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Methanol synthesis system and methanol synthesis method

A technology of methanol synthesis and synthesis tower, which is applied in chemical instruments and methods, preparation of hydroxyl compounds, and preparation of organic compounds, etc. It can solve the problems of waste, exhaust gas residual pressure and waste heat not collected and utilized, and low single-pass conversion rate. Achieve the effect of reducing energy waste and industrial emissions, improving the total carbon conversion rate, and simple process

Pending Publication Date: 2020-07-03
河北金牛旭阳化工有限公司
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Problems solved by technology

There are many ways to synthesize methanol. At present, natural gas, coal gas, and coke oven gas are used in China to produce methanol, all of which belong to the technology of synthesis gas under high temperature, high pressure and catalyst action. The reaction rate is low. After the reacted gas is cooled to separate the liquid, most of the unreacted gas is used as a cycle gas, which needs to be pressurized in the combined compressor, and mixed with the pressurized raw material gas to enter the methanol synthesis system. continue to synthesize methanol
In addition, a small amount of gas is discharged as purge gas, which is used as fuel gas after being decompressed to normal pressure. The residual pressure and waste heat of the purge gas are not collected and utilized, resulting in waste

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  • Methanol synthesis system and methanol synthesis method

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[0042] The embodiment of the present invention also provides a methanol synthesis method, the methanol synthesis method comprises the following steps:

[0043] S100: The raw material gas pressurized by the booster expander 1 enters the multi-stage methanol synthesis unit 2, and utilizes the heat of the reaction gas flowing through the gas-gas heat exchanger 4 of the first-stage methanol synthesis unit to convert the raw material gas to warm up.

[0044] It can be understood that the gas-gas heat exchanger 4 is used to preheat the raw material gas pressurized by the booster expander 1, for example, after the gas-gas heat exchanger 4 preheats the raw material gas to 200°C to 230°C Then enter the synthesis tower 3 for reaction, and the reacted reaction gas enters the gas-gas heat exchanger 4 and can be used as a heat source for preheating the above-mentioned raw material gas.

[0045] S200: The preheated raw material gas enters the synthesis tower 3 through the tube side of the ...

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Abstract

The invention provides a methanol synthesis system and a methanol synthesis method. The methanol synthesis system comprises a booster expander, a multi-stage methanol synthesis device and a heater. Afeed gas inlet is formed in the booster expander; each stage of methanol synthesis device comprises a synthesis tower, a gas-gas heat exchanger, a water cooler and a methanol separator, which are connected in sequence; the gas-gas heat exchanger of the first-stage methanol synthesis device is communicated with the booster expander, and the gas-gas heat exchangers of the other stages of the methanol synthesis device except the first-stage of the methanol synthesis device are all communicated with the methanol separator of the previous stage of the methanol synthesis device. The heater is respectively connected with the methanol separator of the last stage of the methanol synthesis device and the booster expander, the purge gas separated by the methanol separator enters the heater and is heated, the residual pressure and residual heat of the purge gas are utilized to pressurize the feed gas flowing through the booster expander, and the aims of improving the total carbon conversion rate,saving energy and reducing consumption are fulfilled.

Description

technical field [0001] The invention belongs to the technical field of methanol synthesis technology, and in particular relates to a methanol synthesis system and a methanol synthesis method. Background technique [0002] Methanol, commonly known as "wood alcohol", is not only an important basic chemical raw material, widely used in pesticides, medicines, coatings and national defense industries, but also a new type of energy, used as a clean liquid fuel to reduce environmental pressure. There are many ways to synthesize methanol. At present, natural gas, coal gas, and coke oven gas are used in China to produce methanol, all of which belong to the technology of synthesis gas under high temperature, high pressure and catalyst action. The reaction rate is low. After the reacted gas is cooled to separate the liquid, most of the unreacted gas is used as a cycle gas, which needs to be pressurized in the combined compressor, and mixed with the pressurized raw material gas to enter...

Claims

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Application Information

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IPC IPC(8): C07C29/152C07C29/76C07C31/04
CPCC07C29/152C07C29/76C07C31/04Y02P20/10
Inventor 郭俊强王灵清李庆华郎莹李浩伟石志哲孔力军张燕王海平
Owner 河北金牛旭阳化工有限公司
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