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A preparation method of a segmented National VI natural gas equivalence ratio catalyst

A natural gas and equivalent ratio technology, which is applied in the preparation of segmented National VI natural gas equivalent ratio catalysts and the preparation of natural gas equivalent ratio catalysts, can solve the problem of inability to improve catalyst performance, low utilization rate of precious metals, and complicated coating processes. and other problems, to achieve the effect of reducing poisoning effect, widening air-fuel ratio window, improving catalyst performance and durability

Active Publication Date: 2022-06-24
WUXI WEIFU ENVIRONMENT PROTECTION CATALYST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Such a simple coating will lead to uneven distribution of precious metals, low utilization of precious metals, and the ability to improve the conversion rate of pollutants cannot be achieved.
[0005] Patent Document 1: Chinese Patent Publication No. CN 102513165 A, announced on June 27, 2012, titled 'A High-Efficiency Exhaust Gas Purification Three-way Catalyst Coating Method' discloses a new high-efficiency exhaust gas purification three-way catalyst coating method method, wherein the coating layer involved has many layers, and the coating method is relatively complicated, which will lead to the complexity of the coating process and the increase of production cost
In addition, this patent does not involve the coating distribution of precious metals, so it will not be able to explain the improvement of catalyst performance and other aspects

Method used

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  • A preparation method of a segmented National VI natural gas equivalence ratio catalyst
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  • A preparation method of a segmented National VI natural gas equivalence ratio catalyst

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preparation example Construction

[0030] Preparation of A catalyst

[0031] Using the catalyst slurry, the catalyst carrier 1 is coated in two layers with a special negative pressure coating machine. The air pressure of the special negative pressure coating machine is -20~-80kPa. Each layer of coating is divided into two parts: the front end of the lower coating layer. (air intake end) is the first formula coating 5, the rear end of the lower coating layer (air outlet) is the second formula coating 6, the front end of the upper coating layer is the third formula coating 7, the rear end of the upper coating layer Coat 8 for the fourth recipe. The catalyst carrier 1 can be a cordierite honeycomb ceramic with a mesh number of 400-600 mesh and a wall thickness of 3-6 mils.

[0032] After each coating of the slurry, the catalyst needs to be dried. The drying temperature is 150°C to 180°C and the drying time is 3h to 4h until the catalyst quality is no longer reduced. After drying, the catalyst needs to be calcine...

Embodiment A1

[0039]The coating weight of the first formula coating 5 and the second formula coating 6 is 150g / L, the coating weight of the third formula coating 7 and the fourth formula coating 8 is 65g / L, and the precious metal is 150g / L. ft3 (Pt:Pd:Rh=50:90:10); the precious metal content ratio in the first formula coating 5 and the second formula coating 6 is 2:1, the first formula coating 5 and the second formula coating 6 The length ratio of 1:1; the length ratio of the third formula coating 7 and the fourth formula coating 8 is 1:1.

Embodiment A2

[0041] The coating weight of the first formula coating 5 and the second formula coating 6 is 150g / L, the coating weight of the third formula coating 7 and the fourth formula coating 8 is 65g / L, and the precious metal is 150g / L. ft3 (Pt:Pd:Rh=50:90:10); the precious metal content ratio in the first formula coating 5 and the second formula coating 6 is 6:1, the first formula coating 5 and the second formula coating 6 The length ratio of 1:1.5; the length ratio of the third formula coating 7 and the fourth formula coating 8 is 1:1.5.

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Abstract

The invention belongs to the technical field of catalyst preparation, and discloses a method for preparing a segmented National VI natural gas equivalent ratio catalyst. The catalyst carrier is coated with two layers of catalyst slurry. The first formula coating, the second formula coating containing noble metal palladium at the gas outlet end of the lower layer, the third formula coating containing noble metal rhodium at the upper gas inlet end, and the fourth formula coating containing noble metal platinum at the gas outlet end of the upper layer. The present invention adopts double-layer coating to ensure an appropriate coating thickness, so that gas pollutants can be quickly diffused and converted; the distribution of noble metals Pt&Pd&Rh at different positions can effectively improve the conversion rate of hydrocarbons and nitrogen oxides, and, Since the Pd layer is covered with Rh and Pt layers, it can also reduce the poisoning effect of sulfur in the gas on the precious metal palladium, so the performance and durability of the catalyst are greatly improved; the coating process is simple and does not increase production costs.

Description

technical field [0001] The invention belongs to the technical field of catalyst preparation, and relates to a preparation method of a natural gas equivalent ratio catalyst, in particular to a method for preparing a segmented National VI natural gas equivalent ratio catalyst. Background technique [0002] With the rapid development of my country's transportation industry and the continuous improvement of consumption levels, the number of motor vehicles has grown rapidly at a rate of 2% every year. The three main pollutants emitted by motor vehicles are carbon monoxide, hydrocarbons, and nitrogen grades, respectively, and their air pollution share rates have reached 71.5%, 72.9%, and 3.8%, respectively, and have risen to become the main sources of pollutants in the air. [0003] As a clean energy, natural gas has better environmental protection and economic benefits than gasoline and diesel, but at the same time it is more difficult to convert than gasoline and diesel, which i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/46B01J37/02B01D53/94B01D53/62B01D53/72B01D53/56
CPCB01J23/002B01J23/464B01J37/0228B01D53/945B01J2523/00B01J2523/824B01J2523/822B01J2523/828
Inventor 承晓华张杰王平立张云贾莉伟岳军王家明邱祎源
Owner WUXI WEIFU ENVIRONMENT PROTECTION CATALYST
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