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Hydrophilic oleophobic adsorption particle for chemical industry

A technology of adsorbing particles, hydrophilic and oleophobic, applied in the chemical industry, can solve the problems of reduced filtration efficiency, abnormal noise in equipment operation, high risk, etc., and achieve good absorption effect, improved stability and high safety

Inactive Publication Date: 2019-10-22
佛山振业润滑材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the field of chemical industry, water ingress in lubricating oil often occurs in chemical equipment. Once water ingress occurs in chemical equipment, it will cause abnormal noise or other problems in the operation of the equipment, and it will also cause poor lubrication effect of chemical equipment. Severe wear between mechanisms or high temperature, resulting in equipment damage
[0003] The traditional method is dehydration by heating and cooking, but for oil products with low flash points such as gasoline, kerosene, diesel and other flammable chemicals, using heating and cooking is likely to cause fire or explosion, and the risk is high. The traditional oil-water separation adopts pro- The oil-hydrophobic material realizes water resistance and oil passage. Compared with water, oil has a higher viscosity, and it is easy to adhere to the filter mesh to block the mesh, which greatly reduces the filtration efficiency. Secondly, the density of water is relatively high, and the water contacts the filter first under the action of gravity. Omentum, it is easy to form a water film on the surface of the omentum, and oil with a lower density can only float on the water film, making the separation unsustainable

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Embodiment 1: the pore size of the hydrophilic and oleophobic layer of the inner layer is 0.5 nanometers, and the inner core of the single-core structure is wrapped inside the double-layer outer skin, and the inner core is a kind of water-absorbing material, and the percentage of each component in the formula of the outer skin: refined bamboo charcoal 60%, alumina microsphere catalyst 15%, fluorocarbon activator 10%, silicate 8%, organic solvent 7%, fluorocarbon activator includes amino, carboxyl, fluorocarbon chain or alkyl chain one or a combination of two or more.

[0021] The percentage of each component in the formula of the inner core: water-absorbing resin 50%, attapulgite adsorbent 20%, alumina microsphere catalyst 20%, cross-linking agent 10%, water-absorbing resin includes polyolefin resin, polyolefin derivative In one or two compositions, the crosslinking agent is allyl methacrylate.

Embodiment 2

[0022] Example 2: The pore size of the hydrophilic and oleophobic layer of the inner layer is 0.5 microns, and the inner core of the double-core structure is wrapped inside the double-layer outer skin. The inner core is made of two kinds of water-absorbing materials, and each water-absorbing material accounts for half of the inner core. 1. Percentage of each component in the skin formula: refined bamboo charcoal 60%, alumina microsphere catalyst 15%, fluorocarbon activator 10%, silicate 8%, organic solvent 7%, fluorocarbon activator including amino , one or a combination of two carboxyl groups.

[0023] The percentage of each component in the formula of the inner core: half of the inner core of the double-core structure is 60% of the water-absorbing resin, 25% of the attapulgite adsorbent, 10% of the alumina microsphere catalyst, and 5% of the cross-linking agent. The water-absorbing resin is For polyamide resins, the crosslinking agent can be ethyl dimethacrylate.

[0024] T...

Embodiment 3

[0025] Embodiment 3: each component percentage in the formula of outer skin: refined bamboo charcoal 60%, alumina microsphere catalyst 15%, fluorocarbon activator 10%, silicate 8%, organic solvent 7%, fluorocarbon activator comprises Contains one or a combination of fluorocarbon chains or alkyl chains.

[0026] The percentage of each component in the formula of the inner core: water-absorbing resin 70%, attapulgite adsorbent 20%, alumina microsphere catalyst 5%, cross-linking agent 5%, water-absorbing resin includes one of propylene or acrylic copolymer A combination of two or two, the crosslinking agent can be trimethylolpropane-tripropionate.

[0027] The particles can have a long strip structure. When in use, the particles can be inserted into the pipeline to absorb the moisture contained in the lubricating oil. Adding a certain amount of alumina microsphere catalyst to the composition of the outer skin and the inner core can improve the adsorption of the particles. stabil...

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Abstract

The invention relates to a hydrophilic oleophobic adsorption particle for the chemical industry. The hydrophilic oleophobic adsorption particle comprises skin and at least one inner core wrapped by the skin, wherein the skin is a hydrophilic oleophobic layer which is synthesized through a bonding reaction of hydrophilic groups with a polar group contained in a fluorocarbon active agent; the skin is of a two-layer structure, an outer hydrophilic oleophobic layer is a of membrane structure, and an inner hydrophilic oleophobic layer is of a porous structure; and the inner core is made of a water-absorbing material. The adsorption particle is put into the lubricating oil, and the skin of the adsorption particle can isolate oil and permits permeation of water; and water that has entered the adsorption particle through the skin is adsorbed by the inner core.

Description

technical field [0001] The invention relates to the field of chemical industry, in particular to a hydrophilic and oleophobic adsorption particle for chemical industry. Background technique [0002] In the field of chemical industry, water ingress in lubricating oil often occurs in chemical equipment. Once water ingress occurs in chemical equipment, it will cause abnormal noise or other problems in the operation of the equipment, and it will also cause poor lubrication effect of chemical equipment. Severe wear or high temperature between the mechanisms will cause damage to the equipment. [0003] The traditional method is dehydration by heating and cooking, but for oil products with low flash points such as gasoline, kerosene, diesel and other flammable chemicals, using heating and cooking is likely to cause fire or explosion, and the risk is high. The traditional oil-water separation adopts pro- The oil-hydrophobic material realizes water resistance and oil passage. Compar...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D17/022B01D15/08B01J20/26B01J20/28
CPCB01D15/08B01D17/0202B01J20/08B01J20/10B01J20/12B01J20/20B01J20/22B01J20/264B01J20/28016
Inventor 徐龙生
Owner 佛山振业润滑材料有限公司
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