Method for firing photoluminescence fluorescence glaze ceramic through roller kiln

A roller kiln and photo-induced technology, which is applied in chemical instruments and methods, luminescent materials, applications, etc., can solve the problems of glazed architectural ceramics that have not yet appeared photo-induced red fluorescence, and achieve low cost, consistent shrinkage, and relative good capacitive effect

Active Publication Date: 2019-12-20
SHANDONG UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

So far, there have been no reports of photoluminescent red fluorescent glazed architectural ceramics

Method used

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  • Method for firing photoluminescence fluorescence glaze ceramic through roller kiln
  • Method for firing photoluminescence fluorescence glaze ceramic through roller kiln
  • Method for firing photoluminescence fluorescence glaze ceramic through roller kiln

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] (1) Ingredients according to mass percentage: 36.25% dolomite, 27.18% quartz, 5.58% europium oxide, 3.81% yttrium oxide, 27.18% aluminum hydroxide, add water, make the mass ratio of material to water 100:80, in planetary In a ball mill, after ball milling at a speed of 400 rpm for 1 hour, the slurry was dried at 110°C, and then calcined at 1175°C for 15 minutes to obtain a photoluminescent fluorescent powder; the prepared photoluminescent fluorescent The powder is mixed with other raw materials according to mass percentage: 7.46% kaolin, 11.94% talc, 5.97% pyrophyllite, 59.70% medium-temperature frit, 14.93% photoluminescence fluorescent powder, among which, the chemical composition of the medium-temperature frit is 1.77%Na 2 O, 2.00%MgO, 5.97%Al 2 o 3 , 61.59%SiO2 2 , 5.61%K 2 O, 8.63%CaO, 11.7%ZnO, 2.73%BaO, add water, make the mass ratio of material to water 100:80, after ball milling in a planetary ball mill at a speed of 400 rpm for 1 hour, the fluorescent glaze...

Embodiment 2

[0024] (1) Ingredients according to mass percentage: 36.25% dolomite, 27.18% quartz, 5.58% europium oxide, 3.81% yttrium oxide, 27.18% aluminum hydroxide, add water, make the mass ratio of material to water 100:80, in planetary In a ball mill, after ball milling at a speed of 400 rpm for 1 hour, the slurry was dried at 110°C, and then calcined at 1175°C for 15 minutes to obtain a photoluminescent fluorescent powder; the prepared photoluminescent fluorescent The powder is mixed with other raw materials according to mass percentage: 7.69% kaolin, 12.31% talc, 3.07% pyrophyllite, 61.54% medium-temperature frit, 15.39% photoluminescent fluorescent powder, among which, the chemical composition of the medium-temperature frit is 1.77%Na 2 O, 2.00%MgO, 5.97%Al 2 o 3 , 61.59%SiO2 2 , 5.61%K 2 O, 8.63%CaO, 11.7%ZnO, 2.73%BaO, add water, make the mass ratio of material to water 100:80, after ball milling in a planetary ball mill at a speed of 400 rpm for 1 hour, the fluorescent glaze ...

Embodiment 3

[0029] (1) Ingredients according to mass percentage: 36.25% dolomite, 27.18% quartz, 5.58% europium oxide, 3.81% yttrium oxide, 27.18% aluminum hydroxide, add water, make the mass ratio of material to water 100:80, in planetary In a ball mill, after ball milling at a speed of 400 rpm for 1 hour, the slurry was dried at 110°C, and then calcined at 1175°C for 15 minutes to obtain a photoluminescent fluorescent powder; the prepared photoluminescent fluorescent The powder is mixed with other raw materials according to mass percentage: 7.25% kaolin, 11.59% talc, 8.7% pyrophyllite, 57.97% medium-temperature frit, 14.49% photoluminescent fluorescent powder, and the chemical composition of the medium-temperature frit is 1.77%Na 2 O, 2.00%MgO, 5.97%Al 2 o 3 , 61.59%SiO2 2 , 5.61%K 2 O, 8.63%CaO, 11.7%ZnO, 2.73%BaO, add water, make the mass ratio of material to water 100:80, after ball milling in a planetary ball mill at a speed of 400 rpm for 1 hour, the fluorescent glaze is produce...

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Abstract

The invention provides a method for firing photoluminescence fluorescence glaze ceramic through a roller kiln, and belongs to the technical field of building ceramic production. The method comprises the following steps: mixing dolomite, quartz, europium oxide, yttrium oxide and aluminum hydroxide, adding water, carrying out ball milling, drying and calcining to obtain a photoluminescence fluorescent powder material, mixing kaolin, talc, pyrophyllite, a medium-temperature frit and the photoluminescence fluorescent powder material, adding water, and carrying out ball milling to obtain a fluorescent glaze material; mixing kaolin, feldspar and quartz, adding water, and carrying out ball milling, drying, powdering and compression molding to obtain a green body; and finally, applying the fluorescent glaze material to the green body, and firing at a high temperature in the roller kiln to obtain the photoluminescence fluorescence glaze ceramic. According to the photoluminescence fluorescence glaze ceramic produced by the method, the compatibility of the glaze and the green body is good, red fluorescence is emitted, the fluorescence intensity can be regulated and controlled, and the requirements in the fields of anti-counterfeiting marks, real-time display and light response can be met.

Description

technical field [0001] The invention provides a method for firing photoluminescent glazed ceramics through a roller kiln, which belongs to the technical field of building ceramics production. Background technique [0002] With the development of society, people's pursuit of the quality of architectural ceramics is getting higher and higher. While considering excellent decorative properties, functional elements have also received attention, such as optical properties, including long afterglow, luminescence properties or photoluminescent real-time fluorescent ceramics have attracted the attention of researchers, producers and consumers in recent years. The materials selected for long afterglow ceramic glazes are mainly obtained from aluminate, silicate, aluminosilicate or titanate-based spinel materials doped with rare earths, which are not suitable for high-temperature firing (generally no more than 950 ℃), cannot be used in the roller kiln production of architectural cerami...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B33/13C03C8/04C03C8/14C04B41/86C09K11/77
CPCC04B33/13C03C8/14C03C8/04C09K11/7783C04B41/5022C04B41/86C04B2235/3463C04B2235/3418
Inventor 李成峰李永倩黄华张肖林张伟褚建悦葛筱璐
Owner SHANDONG UNIV OF TECH
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