Sulfonic acid functionalized polystyrene high-fluorescence microsphere and preparation method thereof
A polystyrene and sulfonic acid functional technology, which is applied in the field of sulfonic acid functionalized polystyrene high fluorescent microspheres and its preparation, can solve problems such as easy quenching, achieve weak interaction, strong fluorescence intensity, and not easy Aggregated effect
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Embodiment 1
[0045] A kind of preparation method of 1,7-vinyl-perylene imide derivative is as follows:
[0046] Insertion method of bulky substituent at imide position:
[0047] Add crude product PTCDA-Br in 250mL three-necked flask (0.50g, 0.91mmol) and 1-methyl-2-pyrrolidone (NMP) 15.00mL and the solid was dissolved and stirred at 25°C for 1h. Then add 2-ethylhexylamine (4.5mmol), glacial acetic acid (16mL, 140mmol). Under the protection of nitrogen, the temperature was raised to 85°C, and the reaction was continued for 7h. After the reaction was completed, it was cooled to room temperature, and then 120.00 mL of methanol was added thereto and stirred overnight. After suction filtration, a red solid was obtained, which was dried in vacuum for 24 hours at 85°C, and 1,7-Br-PDI-X was obtained after column chromatography.
[0048] The access method of the double bond substituent at the bay position:
[0049] Take 1,7-Br-PDI-X (77.4mg, 0.10mmol) in a 50mL eggplant-shaped flask, add HP...
Embodiment 2
[0052] A kind of preparation method of 1,7-vinyl-perylene imide derivative is as follows:
[0053] Insertion method of bulky substituent at imide position:
[0054] Add crude product PTCDA-Br in 250mL three-necked flask (0.50g, 0.91mmol) and 1-methyl-2-pyrrolidone (NMP) 15.00mL and the solid was dissolved and stirred at 25°C for 1h. then join (4.5mmol), glacial acetic acid (16mL, 140mmol). Under the protection of nitrogen, the temperature was raised to 85°C, and the reaction was continued for 7h. After the reaction was completed, it was cooled to room temperature, and then 120.00 mL of methanol was added thereto and stirred overnight. After suction filtration, a red solid was obtained, which was dried in vacuum for 24 hours at 85°C, and 1,7-Br-PDI-X was obtained after column chromatography.
[0055] The access method of the double bond substituent at the bay position:
[0056] Take 1,7-Br-PDI-X (77.4mg, 0.10mmol) in a 50mL eggplant-shaped flask, add HPLC grade THF (20m...
Embodiment 3
[0059] A kind of preparation method of 1,7-vinyl-perylene imide derivative is as follows:
[0060] Insertion method of bulky substituent at imide position:
[0061] Add crude product PTCDA-Br in 250mL three-necked flask (0.50g, 0.91mmol) and 1-methyl-2-pyrrolidone (NMP) 15.00mL and the solid was dissolved and stirred at 25°C for 1h. Then add 2-ethylhexylamine (4.5mmol), glacial acetic acid (16mL, 140mmol). Under the protection of nitrogen, the temperature was raised to 85°C, and the reaction was continued for 7h. After the reaction was completed, it was cooled to room temperature, and then 120.00 mL of methanol was added thereto and stirred overnight. After suction filtration, a red solid was obtained, which was dried in vacuum for 24 hours at 85°C, and 1,7-Br-PDI-X was obtained after column chromatography.
[0062] The access method of the double bond substituent at the bay position:
[0063] Take 1,7-Br-PDI-X (77.4mg, 0.10mmol) in a 50mL eggplant-shaped flask, add HP...
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