Novel environment-friendly composite material for air purification and preparation method thereof
A new material and environmentally friendly technology, applied in chemical instruments and methods, separation methods, gas treatment, etc., can solve the problems of poor removal of heavy metal pollutants, worsening the environment, and achieve excellent cleaning durability and reusability. Slowing uptrend effects of slowing uptrends, resistance pressure drops
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[0028] A method for preparing an environmentally friendly new composite material, comprising: under the condition that the nanofiltration layer is supported, a microfiltration layer and a primary filtration layer are arranged on the surface of the nanofiltration layer to obtain a new composite material with a "sandwich" structure;
[0029] The above-mentioned primary filter layer is a three-dimensional graphene airgel material prepared by self-assembly of polyethyleneimine and graphite oxide;
[0030] The above-mentioned microfiltration layer is a micron fiber layer made of chitosan solution by electrospinning; the above-mentioned micron fiber layer is loaded with functional ceramic materials and activated carbon in the presence of thiolactic acid and sodium benzoate;
[0031]The above-mentioned nanofiltration layer is a nanofiber layer made of chitosan solution through electrospinning; the fibers of the above-mentioned nanofiber layer are doped with silica particles; the fiber...
Embodiment 1
[0053] A preparation method of an environmentally friendly composite new material, comprising the following specific steps:
[0054] 1) Ultrasonic disperse the graphene oxide solid in water for 1 hour to obtain a suspension with a concentration of 3 g / L, then add polyethyleneimine to the suspension to form a mixed solution, and then react the mixed solution at 85°C for 2 hours to obtain water Gel, then rinse the hydrogel, freeze-dry at -50°C for 24 hours, and then vacuum-dry at -50°C to obtain a three-dimensional graphene airgel material, that is, the primary filter layer, the above mixing The average molecular weight of polyethyleneimine in the solution is 3000Da, and the weight ratio of polyethyleneimine and graphene oxide is 13.5:1;
[0055] 2) Chitosan and polyoxyethylene are mixed, then adding concentration is the acetic acid aqueous solution of 50wt%, stirring and dissolving, make the base liquid for electrospinning, standby, chitosan and polyoxyethylene content are resp...
Embodiment 2
[0061] A preparation method of an environmentally friendly composite new material, other steps are consistent with Example 1, the only difference is: step 5) the spinning solution for preparing the nanofiltration layer also contains 0.05wt% ethambutol and 0.25wt% salicylic acid aldehyde.
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