640 medium, penicillin, streptomycin and fetal bovine serum were purchased from Invitrogen, USA. Lipopolysaccharide (LPS), dimethylsulfoxide (DMSO) and hydrocortisone were purchased from Sigma.
[0070] 2 test process
[0071] 2.1 Cell culture and treatment
[0072] RAW 264.7 cells were cultured in RPMI 1640 medium containing penicillin (100U / ml), streptomycin (100g / ml) and 10% heat-inactivated fetal bovine serum (5% CO2 and 95% air), every two days on average Change medium once. 264.7 cells were trypsinized to confluence and assayed during exponential growth. Compounds 1-15 were dissolved in dimethyl sulfoxide (DMSO) at the cell culture level and added to the culture medium to obtain a ...
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