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Preparation method of high performance polyacrylonitrile fiber

A technology of polyacrylonitrile fiber and polyacrylonitrile, which is applied in the direction of fiber chemical characteristics, single-component synthetic polymer rayon, textiles and papermaking, etc., which can solve the problems of low fiber breaking strength and easy generation of fuzz, etc., and achieve reduction Static electricity, reduce the generation of fuzz, avoid the effect of increasing

Active Publication Date: 2021-05-28
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The technical problem mainly solved by the present invention is the problem that the polyacrylonitrile fiber existing in the prior art is used as the carbon fiber precursor in the preparation process of the low fiber breaking strength and the problem of easy generation of fuzz

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] 1. Coagulation and drafting: Wet spinning is used for the preparation of primary fibers. The intrinsic viscosity of the stock solution used is 1.75, and the solid content of the spinning stock solution is 22%. Spinning is carried out, and the number of spinneret holes is 12,000 to obtain coagulated fibers, followed by two-stage coagulation and drawing, and the draft ratios are 1.0 and 1.05, respectively, to obtain coagulated fibers.

[0027] 2. Washing: 1-3 washes at 55°C, 4-6 washes at 60°C, 7-9 washes at 75°C, and keep the fiber tension constant during the washing process.

[0028] 3. Hot water drawing: the temperature of the three hot water drawing is 90, 98, 99 ℃ respectively, and the drawing ratio is 1.8, 2.0, 2.4 respectively.

[0029] 4. Oiling: the oiling temperature is 35°C, without drawing.

[0030] 5. Drying and densification: Dry and densify the fibers obtained in step 4. The drying and densification temperature is in a stepwise temperature rise mode. The d...

Embodiment 2

[0035] 1. Coagulation and drafting: Wet spinning is used for the preparation of primary fibers. The intrinsic viscosity of the stock solution used is 1.75, and the solid content of the spinning stock solution is 22%. Spinning is carried out, and the number of spinneret holes is 12,000 to obtain coagulated fibers, followed by two-stage coagulation and drawing, and the draft ratios are 1.0 and 1.05, respectively, to obtain coagulated fibers.

[0036] 2. Washing: 1-3 washes at 55°C, 4-6 washes at 60°C, 7-9 washes at 75°C, and keep the fiber tension constant during the washing process.

[0037] 3. Hot water drawing: the temperature of the three hot water drawing is 90, 98, 99 ℃ respectively, and the drawing ratio is 1.8, 2.0, 2.4 respectively.

[0038] 4. Oiling: the oiling temperature is 35°C, without drawing.

[0039] 5. Drying and densification: Dry and densify the fibers obtained in step 4. The drying and densification temperature is in a stepwise temperature rise mode. The d...

Embodiment 3

[0044]1. Coagulation and drafting: Wet spinning is used for the preparation of primary fibers. The intrinsic viscosity of the stock solution used is 1.75, and the solid content of the spinning stock solution is 22%. Spinning is carried out, and the number of spinneret holes is 12,000 to obtain coagulated fibers, followed by two-stage coagulation and drawing, and the draft ratios are 1.0 and 1.05, respectively, to obtain coagulated fibers.

[0045] 2. Washing: 1-3 washes at 55°C, 4-6 washes at 60°C, 7-9 washes at 75°C, and keep the fiber tension constant during the washing process.

[0046] 3. Hot water drawing: the temperature of the three hot water drawing is 90, 98, 99 ℃ respectively, and the drawing ratio is 1.8, 2.0, 2.4 respectively.

[0047] 4. Oiling: the oiling temperature is 35°C, without drawing.

[0048] 5. Drying and densification: Dry and densify the fibers obtained in step 4. The drying and densification temperature is in a stepwise temperature rise mode. The dr...

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PUM

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Abstract

The invention relates to a method for producing polyacrylonitrile fibers, which mainly solves the problems of low breaking strength and many fluffs of polyacrylonitrile fibers in the prior art. The present invention adopts a manufacturing method of polyacrylonitrile fibers, including the step of drying and densification, the drying and densification includes at least two temperature intervals, wherein, the air humidity in the first drying and densification interval is 10-40%. The technical solution solves the problem better and can be used in the industrial production of polyacrylonitrile fibers.

Description

technical field [0001] The invention relates to a method for preparing high-performance polyacrylonitrile fibers, more specifically, the invention relates to a method for preparing high-performance polyacrylonitrile fibers suitable for preparing carbon fiber precursors. Background technique [0002] Carbon fiber is an inorganic fiber with a carbon content of 90% or more. It has a series of advantages such as light weight, high specific strength, high specific modulus, high temperature resistance, corrosion resistance, wear resistance, and fatigue resistance. Carbon fiber and various The composite material made by the composite process of the matrix has excellent performance, and has been widely used in the fields of automobile lightweight, wind power blades, sports and leisure products, etc. [0003] The precursors that can be used to prepare carbon fibers include three major raw material systems: polyacrylonitrile-based, viscose-based and pitch-based. Among them, polyacryl...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01D10/02D01D10/06D01F6/18D01F6/38
CPCD01D10/02D01D10/06D01F6/18D01F6/38
Inventor 李磊沈志刚缪金根肖士洁
Owner CHINA PETROLEUM & CHEM CORP