Organic compound and organic electroluminescent element comprising the same
A compound and chemical formula technology, applied in the field of organic electroluminescent elements, to achieve the effect of long life and low driving voltage
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Synthetic example 1
[0109] Synthesis Example 1: Synthesis of Compound 8
[0110]
[0111] Starting material 1-A (17.1 g, 50 mmol), starting material 1-B (13.6 g, 55 mmol), tetrakis(triphenylphosphine) palladium (1.7 g, 1.5 mmol), potassium carbonate (20.7 g, 150 mmol) were charged After entering the 2,000ml flask, add toluene (500ml), ethanol (100ml), H 2 O (100ml). Make N while stirring at room temperature 2 After 30 minutes of bubbling, the temperature was raised and stirring reflux was performed for 6 hours.
[0112] After cooling to room temperature, the reactant was added to methanol (1,000 ml), and the resulting precipitate was filtered. Column chromatography was performed using dichloromethane and n-hexane as developing solvents to obtain Compound 8 (15.1 g, 65%).
[0113] MS (MALDI-TOF) m / z: 464 [M] +
Synthetic example 2
[0114] Synthesis Example 2: Synthesis of Compound 9
[0115]
[0116] Compound 9 (18.2 g, 70%) was obtained in the same manner as in Synthesis Example 1 except that starting material 2-B (13.6 g, 55 mmol) was used instead of starting material 1-B.
[0117] MS (MALDI-TOF) m / z: 464 [M] +
Synthetic example 3
[0118] Synthesis Example 3: Synthesis of Compound 11
[0119]
[0120] Compound 11 (16.8 g, 62%) was obtained in the same manner as in Synthesis Example 1 except that starting material 3-B (17.8 g, 55 mmol) was used instead of starting material 1-B.
[0121] MS (MALDI-TOF) m / z: 540 [M] +
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