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Preparation method of waterborne release agent for polyurethane foam demolding

A polyurethane foam and release agent technology, applied in the field of release agent preparation, can solve the problems of poor release effect, affecting the surface quality of foam, and easy residue on the surface of the mold, so as to achieve the effect of easy falling off and improved release effect

Inactive Publication Date: 2019-12-06
刘群艳
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The technical problem mainly solved by the present invention is that when the common water-based release agent is used for polyurethane foam demoulding, the release agent is difficult to evenly disperse on the surface of the mold, and it is easy to remain on the surface of the mold after demoulding, and it is easy to tear the polyurethane foam skin , affecting the surface quality of the foam and poor demoulding effect, a preparation method of a water-based mold release agent for polyurethane foam demoulding is provided

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Preparation of self-made water-soluble functional substances:

[0031]Mix soybean oil and lipase at a mass ratio of 10:1, put them into an enzymolysis tank, and perform enzymolysis at 35°C for 6 hours to obtain an enzymolysis product. The enzymolysis product and methanol solution with a mass fraction of 70% After mixing at a ratio of 1:1, put it into the reaction kettle, heat up to 60°C, stir and react for 1 hour, and obtain the reactant;

[0032] The above reaction product was put into a hydrogenation reactor, and hydrogen was introduced into the reactor to replace the air. After the replacement was completed, the reactor was sealed and reacted for 4 hours at a pressure of 11 MPa and a temperature of 250° C. to obtain a reaction product;

[0033] Move the above reaction product into the reaction kettle, then add alumina with a reaction product mass of 0.5% in the reaction kettle, and feed an equal volume ratio mixture of nitrogen and ethylene oxide into the reaction ke...

Embodiment 2

[0040] Preparation of self-made water-soluble functional substances:

[0041] Mix soybean oil and lipase at a mass ratio of 10:1, put them into an enzymolysis tank, and perform enzymolysis at 40°C for 7 hours to obtain an enzymolysis product. After mixing at a ratio of 1:1, put it into the reaction kettle, heat up to 65°C, stir and react for 1.5h, and obtain the reactant;

[0042] Put the above reaction product into a hydrogenation reaction kettle, and pass hydrogen into the reaction kettle to replace the air. After the replacement is completed, seal the reaction kettle and react for 4.5 hours under the conditions of a pressure of 12MPa and a temperature of 260°C to obtain the reaction product ;

[0043] Move the above reaction product into the reaction kettle, then add alumina with a reaction product mass of 0.5% in the reaction kettle, and feed an equal volume ratio mixture of nitrogen and ethylene oxide into the reaction kettle until the pressure in the reaction kettle rea...

Embodiment 3

[0050] Preparation of self-made water-soluble functional substances:

[0051] Mix soybean oil and lipase at a mass ratio of 10:1, put them into an enzymolysis tank, and perform enzymolysis at 45°C for 8 hours to obtain an enzymolysis product. After mixing at a ratio of 1:1, put it into the reaction kettle, heat up to 70°C, stir and react for 2 hours, and obtain the reactant;

[0052] The above reaction product was put into a hydrogenation reactor, and hydrogen was introduced into the reactor to replace the air. After the replacement was completed, the reactor was sealed and reacted for 5 hours at a pressure of 13 MPa and a temperature of 270° C. to obtain a reaction product;

[0053] Move the above reaction product into the reaction kettle, then add alumina with a reaction product mass of 0.5% in the reaction kettle, and feed an equal volume ratio mixture of nitrogen and ethylene oxide into the reaction kettle until the pressure in the reaction kettle reaches 0.4MPa, heat up ...

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Abstract

The invention discloses a preparation method of a waterborne release agent for polyurethane foam demolding, and belongs to the technical field of preparation of release agents. The preparation methodcomprises the following steps that soybean oil is taken as a raw material, lipase is used for carrying out enzymolysis on the soybean oil, then esterification reaction is carried out on enzymatic hydrolysate and methanol, hydrogenation reaction is carried out on esterification reaction product to prepare fatty alcohol, oxyethylene reaction is carried out on the fatty alcohol, then esterification is carried out, a water-soluble phosphate product is finally prepared, activated clay bentonite is taken as a raw material, dipping and adsorbing are carried out on the raw material with castor oil, then alkali is added for saponification to obtain modified bentonite, and finally the water-soluble phosphate product, the modified bentonite, a stabilizer and water are mixed and stirred to obtain thewaterborne release agent for the polyurethane foam demolding.

Description

technical field [0001] The invention discloses a preparation method of a polyurethane foam release water-based release agent, which belongs to the technical field of release agent preparation. Background technique [0002] Polyurethane is an important polymer synthetic material. Due to its diversity of raw materials and proportions, it has unique properties and wide application. Polyurethane foam is the most important variety of polyurethane products, and its output accounts for more than half of the entire polyurethane products. Usually, during the molding process of polyurethane foam plastic products, the mold materials used are generally high thermal conductivity materials, such as aluminum, steel, etc., because the isocyanate component in the polyurethane foam raw material has cohesiveness, it will form a strong bond with the metal. Therefore, it is necessary to use a suitable release agent to prevent the polyurethane foam product from bonding to the mold, to prevent th...

Claims

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Application Information

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IPC IPC(8): B29C33/60
CPCB29C33/60
Inventor 刘群艳
Owner 刘群艳