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Graphene composite material for removing formaldehyde and preparation method of graphene composite material

A composite material and graphene technology, applied in the direction of separation methods, chemical instruments and methods, carbon compounds, etc., can solve the problems that the demand for formaldehyde removal is far apart, the removal rate of formaldehyde is not ideal, etc., and achieve the effect of complete removal

Pending Publication Date: 2020-08-07
河南智川节能环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the formaldehyde removal rate of this catalyst is not ideal, the highest is only 92.1%, which is far from people's demand for formaldehyde removal

Method used

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  • Graphene composite material for removing formaldehyde and preparation method of graphene composite material

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Effect test

Embodiment 1

[0032] A method for preparing a formaldehyde-removing graphene composite material. First, titanium carbonitride is modified with γ-methacryloxypropyltrimethoxysilane to obtain modified titanium carbonitride, and then silicon, Boron co-doped graphene is modified with 3-aminopropyltriethoxysilane to obtain modified graphene, and finally modified titanium oxycarbonitride, modified graphene and modified silica gel are mixed and reacted to obtain the described A formaldehyde-removing graphene composite material; wherein, the modified silica gel is obtained by modifying silica gel with 3-aminopropyltrihydroxysilane.

[0033] The titanium oxycarbonitride is obtained by heating titanium carbonitride in an inert gas containing oxygen, wherein the dosages of titanium oxycarbonitride, oxygen and inert gas are 1g, 1L, and 6L respectively, and the inert gas is helium , the heating condition is: heating at 1100° C. for 7 hours.

[0034]The preparation method of modified titanium oxycarboni...

Embodiment 2

[0045] A method for preparing a formaldehyde-removing graphene composite material. Firstly, titanium carbonitride is modified with γ-methacryloxypropyltrimethoxysilane to obtain modified titanium carbonitride, and then silicon, Boron co-doped graphene is modified with 3-aminopropyltriethoxysilane to obtain modified graphene, and finally modified titanium oxycarbonitride, modified graphene and modified silica gel are mixed and reacted to obtain the described A formaldehyde-removing graphene composite material; wherein, the modified silica gel is obtained by modifying silica gel with 3-aminopropyltrihydroxysilane.

[0046] The titanium oxycarbonitride is obtained by heating titanium carbonitride in an inert gas containing oxygen, wherein the dosages of titanium oxycarbonitride, oxygen and inert gas are 1g, 1L, and 7L respectively, and the inert gas is argon , the heating condition is: heating at 1000°C for 8 hours.

[0047] The preparation method of modified titanium oxycarboni...

Embodiment 3

[0058] A method for preparing a formaldehyde-removing graphene composite material. Firstly, titanium carbonitride is modified with γ-methacryloxypropyltrimethoxysilane to obtain modified titanium carbonitride, and then silicon, Boron co-doped graphene is modified with 3-aminopropyltriethoxysilane to obtain modified graphene, and finally modified titanium oxycarbonitride, modified graphene and modified silica gel are mixed and reacted to obtain the described A formaldehyde-removing graphene composite material; wherein, the modified silica gel is obtained by modifying silica gel with 3-aminopropyltrihydroxysilane.

[0059] The titanium oxycarbonitride is obtained by heating titanium carbonitride in an inert gas containing oxygen, wherein the dosages of titanium oxycarbonitride, oxygen and inert gas are 1g, 1L, and 6.5L respectively, and the inert gas is helium gas, and the heating condition is: heating at 1050°C for 7.5 hours.

[0060] The preparation method of modified titaniu...

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PUM

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Abstract

The invention provides a graphene composite material for removing formaldehyde and a preparation method of the graphene composite material. The preparation method comprises the steps: firstly, carrying out modification treatment on titanium oxycarbonitride by utilizing gamma-methacryloxypropyltrimethoxysilane to obtain modified titanium oxycarbonitride; then carrying out modification treatment onsilicon and boron co-doped graphene by utilizing 3-aminopropyltriethoxysilane to obtain modified graphene; and finally, carrying out mixing reaction on the modified titanium oxycarbonitride, the modified graphene and the modified silica gel to obtain the graphene composite material. The modified silica gel is obtained by carrying out modification treatment on silica gel by utilizing 3-aminopropyltrihydroxysilane. The graphene composite material can catalytically oxidize formaldehyde into harmless carbon dioxide and water at normal temperature, and formaldehyde can be thoroughly removed in a short time.

Description

technical field [0001] The invention relates to the technical field, in particular to a graphene composite material for removing formaldehyde and a preparation method thereof. Background technique [0002] Formaldehyde is a colorless gas with a strong pungent odor at normal temperature and pressure, and is easily soluble in water, alcohols and ethers. Indoor decoration materials, such as wood-based panels and products, paints and carpets, etc., mostly use formaldehyde in the production process. Due to the above-mentioned characteristics of formaldehyde, these materials will release formaldehyde and pollute the indoor air. [0003] Formaldehyde is one of the indoor air pollutants, which is highly toxic and irritating, and is extremely harmful to human health. Formaldehyde is easily absorbed by the respiratory tract and gastrointestinal tract due to its high water solubility in water. If the human body is exposed to low-dose formaldehyde for a long time, it can cause chronic...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J31/02B01J35/04B01D53/86B01D53/72C01B32/194
CPCB01J31/0274B01J31/0275B01D53/8628C01B32/194B01J2231/70B01D2257/708B01J35/56
Inventor 石英楠
Owner 河南智川节能环保科技有限公司
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