Cr<3+>-doped lithium-magnesium-based germanate ultra-wideband near-infrared luminescent material and preparation method thereof
A lithium-magnesium-based germanate, luminescent material technology, applied in luminescent materials, chemical instruments and methods, etc., can solve the problems of narrow wavelength range of near-infrared luminescent materials, and achieve easy technology promotion and industrialized mass production, easy operation, Simple preparation method
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[0029] The present invention will be described in further detail below in conjunction with the examples, but the embodiments of the present invention are not limited thereto. Embodiment 1: The chemical composition formula of this embodiment is LiMg 2 sc 0.96 Cr 0.04 Ge 2 o 8 The specific preparation method of the broadband near-infrared luminescent material is as follows:
[0030] According to the chemical composition formula LiMg 2 sc 0.96 Cr 0.04 Ge 2 o 8 According to the stoichiometric ratio, weigh Li respectively 2 CO 3 ,MgO,Sc 2 o 3 ,GeO 2 and Cr 2 o 3 , adding 1 wt% H 3 BO 3 Put it in an agate mortar and add an appropriate amount of absolute ethanol to grind for 30 minutes. After it is dry, scrape off the powder attached to the wall of the mortar and dry grind for 30 minutes. Then put it in a high-temperature alumina crucible and put it in a box-type Pre-fire in the furnace, heat up to 900°C at a heating rate of 8°C / min, keep the temperature for 4 hours...
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