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Filler particle for adsorbing inorganic phosphorus in wastewater

A technology of inorganic phosphorus and particles, applied in the direction of adsorption of water/sewage treatment, water pollutants, water/sewage treatment, etc., to achieve the effects of high porosity, extended regeneration interval, and large specific surface area

Active Publication Date: 2021-02-09
江西挺进环保科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] But the problem is: how to simultaneously improve the removal efficiency and adsorption life of inorganic phosphorus adsorbent

Method used

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  • Filler particle for adsorbing inorganic phosphorus in wastewater
  • Filler particle for adsorbing inorganic phosphorus in wastewater

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A filler particle comprising diatomaceous earth-based porous ceramics, rare earth chelates, and potassium permanganate.

[0024] Prepared by the following method: 10 parts by weight of diatomite-based porous ceramics are distributed in a rare earth chelate solution, and the mass percent concentration of the rare earth chelate in the rare earth chelate solution is 5%; under the action of ultrasonic waves, Stirring and dispersing evenly and then filtering to obtain a solid; drying the solid and spraying a 1% potassium permanganate solution corresponding to 1% of the weight of the porous carrier particles, and drying to obtain the solid. The porous carrier particles are ceramsite, the particle size is 5±2mm,

[0025] The rare earth chelate is obtained by mixing lanthanum chloride and disodium EDTA with a molar ratio of 1:2.5, and its specific preparation method is:

[0026] Add 1.12g of lanthanum chloride and 3.88g of disodium EDTA into 95g of water, stir and disperse for...

Embodiment 2

[0029] A filler particle comprising diatomaceous earth-based porous ceramics, rare earth chelates, and potassium permanganate.

[0030] Prepared by the following method: 10 parts by weight of diatomite-based porous ceramics (same as Example 1) are distributed in the rare earth chelate solution, and the mass percent concentration of the rare earth chelate in the rare earth chelate solution is 10% Under the action of ultrasonic waves, stir and disperse uniformly and then filter to obtain a solid; after drying the solid, spray a solution of 1% potassium permanganate with a concentration equivalent to 1% by weight of the porous carrier particles, and obtain it after drying.

[0031] The rare earth chelate is obtained by mixing lanthanum chloride and disodium EDTA with a molar ratio of 1:2.5, and its specific preparation method is:

[0032] Add 2.24g of lanthanum chloride and 7.76g of disodium EDTA into 90g of water, stir and disperse for 10-20 minutes.

Embodiment 3

[0034] A filler particle comprising diatomaceous earth-based porous ceramics, rare earth chelates, and potassium permanganate.

[0035] Prepared by the following method: 10 parts by weight of diatomite-based porous ceramics (same as Example 1) are distributed in the rare earth chelate solution, and the mass percent concentration of the rare earth chelate in the rare earth chelate solution is 8% Under the action of ultrasonic waves, stir and disperse uniformly and then filter to obtain a solid; spray the solid with a concentration of 1% potassium permanganate solution equivalent to 0.5% by weight of the porous carrier particles after drying, and obtain it after drying.

[0036] The rare earth chelate is obtained by mixing lanthanum chloride and disodium EDTA with a molar ratio of 1:2.2, and its specific preparation method is:

[0037] Add 2g of lanthanum chloride and 6g of disodium EDTA into 90g of water, stir and disperse for 10-20 minutes.

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Abstract

The invention belongs to the field of sewage treatment, and discloses a filler particle for adsorbing inorganic phosphorus in wastewater. The filler particle comprises a porous carrier particle, a rare earth chelate and potassium permanganate, wherein the porous carrier particle is diatomite-based porous ceramic, the particle size of the diatomite-based porous ceramic is 5-10 mm. The preparation method comprises the following steps: step 1, preparing a rare earth chelate, namely dissolving lanthanide soluble salt and disodium EDTA in a molar ratio of 1: (2-3) into water to obtain a rare earthchelate solution; step 2, putting the diatomite-based porous ceramic into the solution obtained in the step 1, and conducting stirring for 10-20 minutes under the action of ultrasonic waves; and step3, filtering and drying the diatomite-based porous ceramic, then spraying a potassium permanganate solution which accounts for 0.5-1% of the weight of the porous carrier particle, and conducting drying to obtain the filler particle. The filler particle hase excellent adsorption efficiency and a long regeneration interval.

Description

technical field [0001] In the field of sewage treatment, the invention specifically relates to filler particles for adsorbing inorganic phosphorus in waste water. Background technique [0002] In various sewage treatment processes, the removal of phosphorus is generally realized in the last stage of the entire sewage treatment process after the removal of ammonia nitrogen. [0003] For the removal of phosphorus, the combination of rare earth metals and inorganic phosphorus is widely used to form salt precipitation for removal. [0004] CN201811342198.6 discloses a preparation method of a magnesium-aluminum-lanthanum composite modified vermiculite adsorbent for adsorption and removal of phosphorus. Dissolve MgCl2 and AlCl3 in deionized water to obtain mixed solution A; put vermiculite into mixed solution A to obtain mixed solution B after modification; mixed solution B is aged to obtain mixed solution C; mixed solution C is centrifuged and ground Then obtain substance B; th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/22B01J20/30C02F1/28C02F101/10
CPCB01J20/14B01J20/223B01J20/0207B01J20/04C02F1/288C02F2101/105
Inventor 罗青春简陈生吉康宁肖建林宗毅肖林梁家平殷丽雅
Owner 江西挺进环保科技股份有限公司