Device for producing dimethyl carbonate by transesterification method and using method thereof

A technology for producing dimethyl carbonate and production equipment, which is applied in the field of production equipment for the production of dimethyl carbonate by transesterification, which can solve the problems of high energy consumption in methanol recovery, complicated operation control, and low production efficiency of the equipment, and reduce energy consumption , The interface is updated quickly and the effect of fast response

Pending Publication Date: 2021-03-12
吴剑华
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The transesterification reaction of propylene carbonate or ethylene carbonate and methanol is a reversible reaction. The traditional production method is to make the reaction in a reactive distillation column. In order to pursue a higher conversion rate of

Method used

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  • Device for producing dimethyl carbonate by transesterification method and using method thereof

Examples

Experimental program
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Example Embodiment

[0033]Example 1

[0034]In this example, an ester exchange method of carbonate, including the first ester exchange reactor 1-1, product separation column 2-1, a dithix exchange reactor 1-2, methanol recovery tower 2 -2, pressurized separation tower 3, atmospheric separation tower 4, propylene glycol releasing tower 5, propylene glycol rectification tower 6 and affiliated raw material tank, product can, intermediate can, condenser, reboiler, material delivery device, equipment Connect pipeline, control and display instrumentation and accessories. The first ester exchange reactor 1-1 and the second transesterification reactor 1-2 are tubular reactors that are or without jackets, and the reaction tubes are disposed or do not set a mixture of media from the medium, static spoiler .

[0035]The first transester exchange reactor 1-1 is provided with a metal carbonate, circulating methanol, methanol, catalyst inlet and a reaction material outlet; the product separation tower 2-1 is provided with...

Example Embodiment

[0046]Example 2

[0047]Example 2 is substantially identical to Example 1, and different in the first ester exchange reactor 1-1 and the second transesterification reactor 1-2 are commercially available static mixers.

Example Embodiment

[0048]Example 3

[0049]The present embodiment is substantially the same as that of Example 1, and the difference is that the device does not set the second ester exchange reactor 1-2, the product separation tower 2-1 tower material removes methanol recovery tower 2-2, column top recovery methanol And the residual carbonate dense pressure separation tower 4 or the pressurized separation tower 3.

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Abstract

The ester exchange method dimethyl carbonate production device provided by the invention is provided with two tubular ester exchange reactors which are connected in series for use, and a product separation tower is arranged between the two ester exchange reactors; a fresh raw material propylene (ethylene) carbonate enters the first transesterification reactor, a fresh raw material methanol entersthe second transesterification reactor, and the two transesterification reactors have high reaction driving force. The reaction effect far exceeding the equilibrium conversion rate can be obtained byusing the total feed composition close to the theoretical molar ratio, and the unconverted propylene (ethylene) carbonate and methanol are separated and recycled. The problems of overhigh energy consumption and complex operation control caused by pursuit of excessive methanol in the propylene (ethylene) carbonate conversion rate in the dimethyl carbonate production operation of the traditional reactive distillation column transesterification method are solved. The device is high in production efficiency, good in product quality, low in energy consumption and high in operation flexibility, andthe production process is easy to control.

Description

technical field [0001] The invention relates to a production device of chemical products and a method for using the same, in particular to a device for producing dimethyl carbonate by transesterification and a method for using the same. Background technique [0002] Dimethyl carbonate (DCM) is a basic organic chemical raw material, known as a green organic chemical facing the 21st century. The methods for producing dimethyl carbonate include methanol phosgene method, sodium methoxide phosgene method, methanol oxidative hydroxylation method, methanol and carbon monoxide electrochemical reaction method, carbon dioxide and methanol supercritical synthesis method, urea alcoholysis method, transesterification method, etc. Some of the above methods have been industrialized, and some are still under development and exploration. [0003] Use propylene oxide or ethylene oxide and carbon dioxide as raw materials to synthesize propylene carbonate or ethylene carbonate under the action...

Claims

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Application Information

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IPC IPC(8): C07C68/065C07C68/08C07C69/96
CPCC07C68/065C07C68/08C07C69/96Y02P20/10
Inventor 吴剑华
Owner 吴剑华
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