Corrosion detection electrode in conductive concrete environment, preparation method of corrosion detection electrode in conductive concrete environment and corrosion detection method in conductive concrete environment

A conductive concrete and corrosion detection technology, which is applied in the direction of measuring devices, manufacturing tools, metal processing equipment, etc., can solve the problems of electrolyte infiltration into gaps, affecting test results, and difficult removal of electrodes, and achieves good isolation effect and simple preparation method Effect

Active Publication Date: 2019-10-15
STATE GRID JIANGXI ELECTRIC POWER CO LTD RES INST +3
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] At present, the electrochemical test and mechanism research in the concrete environment are mainly carried out in the following ways: (1) The test metal material is sealed with epoxy resin to prepare a working electrode, and placed in the simulated pore fluid of concrete for electrochemical test. Due to the particularity of the physical and chemical properties of concrete structures, the corrosion data obtained in the concrete pore simulation solution are often quite different from the actual corrosion conditions, making it difficult to accurately study the corrosion mechanism of materials in concrete environments
(2) Place the working electrode, auxiliary electrode and reference electrode of the electrochemical test inside the concrete test block for electrochemical test. The disadvantage of th...

Method used

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  • Corrosion detection electrode in conductive concrete environment, preparation method of corrosion detection electrode in conductive concrete environment and corrosion detection method in conductive concrete environment
  • Corrosion detection electrode in conductive concrete environment, preparation method of corrosion detection electrode in conductive concrete environment and corrosion detection method in conductive concrete environment
  • Corrosion detection electrode in conductive concrete environment, preparation method of corrosion detection electrode in conductive concrete environment and corrosion detection method in conductive concrete environment

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Embodiment 1

[0036] This embodiment combines Figure 1-3, first process a cylindrical carbon steel metal sample 4 with a diameter of Φ12 mm and a length of 10 mm by wire cutting, place the carbon steel metal sample 4 in a hot mounting machine, add bakelite powder that has submerged the sample for about 15 mm, Set the heating temperature to 135° C. and the holding time for 15 minutes to obtain a sample wrapped with the thermal mosaic layer 5 . Then use 80-mesh coarse sandpaper to grind the upper and lower end surfaces of the sample wrapped with the thermal mosaic layer 5, exposing the working surface and welding surface of the metal to be tested respectively. The copper wire 1 with a rubber protective sheath is welded on the welding surface by spot welding, and the working surface is further polished step by step with metallographic sandpaper of 400 mesh to 2000 mesh to obtain a smooth and bright working surface. Take another PVC electrode mold tube 3 with a diameter slightly larger than t...

Embodiment 2

[0038] In this embodiment, the electrochemical test is carried out on the electrode prepared in Example 1. The prepared working electrode is vertically fixed inside the glass container 11, and the auxiliary electrode 8 and the reference electrode 9 are inserted in parallel with the working electrode. The auxiliary electrode 8 is a platinum electrode. , the reference electrode 9 is a calomel electrode, and then 3.5wt% NaCl solution is added as the electrolyte 10 for the electrochemical test, and the electrochemical workstation is connected to the three-electrode system for constant potential polarization, electrochemical impedance spectroscopy and other tests. This example can not only be used to study Cl — Corrosion mechanism of carbon steel in conductive concrete under infiltration. It is also possible to prepare multiple working electrodes by pouring different types of conductive concrete for research, and to evaluate the corrosion resistance of carbon steel in different typ...

Embodiment 3

[0040] This embodiment combines Figure 1-3 , first process a cylindrical carbon steel metal sample 4 with a diameter of Φ15 mm and a length of 15 mm by wire cutting, place the carbon steel metal sample 4 in a hot mounting machine, add bakelite powder that has submerged the sample for about 15 mm, Set the heating temperature to 145° C. and the holding time for 15 minutes to obtain a sample wrapped with the thermal mosaic layer 5 . Then use 80-mesh coarse sandpaper to grind the upper and lower end surfaces of the sample wrapped with the thermal mosaic layer 5, exposing the working surface and welding surface of the metal to be tested respectively. The copper wire 1 with a rubber protective sheath is welded on the welding surface by spot welding, and the working surface is further polished step by step with metallographic sandpaper of 400 mesh to 2000 mesh to obtain a smooth and bright working surface. Take another PVC electrode mold tube 3 with a diameter slightly larger than ...

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Abstract

The invention belongs to the field of corrosion electrochemistry testing, and particularly relates to a corrosion detection electrode in a conductive concrete environment, a preparation method of thecorrosion detection electrode in the conductive concrete environment and a corrosion detection method in the conductive concrete environment. A columnar sample, a hot inlaying layer, an epoxy resin layer, a conductive concrete layer and a wire are all included. In the preparation method, by sample sealing mode of firstly performing hot inlaying and then performing cold inlaying for a test metal, atest surface is enabled to be combined with an inlaying material tightly, a problem that a concrete work electrode is liable to generate gas corrosion in a cement accelerated curing process can be solved, a simple and convenient work electrode preparation method is provided for realizing metal material corrosion electrochemistry detection in the concrete environment, the preparation method not only is suitable for performing corrosion resistance detection for a conductive concrete composite material newly researched and developed on the market, but also can be used for research on electrochemical corrosion mechanism of the metal material in the concrete environment and evaluation on corrosion inhibition performance of an corrosion inhibitor in the internal/external environment of the concrete.

Description

technical field [0001] The invention belongs to the field of corrosion electrochemical testing, in particular to a corrosion detection electrode in a conductive concrete environment and a preparation and detection method. Background technique [0002] Conductive concrete is a coated resistance-reducing material composed of cement, conductive aggregate (such as coke, graphite and carbon fiber, etc.) and water. Widely used in industrial anti-static, power industry disaster prevention and mitigation, power grounding modules, intelligent buildings and other fields. The addition of conductive particles significantly improves the conductivity of concrete, but it also promotes the electrochemical corrosion process of metal materials in concrete, resulting in varying degrees of corrosion or even rusting after a certain service life. Therefore, for the development and use of new conductive concrete, the corrosion resistance detection and corrosion mechanism analysis of metal materia...

Claims

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Application Information

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IPC IPC(8): G01N27/30G01N27/416B24B7/16
CPCB24B7/16G01N27/30G01N27/416
Inventor 田旭裴锋刘欣朱亦晨刘光明贾蕗路李财芳邓辰星
Owner STATE GRID JIANGXI ELECTRIC POWER CO LTD RES INST
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