Elastomer for railway cushion block of rail transit and preparation method thereof
A rail transit and elastomer technology, applied in the field of rail transit polymer materials, can solve the problems of poor mechanical properties, shortened service life, short service life, etc., and achieve the effect of being conducive to uniform dispersion, overall performance improvement, and broad application prospects.
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Embodiment 1
[0057] I. Preparation of polyester polyol / nano-silica hybrid material
[0058] Add 8g of N-β-(aminoethyl)-γ-aminopropyltrimethoxysilane dropwise to 8.3g of p-phenylene diisocyanate in toluene / ethyl acetate (100ml, volume ratio=4:1) solution; Mechanically stir the reaction at room temperature for 1.5h, then add 141g polypropylene malonate, 0.45g stannous octoate, heat to 70~72°C and stir the reaction at this temperature for 8h, rotary steam, remove the toluene / ethyl acetate solvent, and prepare Obtain a prepolymer; disperse 10g of nano-silica in 100g of toluene, and ultrasonically 30min to obtain a nano-silica dispersion; then, take 15.2g of the prepolymer, and mix it with 12g of the nano-silica dispersion, 2g Water and 90 g of toluene were mixed, stirred and reacted at 80° C. for 3.5 h, and rotated to evaporate to remove the toluene and water to prepare the polyester polyol / nano-silicon dioxide hybrid material.
[0059] II. Preparation of Elastomers
[0060] Take 36g of p...
Embodiment 2
[0063] I. Preparation of polyester polyol / nano-silica hybrid material
[0064] Add 8.2g of N-β-(aminoethyl)-γ-aminopropyltrimethoxysilane dropwise to 9g of p-phenylene diisocyanate in toluene / ethyl acetate (110ml, volume ratio=4:1) solution; Mechanically stir the reaction at room temperature for 2 hours, then add 150g polybutylene adipate, 0.6g dibutyltin dilaurate, heat to 75~80°C and stir the reaction at this temperature for 8.5 hours, rotary steam to remove toluene / ethyl acetate solvent to obtain a prepolymer; disperse 10g nano silicon dioxide in 100g toluene, and ultrasonically 30min to obtain a nano silicon dioxide dispersion; then, take 23g prepolymer and mix it with 16g of the nano The silicon oxide dispersion, 4 g of water and 100 g of toluene were mixed, stirred and reacted at 85° C. for 3.5 h, and rotated to evaporate to remove the toluene and water, so as to obtain the polyester polyol / nano-silicon dioxide hybrid material.
[0065] II. Preparation of Elastomers...
Embodiment 3
[0069] I. Preparation of polyester polyol / nano-silica hybrid material
[0070] Add 8.6g of N-β-(aminoethyl)-γ-aminopropyltrimethoxysilane dropwise to 10.9g of p-phenylene diisocyanate in toluene / ethyl acetate (120ml, volume ratio=4:1) solution; Mechanically stir the reaction at room temperature for 2.5h, then add 166.4g polybutylene succinate, 0.72g dibutyltin dilaurate, heat to 82~85°C and stir the reaction at this temperature for 8h, rotary steaming, Remove the toluene / ethyl acetate solvent to obtain a prepolymer; disperse 10g of nano-silica in 100g of toluene, and ultrasonicate for 30min to obtain a nano-silica dispersion; then, take 30g of the prepolymer and mix it with 19g of the The nano-silica dispersion liquid, 4g of water and 115g of toluene were mixed, stirred and reacted at 80°C for 5h, and then rotary-evaporated to remove the toluene and water to prepare the polyester polyol / nano-silica hybrid material.
[0071] II. Preparation of Elastomers
[0072] Take 56.3...
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