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Hydrogenation device oil-soluble corrosion inhibitor and preparation method and application thereof

An oil-soluble corrosion inhibitor and hydrogenation device technology, which is applied in the direction of corrosion/fouling treatment equipment, petroleum industry, and hydrocarbon oil treatment, and can solve the problems of oil product quality, poor corrosion inhibition effect, and poor product stability.

Inactive Publication Date: 2020-10-27
广东粤首新科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to provide an oil-soluble corrosion inhibitor for a hydrogenation unit and its preparation method and application, so as to solve the problem of poor corrosion inhibition effect in the above-mentioned background technology, which easily emulsifies the oil product and affects the quality of the oil product , and the product stability is poor, and at the same time, it is impossible to improve the dew point corrosion in the condensation process of the condensation cooling system at the top of the hydrogenation tower

Method used

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  • Hydrogenation device oil-soluble corrosion inhibitor and preparation method and application thereof

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preparation example Construction

[0040] A preparation method of an oil-soluble corrosion inhibitor for a hydrogenation unit, comprising the following parts by weight:

[0041] Pure ethanol: 77 parts;

[0042] Isopropanol: 10 parts;

[0043] Active agent: 10 parts;

[0044] Organic corrosion inhibitor: 10 parts;

[0045] Water: 60 parts;

[0046] Ethylenediamine: 31 parts;

[0047] Neutralizer: 1 part.

[0048] Further, the organic corrosion inhibitor is one or a mixture of cis oleylamine ethyl imidazoline, trans oleylamine ethyl imidazoline, and oleylamine ethyl imidazoline.

[0049] Further, the organic corrosion inhibitor is cis oleyl amine ethyl imidazoline, trans oleyl amine ethyl imidazoline and oleyl amine ethyl imidazoline according to the molar ratio of 1-2:1-2:1- 2 composition mixture.

[0050] Further, the neutralizing agent is polyethylene polyamine, and the polyethylene polyamine is one or a mixture of diethylenetriamine, triethylenetetramine and tetraethylenepentamine.

[0051] Further, t...

Embodiment 1

[0064] An oil-soluble corrosion inhibitor for a hydrogenation unit comprises the following components: pure ethanol, isopropanol, active agent, organic corrosion inhibitor, water, ethylenediamine and neutralizing agent.

[0065] A preparation method of an oil-soluble corrosion inhibitor for a hydrogenation unit, comprising the following parts by weight:

[0066] Pure ethanol: 78 parts;

[0067] Isopropanol: 11 parts;

[0068] Active agent: 11 parts;

[0069] Organic corrosion inhibitor: 11 parts;

[0070] Water: 63 parts;

[0071] Ethylenediamine: 36 parts;

[0072] Neutralizer: 3 parts.

[0073] Further, the organic corrosion inhibitor is one or a mixture of cis oleylamine ethyl imidazoline, trans oleylamine ethyl imidazoline, and oleylamine ethyl imidazoline.

[0074] Further, the organic corrosion inhibitor is cis oleyl amine ethyl imidazoline, trans oleyl amine ethyl imidazoline and oleyl amine ethyl imidazoline according to the molar ratio of 1-2:1-2:1- 2 compositi...

Embodiment 2

[0089] An oil-soluble corrosion inhibitor for a hydrogenation unit comprises the following components: pure ethanol, isopropanol, active agent, organic corrosion inhibitor, water, ethylenediamine and neutralizing agent.

[0090] A preparation method of an oil-soluble corrosion inhibitor for a hydrogenation unit, comprising the following parts by weight:

[0091] Pure ethanol: 79 parts;

[0092] Isopropanol: 13 parts;

[0093] Active agent: 13 parts;

[0094] Organic corrosion inhibitor: 13 parts;

[0095] Water: 67 parts;

[0096] Ethylenediamine: 41 parts;

[0097] Neutralizer: 4 parts.

[0098] Further, the organic corrosion inhibitor is one or a mixture of cis oleylamine ethyl imidazoline, trans oleylamine ethyl imidazoline, and oleylamine ethyl imidazoline.

[0099] Further, the organic corrosion inhibitor is cis oleyl amine ethyl imidazoline, trans oleyl amine ethyl imidazoline and oleyl amine ethyl imidazoline according to the molar ratio of 1-2:1-2:1- 2 compositi...

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Abstract

The invention relates to the technical field of oil-soluble corrosion inhibitors, in particular to a hydrogenation device oil-soluble corrosion inhibitor which is characterized by comprising the following components in parts by weight: 78-80 parts of pure ethanol, 10-20 parts of isopropanol, 10-20 parts of an active agent, 10-20 parts of an organic corrosion inhibitor, 10-20 parts of water, 1-3 parts of ethylenediamine and 1-3 parts of a neutralizer. 10 to 15 parts of isopropanol; 10 to 15 parts of an active agent; 10 to 15 parts of an organic corrosion inhibitor; 60 to 70 parts of water; 31 to 45 parts of ethylenediamine; and 1-5 parts of a neutralizer. The corrosion inhibitor has the beneficial effects that the oil-soluble corrosion inhibitor is finally prepared from pure ethanol, isopropanol, an active agent, organic corrosion inhibitor water, ethylenediamine and a neutralizer. The corrosion inhibitor has the advantages of favorable corrosion inhibition effect, favorable film-forming property, high hydrogen sulfide corrosion resistance, no oil emulsification, no oil precipitation and no adverse influence on the oil quality, and the adopted neutralizer is polyethylene polyamine,and can perform a neutralization action with an acidic neutralizing medium.

Description

technical field [0001] The invention relates to the technical field of oil-soluble corrosion inhibitors, in particular to an oil-soluble corrosion inhibitor for a hydrogenation unit and its preparation method and application. Background technique [0002] Crude oil becomes heavier and thicker and the demand for light oil products continues to increase. Heavy oil processing has become the main problem faced by modern refineries. Currently, heavy oil processing mainly includes delayed coking, viscracking, catalytic cracking and heavy oil hydrogenation. , the hydrogenation process is a deep processing technology for heavy oil. Under the action of hydrogen and catalysts, desulfurization, denitrification, and metallization are carried out on atmospheric or vacuum residual oil to obtain light products to the maximum extent. Through combined hydrogenation and upgrading Technology can further optimize product quality and improve product quality. With the improvement of domestic envi...

Claims

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Application Information

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IPC IPC(8): C10G75/02
CPCC10G75/02C10G2300/80
Inventor 付海明叶显孟傅小川李兆军
Owner 广东粤首新科技有限公司
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