This invention discloses a branched vinylphenyl polysiloxane and its preparation method, comprising the following steps: mixing vinyl difunctional chain
silane monomers, phenyl difunctional chain
silane monomers,
alkyl difunctional chain
silane monomers, a
solid acid catalyst, and
acetic acid in a certain proportion, and performing a
reflux reaction; filtering out the
solid acid catalyst by cooling to obtain a first filtrate, and distilling it at
atmospheric pressure to obtain a polysiloxane precursor; adding a trifunctional chain silane
monomer, a capping agent,
acetic acid, and a
solid acid catalyst to the polysiloxane precursor, and reacting; filtering out the
solid acid catalyst to obtain a second filtrate, and distilling it at
atmospheric pressure to obtain a branched vinylphenyl polysiloxane with a vinyl content of 1.0~3.0% and a
silanol content ≤0.1%. It can be used for
surface modification of fillers in addition
silicone rubber systems to improve the mechanical properties and
system compatibility of materials, and solve the problems of few modified active sites and weak interfacial forces, as well as the problem that high
silanol content affects the curing and adhesion of addition systems.