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Nano porous thermal insulation material matrix surface high-temperature-resistant coating and preparation method thereof, and matrix

A nanoporous, heat-insulating material technology, applied in the field of coatings, can solve problems such as mismatch between temperature resistance and substrate, oxidation, and inability to use at high temperature for a long time

Active Publication Date: 2020-06-02
AEROSPACE INST OF ADVANCED MATERIALS & PROCESSING TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The problem of aerodynamic heating has become an important constraint on the improvement of the Mach number of aerospace vehicles: during the flight of the aircraft, the intense friction between the fuselage and the atmosphere will generate a lot of heat, and the local maximum temperature can reach above 1600°C, and the high temperature will seriously oxidize and corrode. One of the solutions is to adopt a thermal protection structure and add a thermal protection body on the outside, such as: nanoporous insulation materials, but nanoporous insulation materials have poor strength due to their own structure and performance constraints , which brings some difficulties in practical application
However, the coatings currently applied on the surface of porous thermal insulation materials have the following problems: the temperature resistance does not match the substrate, the high temperature sintering is required in the preparation process, the cost is high, the coating and the substrate are poorly bonded and easy to fall off, and they cannot be used at high temperatures for a long time.

Method used

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preparation example Construction

[0038] According to the second aspect of an embodiment of the present invention, there is also provided a method for preparing the above-mentioned high temperature resistant coating, including the following steps:

[0039] Step 1. Pretreating the surface of the nanoporous heat-insulating substrate;

[0040] Step 2. Mix the components of the first heat-insulating inner layer and apply them on the surface of the substrate, and dry to obtain the first heat-insulating inner layer; then apply the components of the second heat-insulating outer layer After mixing, it can be applied to the surface of the first heat-insulating inner layer, and cured after drying.

[0041] In the above preparation method, the coating method is well known in the art, such as spray coating, brush coating, dip coating and the like.

[0042] In the above preparation method, the temperature involved in the above drying process can be selected according to the composition of the components, for example, the ...

Embodiment 1

[0052] Preparation method of high temperature resistant coating:

[0053] (1) Clean the surface of the nanoporous heat insulation brick substrate with a brush and a blade to make the surface smooth.

[0054] (2) The first layer of coating solution: Weigh the high temperature resistant component according to the mass ratio of 1:0.8:1.2:1: nano-Al 2 o 3 , Nano ZrO 2 , nano-SiO 2 , Quartz fiber, of which the quartz fiber needs to be used after grinding. Coating additives: weigh polyethylene glycol, polyvinyl butyral, and ethanol at a mass ratio of 2:1:1.5, and dissolve the above components in silicon Ultrasonic dispersion in aluminum composite sol. The second layer of coating solution: weigh the high emissivity component MoSi according to the mass ratio of 2:1 2 : SiB 4 , Add a certain amount of aluminosilicate and dispersant HYJ8101 into the composite sol, and ultrasonically disperse.

[0055] (3) Apply the first layer of coating solution on the surface of the heat insula...

Embodiment 2

[0058] Preparation method of high temperature resistant coating:

[0059] (1) Clean the surface of the nanoporous heat insulation brick substrate with a brush and a blade to make the surface smooth.

[0060] (2) The first layer of coating solution: weigh the high temperature resistant component according to the mass ratio of 2:1:1:2: nano-Al 2 o 3 , Nano ZrO 2 , nano-SiO 2 、Al 2 o 3 fiber, where Al 2 o 3 The fibers need to be ground before use. Coating additives: weigh polyethylene glycol, polyvinyl butyral, and ethanol at a mass ratio of 1:1:1.5, and dissolve the above components In the silica-alumina composite sol, ultrasonically disperse. The second layer of coating solution: weigh a certain amount of aluminosilicate, and weigh a certain amount of high emissivity components: SiC, SiB according to the mass ratio of 1:1 6 ; Weigh a certain amount of dispersant HYJ8101 into the composite sol, and ultrasonically disperse.

[0061] (3) Apply the first layer of coating ...

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Abstract

The invention provides a nano porous thermal insulation material matrix surface high-temperature-resistant coating and a preparation method thereof, and a matrix. The coating is composed of a first heat insulation inner layer and a second heat insulation outer layer applied to the first heat insulation inner layer, wherein the first heat insulation inner layer comprises an inorganic oxide sol anda high-temperature-resistant oxide, the main components of the inorganic oxide sol are consistent with the main components of a matrix, the absolute value of the difference value between the particlesize of the high-temperature-resistant oxide and the nano-pore diameter of the nano porous heat insulation material does not exceed 50 nm, and the second heat insulation outer layer includes an inorganic oxide sol, a high emissivity component and a metal oxide-containing silicate. The method comprises the following steps: mixing the components of the first heat insulation inner layer, coating thesurface of a substrate with the mixture, drying, mixing the components of the second heat insulation outer layer, coating the mixture with the mixture, drying, and curing. According to the invention,the problems that the temperature resistance of the existing porous thermal insulation material surface coating is not matched with the matrix, the high-temperature sintering cost is high in the preparation process, the binding force of the coating and the matrix is poor, the coating is easy to fall off, and the long-term high-temperature use cannot be realized can be solved.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to a high-temperature-resistant coating on the surface of a substrate of a nanoporous heat-insulating material, a preparation method and the substrate. Background technique [0002] The problem of aerodynamic heating has become an important constraint on the improvement of the Mach number of aerospace vehicles: during the flight of the aircraft, the intense friction between the fuselage and the atmosphere will generate a lot of heat, and the local maximum temperature can reach above 1600°C, and the high temperature will seriously oxidize and corrode. One of the solutions is to adopt a thermal protection structure and add a thermal protection body on the outside, such as: nanoporous insulation materials, but nanoporous insulation materials have poor strength due to their own structure and performance constraints , which brings some difficulties in practical application. In order to...

Claims

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Application Information

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IPC IPC(8): C04B41/52C09D1/00C09D7/61
CPCC04B41/52C09D1/00C09D7/61C09D5/18C04B41/5042C04B41/5035C04B41/5031C04B41/4857C04B41/4811C04B41/463C04B41/4596C04B41/4539C04B41/0072C04B41/5071C04B41/507C04B41/5032C04B41/4537C04B41/5059
Inventor 黄秀波张凡李健赵英民李文静
Owner AEROSPACE INST OF ADVANCED MATERIALS & PROCESSING TECH