Fixed bed reactor and unsaturated light hydrocarbon hydrogenation method

A fixed bed reactor and reactor technology, which are applied in chemical instruments and methods, hydrogenation to hydrocarbons, sustainable manufacturing/processing, etc., can solve the problem of inability to effectively control reaction temperature, increase equipment investment and energy consumption, and catalyst bed temperature. It can effectively control the temperature of the catalyst bed, reduce the operating cost, and reduce the circulating flow.

Active Publication Date: 2019-12-31
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, due to the change of the raw material of the device and the temperature rise of the catalyst bed under different operating cycles, the amount of cold oil that needs to be injected varies greatly
The cold oil distributor is a fixed structure, the change of the amount of cold oil has a direct impact on the effect of the cold oil distributor, resulting in the inability to effectively control the reaction temperature
[0004] To sum up, although the traditional cold hydrogen temperature control method can effectively control the reaction temperature, the amount of cold hydrogen injected is large, which needs to increase the investment and energy consumption of the device; the use of cold oil temperature control method can reduce part of the investment of the device , but the change in the amount of cold oil injection leads to the inability to effectively control the reaction temperature

Method used

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  • Fixed bed reactor and unsaturated light hydrocarbon hydrogenation method
  • Fixed bed reactor and unsaturated light hydrocarbon hydrogenation method
  • Fixed bed reactor and unsaturated light hydrocarbon hydrogenation method

Examples

Experimental program
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Embodiment 1

[0059] This embodiment adopts figure 1 The reactor shown carries out the hydrogenation reaction of C4-C6 unsaturated light hydrocarbons.

[0060] Fill the reactor with 5m 3 YN-1 hydrofining catalyst, each heat exchange tube is filled with 0.1m 3 YN-1 hydrorefining catalyst. The unsaturated carbon four raw materials containing butadiene and butene and hydrogen are fed into the reactor from inlet 1 at a volume ratio of 200:1. The reaction temperature of the reactor is 30°C and the pressure is 2.7MPa. The reaction product is discharged from the outlet 6 of the reactor. At the same time, the cooled carbon four hydrogenation product enters from the first nozzle of the heat exchange tube at the lower part of the reactor, the temperature is 20° C., and the pressure is 2.7 MPa. Record the temperature of the catalyst bed 13 and the temperature of the second nozzle of the heat exchange tube 4. Analyze the olefin content in the product. The specific values ​​are shown in Table 1.

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Abstract

The invention relates to a fixed bed reactor and an unsaturated light hydrocarbon hydrogenation method. The fixed bed reactor comprises: a reactor cylinder; a catalyst support structure arranged in the reactor cylinder body; a heat exchange tube provided with a first tube opening and a second tube opening, wherein the first tube opening is arranged on the reactor cylinder or outside the reactor cylinder and is lower than the catalyst support structure, and the second tube opening is arranged in the reactor cylinder and is higher than the catalyst support structure; a material inlet arranged atthe top of the reactor cylinder; and a product outlet arranged at the bottom of the reactor cylinder. The unsaturated light hydrocarbon hydrogenation method using the fixed bed reactor has the advantages of less internal circulation material flow of the reaction system, effective control of the temperature of a catalyst bed, and improvement of the product quality.

Description

Technical field [0001] The invention relates to a fixed bed reactor. The invention also relates to a method for hydrogenating unsaturated light hydrocarbons. Background technique [0002] Since the hydrogenation reaction is an exothermic reaction, there is a temperature rise in the catalyst bed. In order to effectively control the reaction temperature, the fixed bed hydrogenation reactor is usually divided into multiple beds for filling, and cold hydrogen is injected between the beds to reduce the catalyst bed. temperature. The specific heat of hydrogen is small, which requires a large amount of hydrogen to be injected to meet the demand. This cold hydrogen needs to be provided by the circulating hydrogen compressor in the device, which requires the circulating hydrogen compressor to provide this part of the cold hydrogen in addition to the hydrogen normally required for the hydrogenation reaction, which increases the investment and energy consumption of the device. . [0003] ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J8/02C07C5/03C07C9/10
CPCB01J8/02C07C5/03C07C9/10Y02P20/10
Inventor 纪玉国熊凯李正艳杜周张富春季静
Owner CHINA PETROLEUM & CHEM CORP
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