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A device and method for producing biogasoline and diesel by pyrolysis of biomass

A technology for biomass pyrolysis and diesel oil, which is applied to diesel devices and the field of biomass pyrolysis to prepare gasoline, which can solve the problems of restricting the industrialization process, high reaction temperature, high viscosity, etc.

Active Publication Date: 2021-07-06
青岛捷天电气设备有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Because a high reaction temperature is required and a large amount of heat is consumed, the energy cost of biomass pyrolysis is relatively high, which limits its industrialization process
In addition, the resulting bio-oil has a complex composition, high oxygen content (35-60wt%), high viscosity (20-200mPa·s at 40°C), high acid value (pH 2-4), low calorific value (14-19MJ / kg) and other characteristics, there are defects in direct use as an alternative vehicle fuel, so subsequent refining is required to produce fuel oil that meets the requirements of vehicles

Method used

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  • A device and method for producing biogasoline and diesel by pyrolysis of biomass
  • A device and method for producing biogasoline and diesel by pyrolysis of biomass
  • A device and method for producing biogasoline and diesel by pyrolysis of biomass

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] This embodiment refers to the attached figure 1 As shown, it is the reaction device for rapid heating of biomass provided by this application.

[0054] The reaction device in this embodiment includes catalyst regenerator IV, biomass pyrolysis reactor III, upgrading reactor (also referred to as catalytic cracking reaction device), condenser V, oil and gas separation tank VI, fractionation tower V . The biomass pyrolysis reactor III is placed in the catalyst regenerator IV through the bottom of the catalyst regenerator. The pyrolysis reactor III is a cylindrical straight pipe, and the upper end of the pyrolysis reactor III is located at the upper part of the catalyst regenerator IV.

[0055] The upper end of the biomass pyrolysis reactor III is connected to the cyclone separator 14, and the pyrolysis gas and coke in the biomass pyrolysis product are separated in the cyclone separator. The top outlet of the cyclone separator is connected to the condenser VII, and the pyr...

experiment example 1

[0062] This experimental example adopts the reaction device for rapid heating of biomass in Example 1, uses pine wood sawdust as raw material, fixed fluidized bed pyrolysis reactor, the fluidization gas is nitrogen, and the reaction time is 20s. The obtained product distribution and pyrolysis oil The properties are shown in Table 1 and Table 2.

[0063] Table 1 Distribution of pyrolysis products

[0064]

[0065] Table 2 Properties of pyrolysis oil

[0066]

[0067]

[0068] The above-mentioned pyrolysis oil (PO) obtained at 510°C was used for catalytic cracking upgrading. Catalytic cracking upgrading uses a fixed bed reactor, the reaction temperature is 500 ° C, and two industrial catalytic cracking balancers with USY and ZSM-5 as active components are used as catalysts respectively, and the weight hourly space velocity is 12h -1 , the product distribution is shown in Table 3.

[0069] Table 3 Distribution of catalytic cracking products of pyrolysis oil

[0070] ...

experiment example 2

[0072] This experimental example adopts the reaction device for rapid heating of biomass in Example 1, uses rice husk as raw material, fixed fluidized bed pyrolysis reactor, fluidization gas is nitrogen, and the reaction time is 20s. The obtained product distribution and pyrolysis oil The properties are shown in Table 4 and Table 5.

[0073] Table 4 Distribution of pyrolysis products

[0074]

[0075]

[0076] Table 5 Properties of pyrolysis oil

[0077]

[0078] The above-mentioned pyrolysis oil (PO) obtained at 510°C was used for catalytic cracking upgrading. Catalytic cracking upgrading uses a fixed bed reactor, the reaction temperature is 500 ° C, and two industrial catalytic cracking balancers with USY and ZSM-5 as active components are used as catalysts respectively, and the weight hourly space velocity is 12h -1 , the product distribution is shown in Table 6.

[0079] Table 6 Distribution of pyrolysis oil catalytic cracking products

[0080]

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Abstract

A reaction device for producing gasoline and diesel by pyrolysis of biomass comprises a biomass pyrolysis reactor, a upgrading reactor and a catalyst regenerator, wherein the biomass pyrolysis reactor is placed inside the catalyst regenerator. The biomass pyrolysis reactor is placed in the catalyst regenerator. During the reaction process, the biochar generated by itself and the coke generated during the upgrading process are used to provide heat, which fully utilizes the heat of the charred catalyst to reduce energy consumption. In the biomass pyrolysis process, no heat carrier is added, which reduces its separation from the reaction product and wear of the reactor.

Description

technical field [0001] The invention relates to a reaction device for pyrolysis of biomass, in particular to a device and method for preparing gasoline and diesel by pyrolysis of biomass. Background technique [0002] Energy is an important material basis for ensuring the progress of human society and an important support for national economic development. It is closely related to human life and production, and plays an indispensable and important role in promoting social progress and economic development. With the rapid development of the economy, fossil energy is becoming increasingly exhausted, and the supply of petroleum resources is becoming more serious. At the same time, fossil fuels have brought severe environmental problems. Facing the current situation of energy crisis and environmental pollution, promoting the revolution of energy production and consumption, and promoting the transformation of economic development model to green and low-carbon are not only the int...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G1/00C10G1/08
CPCC10G1/002C10G1/086C10G2300/1011C10G2400/02C10G2400/04
Inventor 刘熠斌陈小博冯翔杨朝合
Owner 青岛捷天电气设备有限公司