Ammonia-free low-VOC interior wall emulsion and preparation method thereof

An emulsion and interior wall technology, applied in the coating and other directions, can solve the problems of increasing carbon emissions, unfavorable environment, high energy consumption, etc., and achieve the effects of increasing carbon emissions and energy consumption, reducing VOC, and forming a tight film

Active Publication Date: 2019-11-22
GUANGDONG HENGGUANG CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, for the treatment of low VOC and deodorization of interior wall emulsion, most of them remove unreacted monomers or by-products in the reaction process through extraction or distillation. Although the final reaction product has little smell and low VOC Low, but the energy consumption in the extraction process is too large, which increases carbon emissions
On the other hand, more energy consumption is required to solve the extracted VOC and wastewater, which is not good for the environment

Method used

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  • Ammonia-free low-VOC interior wall emulsion and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Ammonia-free low-VOC interior wall emulsion, each component and content: styrene 220g, butyl acrylate 210g, methacrylic acid 10g, acrylic acid 10g, HEMA-P 70M 10g, EGDMA 4g, SR10 5g, RS-610 5g, Sodium sulfate 10g, water 481g, potassium persulfate 8g, tert-butyl hydroperoxide 12g, sodium ascorbate 15g.

[0036] The above-mentioned ammonia-free and low-VOC interior wall emulsion is prepared by the following method:

[0037] (1) Preparation of the first monomer emulsion: Take 48.3g water, 1.5g SR10 and 1.5g RS-610 in a beaker and stir, then add 154g styrene, 42g butyl acrylate, 5g acrylic acid, 2g methacrylic acid , 0.5g HEMA-P 70M and 0.2g EGDMA are emulsified to prepare the first monomer emulsion for use;

[0038] (2) Preparation of the second monomer emulsion: Take 96.9g water, 2g SR10 and 2g RS-610 in a beaker and stir, then add 66g styrene, 168g butyl acrylate, 5g acrylic acid, 8g methacrylic acid, 9.5 g HEMA-P 70M and 3.8g EGDMA are emulsified to prepare the second monome...

Embodiment 2

[0049] Ammonia-free and low-VOC interior wall emulsion, each component and content: styrene 150g, butyl acrylate 280g, methacrylic acid 5g, acrylic acid 5g, HEMA-P 70M 20g, EGDMA 3g, sodium lauryl sulfate 10g, RS- 710 7g, potassium persulfate 8g, t-butyl hydroperoxide 12g, sodium ascorbate 15g, water 485g.

[0050] The above-mentioned ammonia-free and low-VOC interior wall emulsion is prepared by the following method:

[0051] (1) Preparation of the first monomer emulsion: Take 98.9g of water, 5g of sodium lauryl sulfate and 1.8g of RS-710 in a beaker and stir, then add 120g of styrene, 84g of butyl acrylate, 2.5g of acrylic acid, 2.5g methacrylic acid, 2g HEMA-P 70M and 0.3g EGDMA are emulsified to prepare the first monomer emulsion for use;

[0052] (2) Preparation of the second monomer emulsion: Take 101.5g of water, 5g of sodium lauryl sulfate and 1.8g of RS-710 in a beaker and stir, then add 30g of styrene, 196g of butyl acrylate, 2.5g of acrylic acid, 2.5g methacrylic acid, 1...

Embodiment 3

[0063] Ammonia-free low-VOC interior wall emulsion, each component and content: styrene 300g, butyl acrylate 130g, methacrylic acid 7g, acrylic acid 5g, sodium lauryl sulfate 10g, RS-6107g, potassium persulfate 8g, tertiary 17 g of butyl hydroperoxide, 13 g of sodium ascorbate, 20 g of HEMA-P 70M, 5 g of diethylene glycol dimethacrylate, and 478 g of water.

[0064] The above-mentioned ammonia-free and low-VOC interior wall emulsion is prepared by the following method:

[0065] (1) Preparation of the first monomer emulsion: Take 52.5g of water, 4.1g of sodium lauryl sulfate and 1g of RS-610 in a beaker and stir, then add 210g of styrene, 26g of butyl acrylate, and 2.5g of acrylic acid , 1.4g methacrylic acid, 2g HEMA-P70M and 0.5g diethylene glycol dimethacrylate for emulsification to prepare the first monomer emulsion for use;

[0066] (2) Preparation of the second monomer emulsion: Take 100.3g of water, 4.1g of sodium lauryl sulfate and 1g of RS-610 in a beaker and stir, then add ...

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Abstract

The invention relates to an ammonia-free low-VOC interior wall emulsion and a preparation method thereof. The invention belongs to the technical field of building coatings. The emulsion is prepared from the following components in percentage by mass: 30-55% of water, 0.5%-3% of an emulsifier, 0.1%-3% of persulfate, 0.1%-3% of tert-butyl hydroperoxide, 0.1%-3% of a reducing agent, 10%-60% of styrene, 5%-30% of butyl acrylate, 0.5%-3% of acrylic acid, 0.5%-3% of methacrylic acid, 0.1%-6% of a functional monomer I and 0.1%-6% of a functional monomer II, wherein the functional monomer I is 2-methacryloyloxyethyl phosphate, and the functional monomer II is one or a mixture of more than two of ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, 1, 3-butanediol dimethacrylate, 1, 4-butanediol dimethacrylate and allyl methacrylate. The interior wall emulsion has the advantages of no ammonia, low VOC, effective improvement of the smell, low energy consumption, consideration of theglass transition temperature and the lowest film forming temperature, and improvement of the scrubbing resistance and other performances of the emulsion.

Description

Technical field [0001] The invention belongs to the technical field of architectural coatings, and relates to an interior wall coating, in particular to an ammonia-free low-VOC interior wall emulsion and a preparation method thereof. Background technique [0002] In recent years, environmental protection issues have become the focus of people’s attention. Interior wall paints are directly applied to the inner surface of buildings or structures, which are more closely related to people’s lives or work, so the requirements are more stringent, except for the key to wall paint. Environmental protection indicators: VOC, free formaldehyde, heavy metals, and appropriate water resistance, alkali resistance and scrub resistance. Among them, the treatment of low VOC and clean odor for interior wall emulsions is mostly through extraction or distillation to remove unreacted monomers or by-products in the reaction process, although the final reaction product has very little taste and high VOC...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F212/08C08F220/18C08F220/06C08F230/02C08F222/14C08F220/40C08F4/40C08F4/34C08F4/30C09D125/14C09D133/08
CPCC08F212/08C08F4/40C08F4/34C08F4/30C09D125/14C09D143/02
Inventor 郝丽娟曹威徐文通田海水高昊闫树德朱美娟田军
Owner GUANGDONG HENGGUANG CHEM CO LTD
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