The invention belongs to the field of synthetic polymers, and particularly relates to modified
silicone oil for regenerated
polyester staple fibers and a production process of the modified
silicone oil.
Octamethylcyclotetrasiloxane, methyl high-
hydrogen-content
silicone oil and
hydrogen-containing double end sockets are used as raw materials, and side-end
hydrogen-containing
silicone oil is prepared under the action of a catalyst;
glycidyl methacrylate is grafted into side-end hydrogen-containing
silicone oil through a
hydrosilylation reaction, side-end
epoxy silicone oil is obtained, then
polyethylene polyamine is adopted for carrying out ring opening treatment on an
epoxy group, then modified silicone oil is obtained, the modified silicone oil contains ester groups,
ether bonds and amino groups at the same time, and due to the fact that the amino groups and hydroxyl groups have high polarity, the side-end hydrogen-containing silicone
oil can be used for preparing the
epoxy silicone oil. According to the present invention, the
siloxane can interact with the hydroxyl group, the carboxyl group and other groups in the
fiber to produce the strong orientation and the strong adsorption, such that the directional arrangement of the
siloxane on the
fiber is substantially improved, and when the
siloxane is applied to the after-finishing process of the regenerated
polyester fiber fabric, the fabric can have the super soft, smooth and plump hand feeling, and further has characteristics of good
moisture absorption and good durability.