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Carbon-based lithium-ion battery negative electrode slurry and preparation method thereof, carbon-based lithium-ion battery negative electrode, lithium-ion battery and equipment

A lithium-ion battery and ion battery technology, applied in battery electrodes, secondary batteries, circuits, etc., can solve the problems of affecting the electrical performance and cycle performance of batteries, reducing the content of active material conductive agents, and poor bonding effects, etc. Achieving good battery capacity retention, improved lithium precipitation, and good ion transport kinetics

Active Publication Date: 2021-05-18
SOUNDON NEW ENERGY TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, most of the binders used in the negative electrode materials of lithium batteries on the market are SBR, which has a small interface force with graphite, conductive agent, and sodium carboxymethyl cellulose (CMC), resulting in poor bonding effect and affecting the battery cell. electrical properties and cycle performance
At present, the conventional method to solve the poor adhesion of SBR is to increase the amount of SBR, increase the molecular weight of SBR, and develop other types of binders. Although increasing the amount of SBR can improve the adhesion of the negative electrode, it will inevitably reduce the active material and electrical conductivity. However, increasing the molecular weight of SBR and developing other types of binders requires a lot of research and development investment, which is difficult to practice and is not suitable for solving current production problems.

Method used

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  • Carbon-based lithium-ion battery negative electrode slurry and preparation method thereof, carbon-based lithium-ion battery negative electrode, lithium-ion battery and equipment
  • Carbon-based lithium-ion battery negative electrode slurry and preparation method thereof, carbon-based lithium-ion battery negative electrode, lithium-ion battery and equipment
  • Carbon-based lithium-ion battery negative electrode slurry and preparation method thereof, carbon-based lithium-ion battery negative electrode, lithium-ion battery and equipment

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0066] Configure 573.2kg of sodium carboxymethylcellulose glue (using water as a solvent) in the stirring tank 1, the concentration is 1%, the glue making temperature is 25°C, the stirring speed is 800r / min, and the glue making time is 5h;

[0067] Add 538.4kg of artificial graphite, 11.46kg of conductive carbon black, and 5.73kg of oxidized graphite into a double planetary mixing tank for uniform mixing. The revolution speed is 10r / min, the rotation speed is 500r / min, and the stirring time is 25min;

[0068] Get above-mentioned sodium carboxymethyl cellulose glue 240.5kg and add in the double planetary mixing tank, mix; revolution speed 20r / min, rotation speed 1500r / min, stirring time 25min;

[0069] Add 14.3kg of EC (ethylene carbonate) and the remaining sodium carboxymethylcellulose glue to the double planetary mixing tank for mixing; the revolution speed is 25r / min, the rotation speed is 1500r / min, and the stirring time is 60min;

[0070] Add 28.64kg of SBR latex to the do...

Embodiment 2

[0074] Configure 573.2kg of sodium carboxymethylcellulose glue (using water as a solvent) in the stirring tank 1, the concentration is 1%, the glue making temperature is 25°C, the stirring speed is 800r / min, and the glue making time is 5h;

[0075] Add 521.2kg of artificial graphite, 11.46kg of conductive graphite, and 22.91kg of graphene oxide into a double planetary mixing tank for uniform mixing. The revolution speed is 10r / min, the rotation speed is 500r / min, and the stirring time is 25min;

[0076]Get above-mentioned sodium carboxymethyl cellulose glue 240.5kg and add in the double planetary mixing tank, mix; revolution speed 20r / min, rotation speed 1500r / min, stirring time 25min;

[0077] Add 14.3kg of EC and the remaining sodium carboxymethylcellulose glue to the double planetary mixing tank for mixing; the revolution speed is 25r / min, the rotation speed is 1500r / min, and the stirring time is 60min;

[0078] Add 28.64kg of SBR latex to the double planetary mixing tank f...

Embodiment 3

[0082] Configure 573.2kg of sodium carboxymethylcellulose glue (using water as a solvent) in the stirring tank 1, the concentration is 1%, the glue making temperature is 25°C, the stirring speed is 800r / min, and the glue making time is 5h;

[0083] Add 498.3kg of mesocarbon microspheres, 11.46kg of carbon nanotubes, 22.91kg of graphene oxide and 22.91kg of graphite oxide into a double planetary mixing tank for uniform mixing. The revolution speed is 10r / min, the rotation speed is 500r / min, and the stirring time 25min;

[0084] Get above-mentioned sodium carboxymethyl cellulose glue 240.5kg and add in the double planetary mixing tank, mix; revolution speed 20r / min, rotation speed 1500r / min, stirring time 25min;

[0085] Add 14.3kg of EC and the remaining sodium carboxymethylcellulose glue to the double planetary mixing tank for mixing; the revolution speed is 25r / min, the rotation speed is 1500r / min, and the stirring time is 60min;

[0086] Add 28.64kg of SBR latex to the doub...

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Abstract

The invention provides a carbon-based lithium ion battery negative electrode slurry and a preparation method thereof, a carbon-based lithium ion battery negative electrode, a lithium ion battery and equipment. The carbon-based lithium ion battery negative electrode slurry includes basic materials; the basic materials include carbon-based active material 85%-98%, sodium carboxymethyl cellulose 0.5%-5%, conductive agent 0.5%-5%, modifier 0.5% ‑8% and styrene butadiene polymer 0.5%‑5%; modifiers include graphite oxide and / or graphene oxide. Preparation method of carbon-based lithium ion battery negative electrode slurry: mixing raw materials to obtain the carbon-based lithium ion battery negative electrode slurry. The carbon-based lithium-ion battery negative electrode is prepared by using the carbon-based lithium-ion battery negative electrode slurry. Lithium-ion battery, including carbon-based lithium-ion battery negative electrode. devices that use lithium-ion batteries to power themselves or external devices. The carbon-based lithium ion battery negative electrode slurry provided in the present application has good adhesion and can effectively improve the battery capacity retention rate.

Description

technical field [0001] The invention relates to the field of lithium-ion batteries, in particular to a carbon-based lithium-ion battery negative electrode slurry and a preparation method thereof, a carbon-based lithium-ion battery negative electrode, a lithium-ion battery and equipment. Background technique [0002] At present, most of the binders used in the negative electrode materials of lithium batteries on the market are SBR, which has a small interface force with graphite, conductive agent, and sodium carboxymethyl cellulose (CMC), resulting in poor bonding effect and affecting the battery cell. electrical properties and cycle performance. At present, the conventional method to solve the poor adhesion of SBR is to increase the amount of SBR, increase the molecular weight of SBR, and develop other types of binders. Although increasing the amount of SBR can improve the adhesion of the negative electrode, it will inevitably reduce the active material and electrical conduc...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/62H01M4/587H01M4/133H01M10/0525
CPCH01M4/133H01M4/587H01M4/62H01M4/622H01M10/0525Y02E60/10
Inventor 王翔林涛刘学良李世达王耐清
Owner SOUNDON NEW ENERGY TECH CO LTD