Environment-friendly colored TPU film for furniture and preparation method thereof

Abstract

The invention provides an environment-friendly colored TPU film for furniture and a preparation method of the environment-friendly colored TPU film. The environment-friendly colored TPU film for furniture is prepared from the following raw materials in parts by weight: 55-75 parts of polyether polyol, 25-35 parts of diisocyanate, 1-10 parts of a chain extender, 10-20 parts of modified polytetrafluoroethylene, 1-10 parts of modified basalt fibers, 1-5 parts of a nano photocatalyst, 1-5 parts of a plant pigment, 0.5-3 part of an epoxy group-containing silane coupling agent and 0.05-0.1 part of acatalyst. The environment-friendly colored TPU film for furniture is uniform in component color dispersion, free of color stripes and free of local color difference, has excellent waterproof performance and various mechanical properties, is green and environment-friendly in component raw materials, and is suitable for the field of furniture protection.

Description

technical field

[0001] The invention belongs to the technical field of polymer materials, and in particular relates to a TPU film and a preparation method thereof, in particular to an environment-friendly colored TPU film for furniture and a preparation method thereof. Background technique

[0002] TPU (Thermoplasticpolyyrethane, thermoplastic polyurethane) is a new type of organic polymer synthetic material with excellent properties; for example, the wear resistance and resilience are better than ordinary polyurethane and PVC, and the aging resistance is better than rubber. It is a substitute for PVC and PU. The ideal material is an internationally recognized new polymer material. In the coloring of TPU materials, the main use now is to directly add pigment products or dye products into polyurethane resin for synthetic leather, and after stirring, fully mix the pigment products or dye products with polyurethane resin to achieve the purpose of polyurethane resin coloring. M...

Examples

preparation example 1

[0066] This preparation example provides a kind of modified polytetrafluoroethylene I, and described modified polytetrafluoroethylene I is prepared by following preparation method: 100g sodium naphthalene solution (taking the quality of described sodium naphthalene solution as 100%, sodium 3%, naphthalene 12%, the balance is tetrahydrofuran) and 40g polytetrafluoroethylene (the number average molecular weight is 400,000) after mixing and stirring at 15°C for 6min, filtering, and drying at 30°C for 2h to obtain modified polytetrafluoroethylene Vinyl I.

preparation example 2

[0068] This preparation example provides a kind of modified polytetrafluoroethylene II, and described modified polytetrafluoroethylene II is prepared by following preparation method: 100g sodium naphthalene solution (taking the quality of described sodium naphthalene solution as 100%, sodium 4%, naphthalene 15%, the balance is tetrahydrofuran) and 50g polytetrafluoroethylene (the number average molecular weight is 500,000) mixed and stirred at 20°C for 10min, filtered, and dried at 35°C for 1.5h to obtain modified polytetrafluoroethylene Vinyl Fluoride II.

preparation example 3

[0070] This preparation example provides a kind of modified polytetrafluoroethylene III, and described modified polytetrafluoroethylene III is prepared by the following preparation method: 100g sodium naphthalene solution (taking the quality of described sodium naphthalene solution as 100%, sodium 3%, naphthalene 10%, the balance is tetrahydrofuran) and 30g polytetrafluoroethylene (the number-average molecular weight is 300,000) at 10°C and mixed and stirred for 10min, filtered, and dried at 20°C for 2h to obtain modified polytetrafluoroethylene Vinyl III.

technical field

[0001] The invention belongs to the technical field of polymer materials, and in particular relates to a TPU film and a preparation method thereof, in particular to an environment-friendly colored TPU film for furniture and a preparation method thereof. Background technique

[0002] TPU (Thermoplasticpolyyrethane, thermoplastic polyurethane) is a new type of organic polymer synthetic material with excellent properties; for example, the wear resistance and resilience are better than ordinary polyurethane and PVC, and the aging resistance is better than rubber. It is a substitute for PVC and PU. The ideal material is an internationally recognized new polymer material. In the coloring of TPU materials, the main use now is to directly add pigment products or dye products into polyurethane resin for synthetic leather, and after stirring, fully mix the pigment products or dye products with polyurethane resin to achieve the purpose of polyurethane resin coloring. M...

Examples

preparation example 1

[0066] This preparation example provides a kind of modified polytetrafluoroethylene I, and described modified polytetrafluoroethylene I is prepared by following preparation method: 100g sodium naphthalene solution (taking the quality of described sodium naphthalene solution as 100%, sodium 3%, naphthalene 12%, the balance is tetrahydrofuran) and 40g polytetrafluoroethylene (the number average molecular weight is 400,000) after mixing and stirring at 15°C for 6min, filtering, and drying at 30°C for 2h to obtain modified polytetrafluoroethylene Vinyl I.

preparation example 2

[0068] This preparation example provides a kind of modified polytetrafluoroethylene II, and described modified polytetrafluoroethylene II is prepared by following preparation method: 100g sodium naphthalene solution (taking the quality of described sodium naphthalene solution as 100%, sodium 4%, naphthalene 15%, the balance is tetrahydrofuran) and 50g polytetrafluoroethylene (the number average molecular weight is 500,000) mixed and stirred at 20°C for 10min, filtered, and dried at 35°C for 1.5h to obtain modified polytetrafluoroethylene Vinyl Fluoride II.

preparation example 3

[0070] This preparation example provides a kind of modified polytetrafluoroethylene III, and described modified polytetrafluoroethylene III is prepared by the following preparation method: 100g sodium naphthalene solution (taking the quality of described sodium naphthalene solution as 100%, sodium 3%, naphthalene 10%, the balance is tetrahydrofuran) and 30g polytetrafluoroethylene (the number-average molecular weight is 300,000) at 10°C and mixed and stirred for 10min, filtered, and dried at 20°C for 2h to obtain modified polytetrafluoroethylene Vinyl III.

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