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High-performance hydrogenated nitrile rubber material and preparation method thereof

A technology of hydrogenated nitrile rubber and nitrile rubber, which is applied in the field of rubber, can solve the problem of high cost, achieve the effects of low cost, excellent performance, and reduced use cost

Active Publication Date: 2020-01-14
BEIJING UNIV OF CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

But the hydrogenated nitrile butadiene rubber material provided by the above-mentioned patent still has the problem of high cost

Method used

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  • High-performance hydrogenated nitrile rubber material and preparation method thereof

Examples

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Effect test

Embodiment 1

[0041] This embodiment provides a high-performance hydrogenated nitrile rubber material, including the following raw materials in parts by weight: 90 parts of hydrogenated nitrile rubber, 10 parts of hydrogenated nitrile rubber emulsion, 1 part of antioxidant 4010A, 5 parts of zinc oxide, and stearic acid 1 part, 40 parts carbon black N220, 5 parts DCP.

[0042] Wherein, the preparation method of the hydrogenated nitrile rubber emulsion is as follows: weigh a certain quality of nitrile rubber emulsion, according to the molar ratio of carbon-carbon double bonds in the nitrile rubber emulsion to hydrazine hydrate, hydrogen peroxide, and boric acid of 1.6: 1.75: 0.14 Weigh the corresponding masses of hydrazine hydrate, hydrogen peroxide and boric acid. Add the hydrazine hydrate directly to the emulsion. The boric acid is dissolved in a certain mass of deionized water and mixed with hydrogen peroxide evenly. Under certain stirring speed and temperature conditions, Use a peristaltic p...

Embodiment 2

[0049] This embodiment provides a high-performance hydrogenated nitrile rubber material, which includes the following raw materials by weight: 80 parts of hydrogenated nitrile rubber, 20 parts of hydrogenated nitrile rubber emulsion, 1 part of antioxidant 4010A, 5 parts of zinc oxide, and stearic acid 1 part, 40 parts carbon black N220, 5 parts DCP.

[0050] Wherein, the preparation method of the hydrogenated nitrile rubber emulsion and the preparation method of the high-performance hydrogenated nitrile rubber material are the same as in Example 1.

Embodiment 3

[0052] This embodiment provides a high-performance hydrogenated nitrile rubber material, including the following raw materials in parts by weight: 70 parts of hydrogenated nitrile rubber, 30 parts of hydrogenated nitrile rubber emulsion, 1 part of antioxidant 4010A, 5 parts of zinc oxide, and 1 part of stearic acid Parts, 40 parts of carbon black N220, 5 parts of DCP.

[0053] Wherein, the preparation method of the hydrogenated nitrile rubber emulsion and the preparation method of the high-performance hydrogenated nitrile rubber material are the same as in Example 1.

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Abstract

The invention relates to the field of rubber and in particular relates to a high-performance hydrogenated nitrile rubber material and a preparation method thereof. The high-performance hydrogenated nitrile rubber material provided by the invention is prepared from hydrogenated nitrile rubber and hydrogenated nitrile rubber emulsion as main raw materials, wherein the weight ratio of the hydrogenated nitrile rubber to the hydrogenated nitrile rubber emulsion is (6-30):(1-10), preferably (10-15):(4-7). The preparation method of the high-performance hydrogenated nitrile rubber material comprises the following step: performing wet-method mixing or dry-method mixing on a hydrogenated nitrile rubber emulsion, a hydrogenated nitrile rubber emulsion, an anti-aging agent 4010A, zinc oxide, stearic acid, carbon black N220 and DCP (dicumyl peroxide) so as to obtain mixed rubber. The high-performance hydrogenated nitrile rubber material provided by the invention adopts hydrogenated nitrile rubber which is prepared by using a solution hydrogenation method and hydrogenated nitrile rubber which is prepared by using an emulsion hydrogenation method as raw materials, not only is the performance of the hydrogenated nitrile rubber improved, but also the use cost of the hydrogenated nitrile rubber can be lowered.

Description

Technical field [0001] The invention relates to the field of rubber, in particular to a high-performance hydrogenated nitrile rubber material and a preparation method thereof. Background technique [0002] Hydrogenated nitrile rubber (HNBR) is a highly saturated elastomer obtained by special hydrogenation of nitrile rubber (NBR). HNBR has good oil resistance; and due to its highly saturated structure, it has a good High heat resistance, excellent chemical resistance, excellent ozone resistance, high compression set resistance; at the same time, hydrogenated nitrile rubber also has high strength, high tear performance, excellent wear resistance, etc. One of the rubbers with excellent comprehensive performance. The current preparation method is usually prepared by solution hydrogenation. The solution hydrogenation process involves high temperature and high pressure, precious metal catalysts, and high cost, which limits its wide application. [0003] Chinese patent CN106750692B relat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L15/00C08K13/02C08K5/14C08K3/04C08K5/09C08K3/22C08K5/18C08C19/02
CPCC08L15/005C08C19/02C08L2205/025C08K2003/2296C08K13/02C08K5/14C08K3/04C08K5/09C08K3/22C08K5/18
Inventor 岳冬梅徐蒽云谢飞吕文坤王爽张立群
Owner BEIJING UNIV OF CHEM TECH
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