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Ammonia-free environment-friendly medium-phosphorus chemical nickel plating solution and preparation method thereof

An electroless nickel plating solution, an environmentally friendly technology, applied in the field of electroless plating, can solve problems such as increased production costs, unqualified products, dull coating surface, etc., achieve good high temperature resistance and improve performance

Inactive Publication Date: 2020-03-06
中山市美仑化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, during the use of some electroplating solutions, the surface of the coating formed by it is often relatively dull, and it is not easy to have a relatively bright metallic luster, so that the appearance of the metal coated with the above coating is not bright enough. In many cases where the appearance is required It may lead to unqualified products, which will greatly increase the production cost of products.

Method used

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Examples

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Effect test

preparation example Construction

[0038] The second aspect of the present invention provides a method for preparing an ammonia-free and environmentally friendly phosphorous electroless nickel plating solution. The steps include: dissolving nickel sulfate and an organic acid in water, adding sodium hypophosphite, sodium acetate, heat-stable grade Lactic acid, wetting agent, intermediate until well mixed.

[0039] The third aspect of the present invention provides an electroless plating method, which includes immersing the product to be treated in a nickel plating solution for electroplating, and the nickel plating solution is the above-mentioned ammonia-free and environmentally friendly phosphorous electroless nickel plating solution.

Embodiment 1

[0043] Embodiment 1 provides a kind of non-ammonia environment-friendly phosphorus electroless nickel plating liquid and preparation method thereof, by weight, comprising 40 parts of heat-stable grade lactic acid, 700 parts of nickel sulfate, 75 parts of organic acid, 35 parts of sodium acetate, times 120 parts of sodium phosphate, 0.02 parts of wetting agent, and 0.08 parts of intermediate.

[0044] The heat-stable lactic acid is 88% lactic acid;

[0045] The organic acid is a mixture of 2-hydroxysuccinic acid and succinic acid; the 2-hydroxysuccinic acid is 44wt% of the organic acid;

[0046] Described wetting agent is sodium 2-ethylhexyl sulfate;

[0047] The intermediate is butynediol diethoxy ether.

[0048]The preparation method of the phosphorous electroless nickel plating solution in ammonia-free environmental protection, the steps include: dissolving nickel sulfate and organic acid in water, adding sodium hypophosphite, sodium acetate, heat-stable lactic acid, wetti...

Embodiment 2

[0050] Embodiment 2 provides a kind of non-ammonia environment-friendly phosphorous electroless nickel plating solution and its preparation method, by weight, including 50 parts of heat stable grade lactic acid, 730 parts of nickel sulfate, 80 parts of organic acid, 45 parts of sodium acetate, 155 parts of sodium phosphate, 0.05 parts of wetting agent, and 0.11 parts of intermediate.

[0051] The heat-stable lactic acid is 88% lactic acid;

[0052] The organic acid is a mixture of 2-hydroxysuccinic acid and succinic acid; the 2-hydroxysuccinic acid is 50wt% of the organic acid;

[0053] Described wetting agent is sodium 2-ethylhexyl sulfate;

[0054] The intermediate is butynediol diethoxy ether.

[0055] The preparation method of the phosphorous electroless nickel plating solution in the ammonia-free environmental protection is the same as that in Example 1.

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Abstract

The invention relates to the technical field of chemical plating, in particular to an ammonia-free environment-friendly medium-phosphorus chemical nickel plating solution and a preparation method thereof. The ammonia-free environment-friendly medium-phosphorus chemical nickel plating solution comprises, by weight, 35-50 parts of heat-stable lactic acid, 700-730 parts of nickel sulfate, 70-88 partsof organic acid, 30-45 parts of sodium acetate, 120-155 parts of sodium hypophosphite, 0.02-0.05 part of wetting agent and 0.08-0.11 part of intermediate. The ammonia-free environment-friendly medium-phosphorus chemical nickel plating solution is compounded through the specific organic acid, and therefore the electroplating solution can have good high-temperature resistance after being actually electroplated on the surface of a material, the protection effect on the surface of the material in the high-temperature environment is further achieved, and the use performance of the material in thehigh-temperature environment is greatly improved.

Description

technical field [0001] The invention belongs to the technical field of electroless plating, and more specifically relates to an ammonia-free and environmentally friendly phosphorous electroless nickel plating solution and a preparation method thereof. Background technique [0002] Electroless plating is a method of forming a metal coating on the object to be plated through the oxidation-reduction reaction of the metal. It can be plated regardless of the shape of the product, and it can also be plated on insulating objects after a specific pretreatment process. Therefore, it is used in various industrial fields. [0003] The importance of surfaces plated by electroless plating is increasing in the component material industry such as mounting surfaces or bonding interfaces for ultra-small components with high density in various packaging fields. Recently, with the reduction in weight, miniaturization and high functionality of electronic products, higher density and smaller oc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C18/36
CPCC23C18/36
Inventor 邓才君
Owner 中山市美仑化工有限公司
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