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Dielectric composite with reinforced elastomer and integrated electrode

A composite and elastomer layer technology, applied in the direction of carbon-silicon compound conductors, conductive layers on insulating carriers, household appliances, etc., can solve problems such as difficult to operate, difficult to manufacture, and less than ideal batch processing technology

Active Publication Date: 2019-11-22
W L GORE & ASSOC GMBH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Such elastomers are often difficult to manufacture and not easy to handle in roll-to-roll processing
Therefore, these materials may require the use of less than optimal batch processing techniques

Method used

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  • Dielectric composite with reinforced elastomer and integrated electrode
  • Dielectric composite with reinforced elastomer and integrated electrode
  • Dielectric composite with reinforced elastomer and integrated electrode

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] Expanded polytetrafluoroethylene (ePTFE) membranes were prepared generally according to the teachings of US Patent No. 7,306,729 to Bacino et al. The average mass / area of ​​ePTFE membrane is 0.5g / m 2 , with an average thickness of about 0.6 μm. The ePTFE membrane was compacted in the transverse direction (TD) as described in Example 4A of EP3061598A1 to Zaggl et al. At room temperature (about 20° C.) and a speed setting of 2 m / min, the processing rate was 100%. The modulus test was carried out using a Zwick Roell Z005 tensile tester (Georgia, USA) with the following parameters: the measuring speed was 508 mm / min, the clamping length was 82.55 mm, and the sample width was 6 mm. After processing, the modulus of the ePTFE membrane on the TD decreased significantly, as Figure 15 and shown in Table 1.

[0049] Table 1

[0050]

[0051] Prior to coating, the compacted porous ePTFE membrane was positioned on a polyethylene terephthalate (PET) release layer ( RNK 50, ...

Embodiment 2

[0057] The ePTFE membrane was prepared generally according to the teachings of US Patent No. 7,306,729 to Bacino et al. The average mass / area of ​​ePTFE membrane is 0.5g / m 2 , with an average thickness of about 0.6 μm.

[0058] Mount the ePTFE membrane in a metal frame with an inner diameter of 5 cm. Using a Model 108 Automatic Gressington (Gressington) sputter coater (Cressington Scientific Instruments UK, Watford, UK) with parameters of 10 mA and 20 seconds, a sufficient amount of platinum Deposited on the surface of the ePTFE membrane to form a conductive layer.

[0059] Remove the metallized ePTFE membrane from the frame and position it on the stretched silicone sheet. The ePTFE / silicone sheets were biaxially compacted relative to the pristine material as described in EP3061598A1 by Zaggl et al. The processing rate was set at 25% biaxial compaction. Metallized compacted porous ePTFE membranes were placed on polyethylene terephthalate with pressure sensitive acrylic ad...

Embodiment 3

[0063] The ePTFE membrane was prepared generally according to the teachings of US Patent No. 7,306,729 to Bacino et al. The average mass / area of ​​ePTFE membrane is 0.5g / m 2 , with an average thickness of about 0.6 μm. The ePTFE membrane was compacted in the transverse direction of the original material as described in Example 4A of EP3061598 Al to Zaggl et al. At 20° C. and a speed setting of 2 m / min, the processing rate was 100%.

[0064] The compacted porous ePTFE membrane was lightly pressed with a rubber roller onto the acrylic tape on a Kraft release liner (VHB) (type VHB 9460 (3M Deutschland GmbH, Neuss, Germany)) with a thickness of 50 μm , to apply one layer of VHB tape on one side of the ePTFE membrane. Apply a second layer of VHB tape on the other side of the compacted porous ePTFE membrane in the same manner. Gently remove the kraft paper release liner to obtain 3 The strength of the compacted porous ePTFE membrane is favorable so that the fragile 3-layer compos...

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Abstract

The present disclosure is directed to dielectric elastomeric composites that include a retainable processing membrane, an elastomer material, and an electrically conductive material. The elastomer layer may be partially imbibed into the retainable processing membrane. The retainable processing membrane may be porous. The retainable processing membrane is compacted in the transverse direction, machine direction, or in both directions prior to the application of an elastomer material and an electrically conductive material. The compaction of the retainable processing membrane may form structuredfolds or folded fibrils in the membrane, giving the retainable processing membrane a low modulus and flexibility. In some embodiments, the dielectric composites are positioned in a stacked configuration. Alternatively, the dielectric elastomeric composites may have a wound configuration. The dielectric composites have a total thickness less than about 170 microns. The dielectric elastomeric composites may be used, for example, in dielectric elastomer actuators, sensors, and in energy harvesting.

Description

technical field [0001] The present disclosure relates generally to dielectric composites, and more particularly, to dielectric elastomer composites having integrated electrodes, elastomeric materials, and retentive processing layers. Background technique [0002] Dielectric elastomer actuators (DEAs) have potential in various applications. However, technical challenges still need to be overcome before a reliable product can be produced commercially. One challenge is to produce thin elastomeric films (eg, 100 μm thick or less) for DEA applications with driving voltages significantly below 2000 volts, or even below 600 volts. To achieve such voltages, elastomeric films with thicknesses less than 50 μm need to be reliably fabricated without defects and able to be manipulated downstream. Such elastomers are often difficult to manufacture and not easy to handle in roll-to-roll processing. Therefore, these materials may require the use of less than optimal batch processing tech...

Claims

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Application Information

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IPC IPC(8): B32B1/08B32B15/06B32B15/20B32B5/16B32B25/12B32B25/14B32B25/16B32B25/18B32B25/20B32B29/04B32B27/32
CPCB32B5/16B32B15/06B32B15/20B32B25/12B32B25/14B32B25/16B32B25/18B32B25/20B32B27/322B32B29/04B32B1/08B32B2250/03B32B2250/05B32B2255/04B32B2255/10B32B2255/205B32B2260/025B32B2260/048B32B2264/108B32B2307/202B32B2307/204B32B2307/732B32B2457/00B32B27/32B32B2250/02B32B2255/28B32B27/285B32B2307/54B32B27/08B32B2307/582B32B5/245B32B2250/20B32B2255/26B32B27/304B32B5/022B32B2250/22B32B5/32B32B2457/20B32B2266/025B32B2255/102B32B3/26B32B27/065B32B2307/706B32B2255/20B32B2260/021B32B2255/02B32B2307/546B32B2260/02B32B2605/00B32B5/26B32B27/12B32B27/30B32B27/306B32B2250/24B32B5/18H01B5/14H01B1/02H01B1/04C08J9/42C08J2327/18B32B25/08B32B27/40B32B2264/105
Inventor A·德诺佛M·瑞特曼K·赛伯特A·扎吉
Owner W L GORE & ASSOC GMBH
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