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Graphitized carbon purification method

A technology of graphitized carbon and purification methods, applied in chemical instruments and methods, carbon compounds, inorganic chemistry, etc., can solve problems such as difficulty in separating amorphous carbon, and achieve excellent electromagnetic shielding performance, high conductivity, and good adsorption effect Effect

Active Publication Date: 2021-01-12
FUJIAN NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The technical problem to be solved by the present invention is to provide a low-cost graphitized carbon purification method and its application for the existing problem of difficult separation of amorphous carbon left in graphitized carbon. Amorphous carbon is removed from graphitized carbon to obtain pure graphitized carbon, and the prepared graphitized carbon materials exhibit excellent performance in energy storage, environmental treatment, functional plastics and other fields

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] 1. Dilute concentrated nitric acid to prepare 4 mol / L nitric acid solution;

[0025] 2. Soak 10 mg of one-dimensional composite carbon fiber in 25 mL of 4 mol / L nitric acid solution;

[0026] 3. Transfer the above step 2 solution to a 50 mL hydrothermal reactor at 170 °C for 15 hours, and wait for the reactor to cool and filter to obtain one-dimensional graphite carbon fibers;

[0027] 4. Wash the obtained one-dimensional graphite carbon fiber with distilled water and 95% alcohol for 3 times in sequence. After washing, the pH value is 6.5, and dry;

[0028] 5. Heat-treat the dried one-dimensional graphite carbon fiber at 500 °C for 30 min while passing hydrogen / argon mixed gas to a vacuum degree of -100 torr to remove the oxidation functional group;

[0029] 6. Prepare lithium-ion electrodes according to conventional methods: use the prepared graphite carbon fiber as the working electrode, the lithium sheet as the counter electrode, Celgard 2400 as the diaphragm, and 1...

Embodiment 2

[0031] 1. Dilute concentrated nitric acid to prepare 6 mol / L nitric acid solution;

[0032] 2. Soak 10 mg of composite carbon nanofibers embedded with nickel particles in 20 mL of 6 mol / L nitric acid solution;

[0033] 3. Transfer the above step 2 solution to a 50 mL hydrothermal reactor at a temperature of 150 °C for 12 h, and wait for the reactor to cool and filter to obtain hollow carbon nanomaterials;

[0034] 4. The obtained hollow carbon nanomaterials were cleaned 3 times in sequence with distilled water and 95% alcohol, and the pH value after cleaning was 6.8, and dried;

[0035] 5. Heat-treat the dried hollow graphitized carbon nanomaterials at 600°C for 30 minutes under the condition of vacuum degree -200torr while passing hydrogen / nitrogen mixed gas to remove the oxidation functional groups;

[0036] 6. Prepare the capacitor electrode according to the conventional method: use the prepared hollow graphitized carbon nanomaterial as the working electrode, Pt as the cou...

Embodiment 3

[0038] 1. Dilute concentrated nitric acid to prepare 7 mol / L mixed acid, wherein the molar ratio of nitric acid to hydrochloric acid is 9.5:0.5;

[0039] 2. Soak 10 mg of two-dimensional composite carbon membrane in 25 mL of 7 mol / L mixed acid solution;

[0040] 3. Transfer the above step 2 solution to a 50 mL hydrothermal reactor at 180 °C for 10 h, and wait for the reactor to cool and filter to obtain a two-dimensional ultra-thin graphitized carbon film;

[0041] 4, the two-dimensional ultra-thin graphitized carbon membrane obtained is cleaned 3 times with distilled water and 95% alcohol sequence, and the pH value after cleaning is 6.5, dries;

[0042] 5. Heat-treat the dried two-dimensional ultra-thin graphitized carbon film at 700 °C for 30 min to remove impurity functional groups while passing hydrogen / argon mixed gas to a vacuum degree of -300 Torr;

[0043] 6. Put the prepared material into wastewater containing heavy metal ions. The prepared two-dimensional ultra-thin...

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Abstract

The invention relates to a graphitized carbon purification method. The method comprises the following steps: 1) preparing an acid solution with the concentration of 0.5-10 mol / L; 2) soaking the composite carbon in an acid solution to obtain a composite carbon / acid solution, wherein the composite carbon accounts for 1-80% of the weight of the acid solution; (3) reacting the obtained composite carbon / acid solution at high temperature and high pressure, and selectively etching the composite carbon through acid to remove amorphous carbon remained in the composite carbon so as to obtain graphitizedcarbon; 4) sequentially cleaning and thermally treating the obtained graphitized carbon to obtain a pure graphitized carbon material. The method has the following beneficial effects that the purification technology has the advantages of being efficient, rapid, high in selectivity and the like and is not restrained by the morphology of the purified material, and the graphitized carbon material prepared through the method has wide application.

Description

technical field [0001] The invention relates to a method for purifying graphitized carbon, more specifically, to a method for purifying graphitized carbon material by acid selective etching of amorphous carbon. Background technique [0002] Graphitized carbon materials have attracted attention in the fields of electronic devices, sensors, and energy storage due to their unique structures and physical and chemical properties. Template method, electrospinning technology and other technologies can nanomaterials, and have been widely used in the preparation of ordered mesoporous carbon, carbon nanofibers, carbon nanotubes and other functional materials. For example, carbon nanofibers can be obtained by calcining electrospun polyacrylonitrile at a high temperature of 700 degrees, but the obtained carbon is an amorphous carbon material. Catalysts (nickel, cobalt, iron, etc.) can catalyze the conversion of amorphous carbon into graphitized carbon to obtain graphitized carbon. How...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B32/215
CPCC01B32/215
Inventor 李小燕陈育明陈庆华钱庆荣肖荔人李轩王曼茜李川平李瑞玲何佳波邱敏
Owner FUJIAN NORMAL UNIV