This invention relates to the field of battery technology, and particularly to a core-shell material, a preparation method, a negative
electrode material, and a battery. The method provided by this invention includes
processing metal salts of aluminum, iron,
cobalt,
nickel,
zinc, and
lanthanum into high-entropy
metal oxides; using
silicon particles as the core layer, vaporizing the high-entropy
metal oxides and depositing them on the surface of the core layer to form a
coating layer to obtain Si@HEO particles; depositing a
zinc layer on the Si@HEO particles to form a growth layer on the surface of the
coating layer, then dispersing it in a Si@HEO
solvent and adding an
aqueous solution of
zinc nitrate and 2-methylimidazole to react, causing the growth layer on the surface of the
coating layer to grow a shell layer to obtain Si@HEO@ZIF particles; mixing the acidic solution with the Si@HEO@ZIF particles to form secondary channels, and then separating to obtain the core-shell material. The core-shell material provided by this invention solves the problems of
low stress dispersion efficiency, low
ion transport, and poor
volume expansion rate of existing core-shell materials.