The application discloses a preparation method of elastic
semiconductor fibers and application thereof, and belongs to the field of flexible
electronic materials. In view of the fact that existing
semiconductor fibers are difficult to meet the demand of wearable
electronics on elasticity and
electrical stability, the application proposes a
general method containing material compatibility driven synergistic co-
spinning, anti-
solvent regulated nano-phase separation and swelling induced post-crosslinking, and successfully prepares
semiconductor fibers with high elasticity and high
electrical performance. The breaking strain of the
fiber can be more than 860%, and the
fiber still has almost complete elastic
recovery ability under a strain of up to 500%. After the introduction of an insulating
elastomer, the
electrical performance of the composite
fiber is even improved. The method is suitable for various conjugated
polymer systems, and the obtained elastic semiconductor fibers can be used for constructing biosensors and three-dimensional thermoelectric fabrics, and provides a general elastic semiconductor fiber construction strategy for realizing a wearable electronic
system with high performance and strong conformability.