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High-voltage soft polyolefin wire material for new energy automobile and preparation method thereof

A soft polyolefin and new energy vehicle technology, applied in the field of wire materials, can solve the problems of unsolved higher temperature resistance level, unstable high temperature aging, poor mechanical and physical properties, etc., and achieves low preparation cost, thermal stability and Good anti-aging effect and easy process

Active Publication Date: 2020-03-24
苏州铂玛新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The current wire and cable materials for ordinary fuel vehicles cannot meet the requirements of wire and cable materials for new energy vehicles. At present, elastomeric PVC and elastomeric polyethylene cable materials are mainly used to make new energy vehicle wires and cables on the market, but elastomeric rubber and Elastomer polyethylene materials have the following disadvantages: First, if the two materials achieve good flexibility, but poor mechanical and physical properties, if the mechanical and physical properties are good, their flexibility is average; second, high temperature aging is unstable, affecting service life
[0006] Chinese patent CN106380869A discloses a 125-degree radiation cross-linking elastomeric cable material for high-voltage lines of new energy vehicles and its preparation method. The problem of temperature resistance of TPE materials is solved by radiation cross-linking, but the temperature resistance level is only 125 ° C. For There is no solution for a higher temperature resistance level, and the investment in irradiation equipment is large, and the damage to the material is relatively large during the irradiation crosslinking process, and residual components are easily generated inside the material

Method used

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  • High-voltage soft polyolefin wire material for new energy automobile and preparation method thereof
  • High-voltage soft polyolefin wire material for new energy automobile and preparation method thereof
  • High-voltage soft polyolefin wire material for new energy automobile and preparation method thereof

Examples

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Effect test

preparation example Construction

[0030] The polyolefin wire material is prepared by irradiation crosslinking; the olefin copolymer is 1,1,1-trifluoro-2-(trifluoromethyl)-4-pentan-2-ol, 1, 3-adamantanediol monoacrylate and acrylonitrile are prepared by free radical copolymerization; the preparation method of the olefin copolymer comprises the following steps: 1,1,1-trifluoro-2-(trifluoromethyl )-4-pentan-2-ol, 1,3-adamantane diol monoacrylate, acrylonitrile, and initiator are added to the high boiling point solvent, and the reaction is stirred at 70-80°C under nitrogen or inert gas atmosphere 3- After 5 hours, it was precipitated in water, and dried to constant weight in a vacuum oven at 80-90°C to obtain an olefin copolymer.

[0031] Further, the 1,1,1-trifluoro-2-(trifluoromethyl)-4-pentan-2-ol, 1,3-adamantanediol monoacrylate, acrylonitrile, initiator, high The mass ratio of the boiling point solvent is 1:1:(2-3):(0.03-0.05):(15-24).

[0032] Further, the initiator is at least one of azobisisobutyronitril...

Embodiment 1

[0040] Embodiment 1 provides a kind of soft polyolefin wire material for new energy vehicle high voltage wire, which includes the following components by weight:

[0041]

[0042] The polyolefin wire material is prepared by irradiation crosslinking; the olefin copolymer is 1,1,1-trifluoro-2-(trifluoromethyl)-4-pentan-2-ol, 1, 3-adamantanediol monoacrylate and acrylonitrile are prepared by free radical copolymerization; the preparation method of the olefin copolymer comprises the following steps: 1,1,1-trifluoro-2-(trifluoromethyl )-4-pentan-2-ol, 1,3-adamantanediol monoacrylate, acrylonitrile, and initiator were added to a high-boiling point solvent, stirred and reacted at 70°C for 3 hours in a nitrogen atmosphere, and then precipitated in water and dried to constant weight in a vacuum oven at 80°C to obtain an olefin copolymer; the 1,1,1-trifluoro-2-(trifluoromethyl)-4-pentan-2-ol, 1, The mass ratio of 3-adamantanediol monoacrylate, acrylonitrile, initiator, and high boil...

Embodiment 2

[0049] Embodiment 2 provides a soft polyolefin wire material for high-voltage wires of new energy vehicles. Its formula and preparation method are basically the same as in Embodiment 1, except that it includes the following components in parts by weight:

[0050]

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Abstract

The invention discloses a soft polyolefin wire material for a high-voltage wire of a new energy automobile. The soft polyolefin wire material is characterized by comprising the following components inparts by weight: 15-25 parts of elastomer rubber; 15-25 parts of elastomer polyethylene; 30-50 parts of an olefin copolymer; 15-25 parts of a toughening agent; 7-12 parts of an inorganic flame retardant; 5-10 parts of an auxiliary agent; 5-10 parts of an antioxidant and 5-10 parts of a cross-linking agent; the polyolefin electric wire material is prepared in an irradiation crosslinking mode, wherein the olefin copolymer is prepared from 1, 1, 1-trifluoro-2-(trifluoromethyl)-4-pent-2-ol, 1, 3-adamantanediol monoacrylate and acrylonitrile through a free radical copolymerization reaction. According to the high-voltage soft polyolefin wire material for the new energy automobile, disclosed by the invention, the flexibility of the two materials is retained; according to the present invention, the olefin cable material can meet the use characteristics of the high-voltage line by adding the special fillers, and the irradiation cross-linking manner is used in the preparation method, such thatthe thermal stability, the aging resistance and the service life of the olefin cable material are improved.

Description

technical field [0001] The invention relates to the technical field of wire materials, in particular to a high-voltage soft polyolefin wire material for new energy vehicles and a preparation method thereof. Background technique [0002] With the deepening of the global energy crisis, the depletion of oil resources and the increasing harm of air pollution and global temperature rise, governments and automobile companies generally recognize that energy saving and emission reduction are the main direction of future automobile technology development. It is in this situation that new energy vehicles emerge as the times require. Wires for new energy vehicles are crucial to the normal operation and service life of new energy vehicles. [0003] Since the kinetic energy system of new energy vehicles is different from that of ordinary fuel vehicles, the differences between the wires used in new energy vehicles and ordinary fuel vehicles are: the high-voltage cables of electric vehicl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L33/20C08L23/06C08L75/04C08L33/04C08L83/08C08L13/00C08L23/34C08L9/02C08K13/06C08K9/06C08K3/22C08F220/44C08F220/20H01B3/44
CPCC08F220/44C08J3/246C08J3/28C08K2003/026C08K2003/2224C08L33/20C08L2201/02C08L2201/08C08L2203/202C08L2205/035C08L2312/06H01B3/447C08L23/06C08L75/04C08L33/04C08K13/06C08K9/06C08K3/2279C08F220/20C08L83/08C08L13/00C08K3/22C08L23/34C08L9/02C08K3/02
Inventor 王登辉詹芊芊
Owner 苏州铂玛新材料有限公司
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