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Color change cellulose fiber preparation method

A cellulose fiber, temperature-sensitive discoloration technology, applied in the textile field, can solve the problems of unsustainable discoloration effect, poor stability of temperature-sensitive discoloration materials, etc., and achieves the effects of stable performance, easy coating, and improved discoloration durability.

Inactive Publication Date: 2020-01-07
CHTC HELON (WEIFANG) NEW MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0011] (1) Pure temperature-sensitive color-changing materials can only change color in an environment with light and temperature changes, and will not actively emit light in a dark environment. At present, color-changing materials that can not only change temperature but also emit light in a dark environment The material is not suitable for adding directly to the wet spinning solution;
[0012] (2) The temperature-sensitive color-changing material has poor stability, and the color-changing effect is not long-lasting

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] (1) Preparation of color-changing microcapsule slurry

[0043] The capsule core material in the color-changing microcapsules is composed of temperature-sensitive color-changing material and luminous material. The temperature-sensitive color-changing material is composed of 3,6-diethoxyfluorane, boric acid and myristyl alcohol, and the luminous material is SrAl, a long-lasting afterglow material. 2 o 4 : Eu, Dy; the mass ratio of 3,6-diethoxyfluorane, boric acid and myristyl alcohol in the thermochromic material is 1:2:30.

[0044] The specific preparation method of the capsule core material is to mix 3,6-diethoxyfluorane and luminous material in a mass ratio of 1:1, grind in a grinder until the particle size is less than 100nm, and then mix it with boric acid and myristyl alcohol evenly , to obtain the capsule core material;

[0045] The wall material of the microcapsules is polymethyl methacrylate, the mass ratio of the wall material of the microcapsules to the core ...

Embodiment 2

[0051] (1) Preparation of color-changing microcapsule slurry

[0052] The capsule core material in the color-changing microcapsules is composed of temperature-sensitive color-changing material and luminous material. The temperature-sensitive color-changing material is composed of crystal violet lactone, bisphenol A and cetyl alcohol, and the luminous material is long afterglow material CaAl 2 o 4 : Eu, Nd; the mass ratio of crystal violet lactone, bisphenol A and cetyl alcohol in the thermochromic material is 1:3:50.

[0053] The preparation method of the capsule core material is to mix crystal violet lactone and luminous material at a mass ratio of 2:1, grind them in a grinder until the particle size is less than 100nm, and then mix them with bisphenol A and cetyl alcohol to prepare the capsule core Material;

[0054] Melamine-formaldehyde resin was selected as the capsule wall material, and the mass ratio of microcapsule capsule wall material to capsule core material was 1...

Embodiment 3

[0060] (1) Preparation of color-changing microcapsule slurry

[0061] The capsule core material in the color-changing microcapsules is composed of temperature-sensitive color-changing materials and luminous materials. The temperature-sensitive color-changing materials are composed of crystal violet lactone, bisphenol A and stearyl alcohol. The luminous material is long afterglow material MgSiO 3 : Mn, Eu, Dy; the mass ratio of crystal violet lactone, bisphenol A and stearyl alcohol in the thermochromic material is 1:4:40.

[0062] The preparation method of the capsule core material is to mix crystal violet lactone and luminous material at a mass ratio of 3:1, grind in a grinder until the particle size is less than 100nm, and then mix it evenly with bisphenol A and stearyl alcohol.

[0063] Urea-formaldehyde resin was selected as the capsule wall material, and the mass ratio of microcapsule capsule wall material to capsule core material was 1:1. Microcapsule slurry with a parti...

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PUM

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Abstract

The invention provides a color change cellulose fiber preparation method which includes the steps: color change microcapsule sizing agent preparation; ultraviolet absorbent sizing agent preparation; spinning. Fibers prepared by the method have temperature sensing color change and night light effects, fiber colors are changed along with change of environment temperature, and the fibers can emit light at night or in dark environments. According to the method, color change materials and luminous materials are coated by a microcapsule method to prepare sizing agents, and the sizing agents are uniform, cannot be layered and are suitable for being added into cellulose solution to perform spinning. Rare-earth luminous materials are of pore structures, the color change materials and the luminous materials can be more closely and integrally combined in microcapsules and more easily coated, and performances are more stable. According to the method, inorganic ultraviolet absorbents are added intothe fibers, chemical properties are stable, easily light decomposed color change materials can be protected, color change durability of the cellulose fibers is improved, and the cellulose fibers havesun-screening effects.

Description

technical field [0001] The invention belongs to the technical field of textiles, and in particular relates to a preparation method of cellulose fibers with a color-changing function. Background technique [0002] The color-changing fiber is a textile prepared by using the unique structure and performance of the color-changing material. The color of the fiber can show a dynamic change effect with the change of external conditions, giving the textile a dynamic visual impact and catering to people's pursuit of newness and individuality in textiles. The consumption psychology of modernization and functionalization has made textiles have a new development in the application of clothing, military, and temperature indicators. [0003] At present, there are mainly three types of temperature-sensitive color-changing materials: inorganic, crystalline, and organic. Inorganic color-changing materials are highly toxic and have low sensitivity, so they are not suitable for direct use on ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F1/10D01F2/02B01J13/18
CPCB01J13/18D01F1/10D01F2/02
Inventor 秦翠梅马君志刘长军李昌垒刘乐刘子东
Owner CHTC HELON (WEIFANG) NEW MATERIALS CO LTD
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