Intelligent anti-icing material, and preparation method and application thereof

An anti-icing, intelligent technology, applied in chemical instruments and methods, other chemical processes, etc., can solve the problems of rubber prone to aging, short service life, energy consumption, etc. The effect of adhesion and acceleration of voluntary shedding

Active Publication Date: 2019-12-20
NANJING UNIV OF AERONAUTICS & ASTRONAUTICS
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] At present, the anti-icing means mainly use the surface structure of the equipment or material itself as a heat source to form an anti-icing system to avoid surface icing and adhesion, but this method needs to ensure the heating power to ensure that the surface temperature is maintained above freezing point , the energy consumption is very large
Or combine heating means with hydrophobic coating means (as the Chinese patent application number CN201710508043.4 discloses a kind of anti-icing film and its preparation method), but this method still needs to provide heat source, consumes energy, and this method The coating raw material matrix involved in this method is mainly epoxy resin and rubber. The resin must be molded at one time, which is inconvenient to use. Rubber is prone to aging during low temperature service and has a short service life.

Method used

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  • Intelligent anti-icing material, and preparation method and application thereof
  • Intelligent anti-icing material, and preparation method and application thereof

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preparation example Construction

[0031] The present invention also provides a preparation method for the intelligent anti-icing material described in the above technical solution, comprising the following steps:

[0032] (1) carrying out hydroxylation treatment on the nickel-titanium alloy wire to obtain hydroxylated nickel-titanium alloy wire;

[0033] (2) coating the surface of the hydroxylated nickel-titanium alloy wire obtained in the step (1) with an adhesive to obtain the nickel-titanium alloy wire to be bonded;

[0034] (3) The nickel-titanium alloy wire to be bonded obtained in the step (2) is sequentially mixed with a hydrophobic resin for granulation and injection molding to obtain an intelligent anti-icing material.

[0035] In the present invention, the amount of each component used in the preparation method is consistent with the amount used in the technical solution of the aforementioned intelligent anti-icing material, and will not be repeated here.

[0036] In the invention, the nickel-titani...

Embodiment 1

[0050] Heat treatment: anneal a nickel-titanium alloy wire (composition of Ti-50.8Ni) with a diameter of 150 μm and a length of 0.3 cm at 650 ° C for 25 min, water quenching, and then hold at 300 ° C for 24 h to obtain a martensitic phase Nickel-titanium alloy wire with a change point temperature of -30 to -10°C;

[0051] Pretreatment: Ultrasound the heat-treated nickel-titanium alloy wire in acetone for 30 minutes at a frequency of 100 Hz, wash it with distilled water, and wash it in a mixed acid solution of hydrofluoric acid: nitric acid: water with a volume ratio of 1:5:2 for 30 seconds. N 2 blow dry;

[0052] Preparation of intelligent anti-icing material: Disperse the pretreated nickel-titanium alloy wire in Piranha solution, immerse at 90°C for 3 minutes, filter with suction, wash with distilled water and dry to obtain hydroxylated nickel-titanium alloy wire; The hydroxylated nickel-titanium alloy wire is immersed in the Schiff base metal complex / DMF solution, ultrason...

Embodiment 2

[0054] Heat treatment: anneal a nickel-titanium alloy wire (composition of Ti-58.6Ni) with a diameter of 80 μm and a length of 0.3 cm at 450 ° C for 120 min, air-cool, and then hold at 400 ° C for 24 h to obtain a martensitic transformation Nickel-titanium alloy wire with a point temperature of -30~-10°C;

[0055] Pretreatment: Ultrasound the heat-treated nickel-titanium alloy wire in acetone for 30 minutes at a frequency of 100 Hz, wash it with distilled water, and wash it in a mixed acid solution of hydrofluoric acid: nitric acid: water with a volume ratio of 1:5:2 for 15 seconds. N 2 blow dry;

[0056] Preparation of intelligent anti-icing material: Disperse the pretreated nickel-titanium alloy wire in Piranha solution, immerse at 90°C for 1.5 min, filter with suction, wash with distilled water and dry to obtain hydroxylated nickel-titanium alloy wire; The obtained hydroxylated nickel-titanium alloy wire is immersed in the Schiff base metal complex / DMF solution, ultrasoni...

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Abstract

The invention belongs to the technical field of composite materials, and particularly relates to an intelligent anti-icing material, and a preparation method and application thereof. The invention provides an intelligent anti-icing material. The intelligent anti-icing material comprises hydrophobic resin and nickel-titanium alloy wires embedded in the hydrophobic resin. When the ambient temperature reduces, the hydrophobic resin in the intelligent anti-icing material disclosed by the invention can shrink; the nickel-titanium alloy wires with a thermoelastic martensite phase transformation characteristic is subjected to phase transformation and is expanded; and the direction of expansion force in an ice layer is changed, so that tiny cracks are generated on the interface between the ice layer and the surface of the material, the adhesive force of the ice layer on the surface of the material is reduced, automatic falling of the ice layer is accelerated, and an excellent anti-icing usingeffect is achieved without need of heating. Experimental effects show that the intelligent anti-icing material disclosed by the invention has a good anti-icing effect; under the condition of-20 DEG C,compared with a non-intelligent anti-icing composite material, the intelligent anti-icing material provided by the invention has the advantage that the adhesion force of an ice layer on the surface is reduced by 18.2%-24.2%.

Description

technical field [0001] The invention belongs to the technical field of composite materials, and in particular relates to an intelligent anti-icing material and its preparation method and application. Background technique [0002] Icing phenomena such as precipitation icing and sublimation icing are very common in nature. In most cases, the occurrence of icing will bring great inconvenience to people's production and life, especially on vehicles and external equipment. The continuous attachment and accumulation of pollutants will cause traffic obstruction and equipment damage. Existing methods for removing icing include mechanical deicing and thermal deicing; however, mechanical deicing uses beating, which is likely to cause damage to equipment and equipment surfaces, and both mechanical deicing and thermal deicing consume a lot of energy. If the surface of the equipment or material has anti-icing properties, the de-icing work can be reduced to a certain extent. Therefore, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L61/16C08K9/04C08K7/00C08K3/08C09K3/18
CPCC08K9/04C08K7/00C08K3/08C09K3/18C08K2201/004C08L23/12C08L61/16C08K2201/005C08K7/04
Inventor 潘蕾郭华鑫王斐庞小飞仲浪袁潇洒胡静玲
Owner NANJING UNIV OF AERONAUTICS & ASTRONAUTICS
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