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Nano -porous thermal insulation material substrate surface surface resistance, preparation method and matrix

A nanoporous, heat insulating material technology, applied in the field of coatings, can solve the problems of poor adhesion between the coating and the substrate, easy to fall off, corrosion, poor strength, etc., to solve the mismatch of thermal expansion coefficients, ensure long-term high-temperature use, and simplify the process flow Effect

Active Publication Date: 2022-08-09
AEROSPACE INST OF ADVANCED MATERIALS & PROCESSING TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The problem of aerodynamic heating has become an important constraint on the improvement of the Mach number of aerospace vehicles: during the flight of the aircraft, the intense friction between the fuselage and the atmosphere will generate a lot of heat, and the local maximum temperature can reach above 1600°C, and the high temperature will seriously oxidize and corrode. One of the solutions is to adopt a thermal protection structure and add a thermal protection body on the outside, such as: nanoporous insulation materials, but nanoporous insulation materials have poor strength due to their own structure and performance constraints , which brings some difficulties in practical application
However, the coatings currently applied on the surface of porous thermal insulation materials have the following problems: the temperature resistance does not match the substrate, the high temperature sintering is required in the preparation process, the cost is high, the coating and the substrate are poorly bonded and easy to fall off, and they cannot be used at high temperatures for a long time.

Method used

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Examples

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Comparison scheme
Effect test

preparation example Construction

[0038] According to the second aspect of the embodiment of the present invention, there is also provided a preparation method of the above-mentioned high temperature resistant coating, comprising the following steps:

[0039] Step 1, pretreating the surface of the nanoporous heat insulating substrate;

[0040] Step 2: Mix the components of the first thermal insulation inner layer and apply it to the surface of the substrate, and then dry to obtain the first thermal insulation inner layer; and then combine the components of the second thermal insulation outer layer. After mixing, it is applied to the surface of the first thermal insulation inner layer, and then cured after drying.

[0041] In the above preparation method, the coating method is known in the art, for example, spray coating, brush coating, dip coating and the like.

[0042] In the above preparation method, the temperature involved in the above drying process can be selected according to the composition of the com...

Embodiment 1

[0052] Preparation method of high temperature resistant coating:

[0053] (1) Use a brush and a blade to clean the surface of the nanoporous thermal insulation brick substrate to make the surface smooth.

[0054] (2) The first layer of coating solution: Weigh the high temperature resistant component according to the mass ratio of 1:0.8:1.2:1: nano-Al 2 O 3 , Nano ZrO 2 , Nano SiO 2 , Quartz fiber, in which the quartz fiber needs to be ground before use. Coating auxiliary: Weigh polyethylene glycol, polyvinyl butyral, and ethanol in a mass ratio of 2:1:1.5, and dissolve the above components in silicon In the aluminum composite sol, ultrasonic dispersion. The second layer coating solution: Weigh the high emissivity component MoSi according to the mass ratio of 2:1 2 : SiB 4 , add a certain amount of aluminosilicate and dispersant HYJ8101 into the composite sol, and ultrasonically disperse.

[0055] (3) Coat the first layer of coating solution on the surface of the thermal...

Embodiment 2

[0058] Preparation method of high temperature resistant coating:

[0059] (1) Use a brush and a blade to clean the surface of the nanoporous thermal insulation brick substrate to make the surface smooth.

[0060] (2) The first layer of coating solution: weigh the high temperature resistant component according to the mass ratio of 2:1:1:2: nano-Al 2 O 3 , Nano ZrO 2 , Nano SiO 2 , Al 2 O 3 fibers, where Al 2 O 3 The fibers need to be ground before use. Coating additives: Weigh polyethylene glycol, polyvinyl butyral, and ethanol in a mass ratio of 1:1:1.5. dispersion. Second layer coating solution: Weigh a certain amount of aluminosilicate, and weigh a certain amount of high emissivity components in a mass ratio of 1:1: SiC, SiB 6 ; Weigh a certain amount of dispersant HYJ8101 into the composite sol, and ultrasonically disperse.

[0061] (3) Coat the first layer of coating solution on the surface of the substrate, dry at 40 °C for 2 hours, then apply the second layer o...

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Abstract

The invention provides a high temperature resistant coating on the surface of a nanoporous heat insulating material substrate, a preparation method and the substrate. The coating consists of a first heat insulating inner layer and a second heat insulating outer layer applied thereon. The layer includes inorganic oxide sol and high temperature resistant oxide. The main components of the inorganic oxide sol are consistent with the main components of the matrix. The insulating outer layer includes an inorganic oxide sol, a high emissivity component, and a metal oxide-containing silicate. The method includes: mixing the components of the first thermal insulation inner layer and coating the surface of the substrate, drying the components of the second thermal insulation outer layer, mixing and coating the components, and curing after drying. The invention can solve the problems existing in the surface coating of the current porous heat insulating material: the temperature resistance performance does not match the substrate, the high temperature sintering is required in the preparation process, the cost is high, the bonding force between the coating and the substrate is poor and easy to fall off, and the long-term high temperature cannot be used.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to a high temperature resistant coating on the surface of a nanoporous heat insulating material substrate, a preparation method and the substrate. Background technique [0002] The problem of aerodynamic heating has become an important constraint on the improvement of the Mach number of the spacecraft: during the flight of the aircraft, the violent friction between the fuselage and the atmosphere will generate a lot of heat, and the local maximum temperature can reach more than 1600 ° C, and the high temperature will cause serious oxidation and corrosion. One of the solutions is to adopt a thermal protection structure and add a thermal protection body to the outside, such as nanoporous thermal insulation materials, but nanoporous thermal insulation materials have poor strength due to their own structure and performance constraints. , which brings certain difficulties in practical a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B41/52C09D1/00C09D7/61
CPCC04B41/52C09D1/00C09D7/61C09D5/18C04B41/5042C04B41/5035C04B41/5031C04B41/4857C04B41/4811C04B41/463C04B41/4596C04B41/4539C04B41/0072C04B41/5071C04B41/507C04B41/5032C04B41/4537C04B41/5059
Inventor 黄秀波张凡李健赵英民李文静
Owner AEROSPACE INST OF ADVANCED MATERIALS & PROCESSING TECH