Unlock instant, AI-driven research and patent intelligence for your innovation.

Cadmium-contaminated soil and underground water remediation agent and remediation method thereof for cadmium-contaminated soil and underground water

A technology for remediation of cadmium-contaminated soil and groundwater, applied in the field of soil and groundwater environmental remediation, can solve the problems of slow corrosion and low cadmium removal efficiency, and achieves the effect of enhancing effective adsorption and solving poor effects

Inactive Publication Date: 2020-12-29
SOUTH CHINA UNIV OF TECH
View PDF11 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0012] Aiming at the problems of slow corrosion and low cadmium removal efficiency of zero-valent iron when repairing cadmium-contaminated soil and groundwater, the invention provides a cadmium-contaminated soil and groundwater restoration agent and its restoration method

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Cadmium-contaminated soil and underground water remediation agent and remediation method thereof for cadmium-contaminated soil and underground water
  • Cadmium-contaminated soil and underground water remediation agent and remediation method thereof for cadmium-contaminated soil and underground water
  • Cadmium-contaminated soil and underground water remediation agent and remediation method thereof for cadmium-contaminated soil and underground water

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] A cadmium-contaminated soil and groundwater remediation agent and a remediation method thereof, comprising the following steps:

[0048] Collect 2kg of urban sludge, adjust the sludge concentration to 10-20g / L with clean water, add 1g / L of glucose and 2g / L of sodium nitrate. The supernatant was replaced every day, and glucose 1g / L and sodium nitrate 2g / L were added. After 14d, the sludge was transferred to an anaerobic incubator, with the ratio of N 2 :H 2 :CO 2 =85%:10%:5% mixed gas, the sludge was cultivated under the conditions of nitrate concentration of 2g / L and 25°C. After six months of cultivation, the sludge and culture solution were separated by centrifugation, and the sludge in the middle of the sludge layer was taken as the inoculum sludge of 1 / 3 thickness for domestication and expansion in the anaerobic reactor. The inoculum concentration of the sludge was 10g / L, add clear water, 20g / L zero-valent iron powder (particle size 0.15mm), 50mg / L glucose, 85mg / ...

Embodiment 2

[0055] A cadmium-contaminated soil and groundwater remediation agent and a remediation method thereof, comprising the following steps:

[0056] The preparation method of the restoration agent is as described in Example 1.

[0057] Prepare 250mL cadmium-contaminated groundwater samples with deoxygenated water in an anaerobic reactor, where Cd 2+ The concentration is 10mg / L, NO 3 - -N concentration is 0, 7, 14, 28, 56mg / L respectively, adjust pH to 7.0, add repair agent containing zero-valent iron and microorganisms (wherein the content of zero-valent iron in the sample is 1g / L, microorganisms in the sample The content in the reactor is 50mg / L), use nitrogen to exhaust the air in the reactor, and then seal it and place it at 25°C for 5d. At 0d, 0.5d, 1d, 2d, 3d, 4d and 5d after the start of the reaction, 5mL water samples were taken from the reactor and filtered through a 0.22μm filter membrane for the determination of Cd 2+ concentration.

[0058] Under different nitrate c...

Embodiment 3

[0060] A cadmium-contaminated soil and groundwater remediation agent and a remediation method thereof, comprising the following steps:

[0061] The preparation method of the restoration agent is as described in Example 1.

[0062] Prepare 250mL cadmium-contaminated groundwater samples with deoxygenated water in an anaerobic reactor, where Cd 2+ The concentration is 10mg / L, NO 3 - -N concentration is 28mg / L, adjust pH to be 5.0, 6.0, 7.0, 8.0 respectively, add restoration agent containing zero-valent iron and microorganism (wherein the content of zero-valent iron in sample is 1g / L, the content of microorganism in sample Content is 50mg / L), use nitrogen to exhaust the air in the reactor, then seal it and place it at 25°C for 5d. At 0d, 0.5d, 1d, 2d, 3d, 4d and 5d after the start of the reaction, 5mL water samples were taken from the reactor and filtered through a 0.22μm membrane to measure Cd 2+ concentration.

[0063] At different pH, the remediation effect of nitrate-medi...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
particle diameteraaaaaaaaaa
Login to View More

Abstract

The invention discloses a cadmium-contaminated soil and underground water repairing agent and a repairing method thereof. The repairing agent comprises zero-valent iron powder and hydrogen autotrophicdenitrifying bacteria. The method comprises the following steps: adding zero-valent iron powder, hydrogen autotrophic denitrifying bacteria and nitrate into cadmium-polluted soil and underground water, and repairing in a normal-temperature anaerobic environment. According to the method, hydrogen released by reaction of zero-valent iron and water under anaerobic conditions is used as an electron donor for denitrification through hydrogen autotrophic denitrifying bacteria to promote the corrosion of the zero-valent iron so as to generate high-activity iron minerals on the surface of the zero-valent iron, so that the zero-valent iron can adsorb and fix a large number of cadmium ions; the repairing method effectively solves the problem that zero-valent iron cannot be directly subjected to a redox reaction with cadmium to cause corrosion limitation of the zero-valent iron, and can greatly reduce the migration capacity and bioavailability of cadmium in soil and underground water; and the repairing agent has the characteristics of being stable in remediation effect, low in cost, small in environmental influence and the like, and is suitable for remediation of cadmium-contaminated soil and underground water.

Description

technical field [0001] The invention belongs to the technical field of soil and groundwater environment restoration, and in particular relates to a cadmium-contaminated soil and groundwater restoration agent and a restoration method for cadmium-contaminated soil and groundwater. Background technique [0002] As an important chemical raw material, cadmium is widely used in metal processing, battery manufacturing, electroplating, dyes and other industries. Under natural conditions, cadmium often coexists with lead and zinc to form lead-zinc ore. In industrial production such as ore sintering and metal smelting, due to leakage in the production process, unreasonable discharge of wastewater, and seepage of cadmium-containing waste residue, etc., A large amount of cadmium enters the soil and groundwater environment, causing increasingly serious cadmium pollution. Cadmium has a bioaccumulation effect and can be accumulated and transmitted through the food chain. Excessive intake ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C09K17/40C09K17/42B09C1/00B09C1/08B09C1/10C02F9/14C02F101/22C02F103/06
CPCB09C1/002B09C1/08B09C1/10B09C2101/00C02F1/001C02F1/705C02F3/28C02F9/00C02F2101/22C02F2103/06C09K17/40C09K17/42
Inventor 吴锦华颜铭佳李冰吕斯濠邓建平李平
Owner SOUTH CHINA UNIV OF TECH