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Superhydrophobic particles for surface layer water storage and preparation method thereof

A super-hydrophobic, surface layer technology, applied in botanical equipment and methods, chemical instruments and methods, applications, etc., can solve the problem of poor bonding performance of silane coupling agents, easy adhesion on the surface, easy peeling off of calcium stearate, Migration and other issues, to achieve broad application prospects, the effect of simple preparation process

Inactive Publication Date: 2019-10-08
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the silane coupling agent has poor bonding performance and cannot firmly adhere calcium stearate to the sand surface, and the heat resistance of stearic acid is not good. When it is used for a long time, the calcium stearate on the surface is easy to fall off. Migrate, and then lose the hydrophobic function, and pollute the surrounding soil and water source environment at the same time
Therefore, the breathable anti-seepage sand has problems such as poor hydrophobic effect, easy adhesion on the surface, and poor durability.

Method used

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  • Superhydrophobic particles for surface layer water storage and preparation method thereof
  • Superhydrophobic particles for surface layer water storage and preparation method thereof
  • Superhydrophobic particles for surface layer water storage and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Heat 94 parts of quartz sand with a particle size of 0.2-0.4mm to 200°C, remove the moisture on the surface, and let it stand; when it is cooled to 70°C, add it to the stirring pot, and add 4 parts of fluorine modified Stir the silicone resin and 0.4 parts of m-phenylenediamine evenly; then add 1.2 parts of polytetrafluoroethylene micropowder with a particle size of 5-70um and 0.4 parts of nano-SiO with a particle size of 5-80nm 2 and stir evenly to prepare the superhydrophobic particles used for water storage in the surface layer.

[0030] Lay 1.5cm thick super-hydrophobic particles at a depth of 15cm under the sandy soil, plant 20g of rhododendron seeds in the sandy soil, and set the sandy soil without super-hydrophobic particles as the control group. After the seeds are sown, water every half a month 1 water, observe its survival rate. After 3 months, the survival rate of rhododendrons on the sandy soil with super-hydrophobic particles was 92%, while the survival ra...

Embodiment 2

[0032] Heat 92 parts of tailings with a particle size of 0.1-0.3mm to 180°C, remove the moisture on the surface, and let it stand still; when it cools to 60°C, add it to the stirring pot, and add 4 parts of polymethyl Silicone resin and 0.8 parts of hexamethylenediamine are stirred evenly; then 2.6 parts of polyorganosilicon powder water-repellent with a particle size of 5-70um and 0.6 parts of nano-CuO with a particle size of 5-80nm are sequentially added, and stirred evenly to obtain The superhydrophobic particles used for surface water storage.

[0033] Lay 2cm thick super-hydrophobic particles at a depth of 20cm under the sandy soil, plant 20g rose seeds in the sandy soil, and set the sandy soil without super-hydrophobic particles as the control group. Second water, observe its survival rate. After 3 months, the survival rate of roses on the sandy soil with super-hydrophobic particles was 90%, while the survival rate of roses on the sandy soil without super-hydrophobic pa...

Embodiment 3

[0035] Heat 90 parts of fly ash with a particle size of 0.08-0.2mm to 150°C, remove the moisture on the surface, and let it stand still; when it is cooled to 50°C, add it to the stirring pot, and add 6 parts of acrylic resin Stir well with 1 part of pyridine; then add 2 parts of polyvinylidene fluoride micropowder with a particle size of 5-70um and 1 part of nano-TiO with a particle size of 5-80nm 2 and stir evenly, that is, the superhydrophobic particles for surface water storage are prepared.

[0036] Lay 1cm-thick super-hydrophobic particles at a depth of 15cm under the sandy soil, plant 20g of jasmine seeds in the sandy soil, and set the sandy soil without super-hydrophobic particles as the control group. After the seeds are sown, water once every half a month Water, observe its survival rate. After 3 months, the survival rate of jasmine was 95% in the sandy soil with super-hydrophobic particles, and 0 in the sandy soil without super-hydrophobic particles.

[0037] Simul...

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Abstract

The invention relates to superhydrophobic particles for surface layer water storage and a preparation method thereof. The superhydrophobic particles comprise particle cores and hydrophobic films covering the particle cores. Micro-nano double-level rough structures formed by micron-scale materials and a nano-scale material are created on the surfaces of the hydrophobic films. The hydrophobic filmsare obtained by crosslinking and curing hydrophobic resin and a corresponding curing agent on the surfaces of the particle cores. The superhydrophobic particles comprise, by weight, 90-94 parts of theparticle cores, 4-6 parts of the hydrophobic resin, 0.5-1 part of the curing agent, 1.2-3 parts of the micron-scale materials and 0.4-1 part of the nano-scale material. Compared with the prior art, the superhydrophobic particles and the preparation method thereof have the advantages that the problems, such as low water resource utilization rate and proneness to leakage, in a vegetation planting process are solved, and the utilization rate of water resources and the survival rate of plants are remarkably increased; the preparation and construction process is simple, and the superhydrophobic particles have a very broad application prospect.

Description

technical field [0001] The invention relates to the field of ecological environment, in particular to a superhydrophobic particle used for water storage on the ground surface and a preparation method thereof. Background technique [0002] Land desertification is one of the most serious problems of resources and ecological environment in the world. It is also an important economic and social problem in the world, and it is an important reflection of the serious degradation of the fragile ecological environment. An effective way to control desertification is to increase vegetation coverage to achieve the purpose of water conservation and water and soil conservation. However, the problems of vegetation construction in sandy and arid areas are: water resources are scarce; irrigation water diversion and water delivery are more difficult; the high leakage and high evaporation of soil in sandy and arid areas lead to low effective utilization of water resources, thus resulting in sa...

Claims

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Application Information

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IPC IPC(8): C09K17/40A01G24/10A01G24/50C09K101/00
CPCA01G24/10A01G24/50C09K17/40C09K2101/00
Inventor 张雄张恒
Owner TONGJI UNIV