Perylene diimide derivative, preparation method and application of perylene diimide derivative in preparation of ATP (adenosine triphosphate) fluorescent probe

A technology of perylene imide and fluorescent probe, applied in the field of fluorescent probe, can solve the problems of poor solubility of perylene imide derivatives, harsh synthesis conditions, high reaction temperature, etc. good effect
CN110746420AActive Publication Date: 2020-02-04TIANJIN UNIV
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
TIANJIN UNIV
Publication Date
2020-02-04

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Abstract

The invention discloses a perylene diimide derivative, a preparation method and application of the perylene diimide derivative in preparation of an ATP (adenosine triphosphate) fluorescent probe. Theperylene diimide derivative is shown as a formula (IV), wherein R<+> = R'2(CH3)2N<+>, and R' is linear alkyl with 16-18 carbon atoms, branched alkyl or alkyl with a cyclic alkyl chain. The ATP fluorescent probe prepared from the perylene diimide derivative can selectively and quickly detect ATP, the prepared ATP fluorescent probe is good in chemical stability, high in sensitivity and good in selectivity and can be combined with a commercial fluorescent instrument to achieve quick response and real-time monitoring of the ATP; the perylene diimide derivative is used for preparing the fluorescentprobe high in luminescence performance and capable of quickly selectively analyzing the ATP, the preparation method is simple and convenient, reaction conditions are mild, reaction is performed in ethanol water, environment pollution is avoided, the requirements of green chemical probes are met, synthesis is simple, and products are easy to separate and purify.
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Description

technical field

[0001] The invention belongs to the technical field of fluorescent probes, and in particular relates to a perylene imide derivative, a preparation method and an application for preparing an ATP fluorescent probe. Background technique

[0002] Perylene diimide (PDI) derivatives are an important class of fused-ring aromatic hydrocarbon compounds. This type of compound has a large conjugated system, high fluorescence quantum yield, and a wide range of absorption spectra. Excellent photoelectric properties and thermal stability. Since it was first synthesized in the 10s of the 20th century, after more than 100 years of development, it has played a very important role in the fields of organic light-emitting diodes, liquid crystal display materials, molecular switches, photovoltaic devices and fluorescent probes, and has important application value. .

[0003] However, due to the influence of special structure, the solubility of most perylene imide derivatives is...

Claims

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