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A kind of brine refining scale inhibitor and dispersant and its preparation method and application

A scale inhibitor dispersant and brine technology, applied in the field of scale inhibitors, can solve the problems of low removal rate, limited use range of removal means, high removal cost, etc., achieve simple formula, ensure scale inhibition effect, and be environmentally friendly

Active Publication Date: 2022-08-02
四川鸿康科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The object of the present invention is to: the CaSO2 that exists in the process of refining brine when making salt in the prior art is low to the removal rate of calcium, magnesium, sulfate radical etc., waste residue is many and forms 4 , CaCO 3 Such technical problems as extremely easy to accumulate and form scale, high removal cost, and limited application range of removal means, the present invention provides a scale inhibitor dispersant and its preparation method and application. The scale inhibitor dispersant is used in the brine refining process, Can effectively prevent CaSO 4 , CaCO 3 Crystals are naturally formed on the surface of equipment pipes to form scales, but after they are dispersed, they are discharged in a controlled manner at the subsequent settlement site, avoiding CaSO 4 , CaCO 3 Such substances continue to accumulate and scale, causing equipment and pipeline blockage, greatly reducing the volume of the vacuum tank, low heat transfer efficiency, and high energy consumption. At the same time, the scale inhibitor dispersant has the advantages of low cost, easy industrial application, and environmental friendliness.

Method used

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  • A kind of brine refining scale inhibitor and dispersant and its preparation method and application
  • A kind of brine refining scale inhibitor and dispersant and its preparation method and application
  • A kind of brine refining scale inhibitor and dispersant and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] Scale inhibitor and dispersant, the composition is as follows (mass percentage):

[0045]

[0046] The aforementioned itaconic acid-acrylic acid copolymer solution is an aqueous solution with a mass fraction of 30%, the maleic anhydride-acrylic acid copolymer solution is an aqueous solution with a mass fraction of 50%, and the polyaspartic acid solution is a mass fraction of 40%. The content of succinic acid solution is 40% by mass, and the stabilizer is Na 2 SO 3 .

[0047] Preparation process: first, add 100% of the water usage to the reaction kettle, and add a stabilizer (Na 2 SO 3 ), stirred for 15min, successively added itaconic acid-acrylic acid copolymer solution, maleic anhydride-acrylic acid copolymer solution, polyaspartic acid solution, polyepoxysuccinic acid solution in proportion, and stirred for 15min to obtain the brine refining scale inhibition Dispersant. All operations were performed at room temperature.

[0048] Experimental research results:...

Embodiment 2-6

[0132] Based on the research on the mixing ratio of the four raw materials in Test 2.9, it was found that the itaconic acid-acrylic acid copolymer solution, the maleic anhydride-acrylic acid copolymer, the polyaspartic acid solution, and the polyepoxysuccinic acid solution When the mass ratio of raw materials is 4:2:1:0.5~1.5, the scale inhibition rate reaches more than 77%, and when the raw material ratio is 4:2:1:1, the maximum scale inhibition rate is 81.98. Example 2-6 also studied the influence of other proportions on the scale inhibition rate performance of the product. The preparation process of the scale inhibitor and dispersant in Example 2-6, the total mass of the scale inhibitor and dispersant, the mass content of the stabilizer, and the quality of the water were the same. The content is the same as in test 2.9, only the mass ratio, mass ratio and scale inhibition of itaconic acid-acrylic acid copolymer solution, maleic anhydride-acrylic acid copolymer, polyaspartic ...

Embodiment 7

[0137] Brine refining scale inhibitor and dispersant, the composition is as follows (mass percentage):

[0138]

[0139]

[0140] The aforementioned itaconic acid-acrylic acid copolymer solution is an aqueous solution with a content of 33%, the maleic anhydride-acrylic acid copolymer is an aqueous solution with a content of 48%, the polyaspartic acid solution is an aqueous solution with a content of 41%, and the polyepoxysuccinic acid solution has a content of 40%, stabilizer is Na 2 SO 3 .

[0141]Preparation process: first, add 100% of the water usage to the reaction kettle, and add a stabilizer (Na 2 SO 3 ), stirred for 12min, successively added itaconic acid-acrylic acid copolymer solution, maleic anhydride-acrylic acid copolymer, polyaspartic acid solution, polyepoxysuccinic acid solution in proportion, and stirred for 15min to obtain the brine refining scale inhibition dispersion agent. All operations were performed at room temperature.

[0142] Measure 0.032...

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Abstract

The invention relates to a brine-refined scale inhibitor and dispersant, a preparation method and application thereof. The brine-refined scale inhibitor and dispersant is mainly prepared from the following raw materials in mass percentage: itaconic acid-acrylic acid copolymer solution 20%-60% %; maleic anhydride-acrylic acid copolymer solution 5%-30%; polyaspartic acid solution 5%-20%; polyepoxysuccinic acid solution 5%-20%; stabilizer 0.5%-2%; water 5 %~25%; the present invention selects itaconic acid-acrylic acid copolymer solution, maleic anhydride-acrylic acid copolymer solution, polyaspartic acid solution, polyepoxysuccinic acid solution and stabilizer, water as scale inhibitor and dispersant raw materials, and screen the proportion of each component, which can be used for CaSO produced in the process of refining and separating calcium, magnesium and sulfate ions from brine. 4 , CaCO 3 and other substances play an excellent scale inhibition and dispersion effect, effectively preventing CaSO 4 , CaCO 3 Crystals naturally form on the surface of equipment pipes to form scale.

Description

technical field [0001] The invention belongs to the technical field of scale inhibitors, and particularly relates to a brine refining scale inhibitor and dispersant and a preparation method and application thereof. Background technique [0002] The scientific name of brine is salt brine, which is a mixture of sodium chloride, calcium chloride, magnesium sulfate, etc. The brine often contains Na + , Ca 2+ , Mg 2+ , Cl - , SO 4 2- , CO 3 2- , HCO 3 - Plasma, in terms of vacuum salt production, the existence of calcium, magnesium and sulfate will not only affect product quality, but also calcium, magnesium, sulfate and other substances in the production process as calcium sulfate, magnesium sulfate, sodium sulfate, calcium carbonate. The form of isocrystalline adheres to the surface of system equipment and pipelines, resulting in a series of problems such as fouling and blockage, greatly reducing the volume of the vacuum tank, low heat transfer efficiency, and high ene...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F5/12
CPCC02F5/12
Inventor 殷捷郑文强李平杨慧林龙红梅贺飞燕
Owner 四川鸿康科技股份有限公司
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