A kind of high specific power thermal battery single cell and preparation method thereof
A single battery, high specific power technology, applied in the electrodes of primary batteries, battery electrodes, primary battery use/maintenance, etc. Large and other problems, to achieve the effect of good high-current discharge characteristics, low internal resistance, and low equipment cost
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Examples
Embodiment 1
[0028] Embodiment 1: The preparation method of high specific power thermal battery single cell, comprising the following steps:
[0029] 1) Cleaning and deoxidation of materials: prepare foam copper, aluminum foil and nickel foil, put them into 0.1mol / L hydrochloric acid for cleaning for 2 minutes, and put them into a vacuum drying oven to dry after cleaning; the area of foam copper is 18.08cm 2 , the thickness is 1mm, the aperture is 0.3mm, and the porosity is 85%;
[0030] 2) Preparation of Cu-CuO-V 2 O 5 Positive electrode material: the NH 4 VO 3 Put it in water at 50°C and configure it as NH 4 VO 3 Saturated solution; put in the copper foam prepared in step 1), then heat up to 90°C and hold for 120min; take out the copper foam and put it in an oven at 60°C for 8 hours, then transfer it to a tube furnace at 600°C for 4 hours, and finally at 10MPa The pressure is pressed down to a thickness of 0.18mm;
[0031] 3) Preparation of boron nitride fiber composite diaphrag...
Embodiment 2
[0035] Embodiment 2: The preparation method of high specific power thermal battery single cell, comprising the following steps:
[0036] 1) Cleaning and deoxidation of materials: prepare foam copper, aluminum foil and nickel foil, put them into 0.3mol / L hydrochloric acid for cleaning for 1 min, and put them into a vacuum drying oven to dry after cleaning; the area of foam copper is 18.08cm 2 , the thickness is 2mm, the aperture is 0.5mm, and the porosity is 90%;
[0037] 2) Preparation of Cu-CuO-V 2 O 5 Positive electrode material: the NH 4 VO 3 Put in water at 70°C and prepare NH 4 VO 3 Saturated solution; put in the copper foam prepared in step 1), then heat up to 90°C and hold for 60min; take out the copper foam and put it in an oven at 100°C for calcination for 18h, then transfer it to a tube furnace at 600°C for 4 hours, and finally at 30MPa Press down to a thickness of 0.2mm under the pressure;
[0038] 3) Preparation of boron nitride fiber composite diaphragm: ...
Embodiment 3
[0041] Embodiment 3: The preparation method of high specific power thermal battery single cell, comprising the following steps:
[0042] 1) Cleaning and deoxidation of materials: prepare foam copper, aluminum foil and nickel foil, put them into 0.1mol / L hydrochloric acid for cleaning for 2 minutes, and put them into a vacuum drying oven to dry after cleaning; the area of foam copper is 18.08cm 2 , the thickness is 0.5mm, the aperture is 0.1mm, and the porosity is 82%;
[0043] 2) Preparation of Cu-CuO-V 2 O 5 Positive electrode material: the NH 4 VO 3 Put in water at 60°C and prepare NH 4 VO 3 Saturated solution; put in the foamed copper prepared in step 1), then heat up to 90 °C and hold for 120 min; take out the foamed copper, put it in an oven at 100 °C for 2 hours, then transfer it to a tube furnace at 600 °C for 2 hours, and finally at 10MPa Under the pressure, it is thinned to a thickness of 0.15mm;
[0044] 3) Preparation of boron nitride fiber composite diaphr...
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Abstract
Description
Claims
Application Information
- IPC
- H01M50/44; H01M50/446; H01M50/403; H01M4/06; H01M4/08; H01M4/36; H01M6/36; H01M6/50; H01M50/431
- CPC
- H01M4/06; H01M4/08; H01M6/5038; H01M6/36; H01M50/431; H01M50/44; H01M50/403; H01M50/449
- Inventors
- 王明灿; 冉岭